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RESEARCH PAPER · Journal of Solid State Chemistry · 2000

Formation of Chiral Solids via a Molecular Building Block Approach

Vincent L. Pecoraro, Jeffrey J. Bodwin, Annabel D. Cutland

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Formation of Chiral Solids via a Molecular Building Block ApproachOriginalPreparation of a Chiral, 2-Dimensional Network Containing Metallacrown and Copper Benzoate Building Blocks111ChemInform Abstract: Formation of Chiral Solids via a Molecular Building Block Approach0Hydrothermal Syntheses and Crystal Structures of Ni(II), Co(II), and Cu(II), Bis(trans-4-pyridylacrylate) Interpenetration Networks26Preparation of Site-Differentiated Mixed Ligand and Mixed Ligand/Mixed Metal Metallacrowns97Assembly of a Robust, Thermally Stable Porous Cobalt(II) Nicotinate Framework Based on a Dicobalt Carboxylate Unit74[CdII(bpdc)·H2O]n: A Robust, Thermally Stable Porous Framework through a Combination of a 2-D Grid and a Cadmium Dicarboxylate Cluster Chain (H2bpdc = 2,2‘-Bipyridyl-4,4‘-dicarboxylic Acid)146Nature of the Reactants and Influence of Water on the Supramolecular Assembly59An Unprecedented 8-Fold Interpenetrating Diamondoid-like Coordination Polymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node43Homochiral Zn and Cd Coordination Polymers Containing Amino Acid−Tetrazole Ligands121[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide‐Bridged Nanosized Molecular Wheel166[MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide‐Bridged Nanosized Molecular Wheel13Metallacrown-based compartments: selective encapsulation of three isonicotinate anions in non-centrosymmetric solids61Old materials with new tricks: multifunctional open-framework materials1073Controlling the Polymorph of LnIII(NO3)3-x(OH)x[15-MCCuII(N)S-pheHA-5] Complexes through Solvent Type and LnIII Ion Choice38Substituent Effect on Formation of Heterometallic Molecular Wheels: Synthesis, Crystal Structure, and Magnetic Properties94Preparation and Reactivity of 4,4′-diaminostilbene-2,2′disulphonate2Structural and Functional Evolution of Metallacrowns504Periodic Nanostructures Based on Metal–Organic Frameworks (MOFs): En Route to Zeolite‐Like Metal–Organic Frameworks (ZMOFs)14Copper(II)–lanthanide(III) 15-metallacrown-5 complexes based on pyrazinohydroxamic acid as new multiple-binding pentagonal platforms with Lewis amphoteric nature19A 2D Layered Metal–Organic Framework Constructed by Using a Hexanuclear Manganese Metallamacrocycle as a Supramolecular Building Block242D Layered metal–organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks24Polymorphism and Inclusion Properties of Three-Dimensional Metal-Organometallic Frameworks Derived from a Terephthalate Sandwich Compound23An extremely rare example of asymmetric tetranuclear core {M 4 (μ 3 -X) 2 (μ-X) 4 } in a novel alkoxo-bridged heterometallic Cr/Cd complex8Chiral Metallacrown Supramolecular Compartments that Template Nanochannels: Self‐Assembly and Guest Absorption51Use of 2-pyrimidineamidoxime to generate polynuclear homo-/heterometallic assemblies: synthesis, crystal structures and magnetic study with theoretical investigations on the exchange mechanism32Voltammetric Characterization of Redox‐Inactive Guest Binding to LnIII[15‐Metallacrown‐5] Hosts Based on Competition with a Redox Probe54Gd(III)[15-Metallacrown-5] Recognition of Chiral α-Amino Acid Analogues66Metallacrowns of copper(II) and aminohydroxamates: Thermodynamics of self assembly and host–guest equilibria133Effects of the Central Lanthanide Ion Crystal Radius on the 15-MCCuII(N)pheHA-5 Structure49Influencing the Size and Anion Selectivity of Dimeric Ln3+[15-Metallacrown-5] Compartments through Systematic Variation of the Host Side Chains and Central Metal59Transposition of chirality from diphosphonate metal–organic framework precursors onto porous lanthanide pyrophosphates20Isolation of Elusive Tetranuclear and Pentanuclear M(II)–Hydroximate Intermediates in the Assembly of Lanthanide [15-Metallacrown-5] Complexes3322-Azametallacrown-8 complex with a triazole-bridged ligand: synthesis, structure and magnetic properties13One-Dimensional Coordination Polymers of 12-Metallacrown-4 Complexes: {Na2(L)2[12- ${\rm{M}}{{\rm{C}}_{{\rm{M}}{{\rm{n}}^{{\rm{III}}}}{\rm{(N)shi}}}}$ M C M n III ( N ) shi -4]} n , where L is Either −O2CCH2CH3 or −O2CCH2CH2CH39A breathing chiral molecular solid for enantioseparation via single-crystal-to-single-crystal transformation13Heterometal–organic frameworks: Three novel copper(II)–lanthanide(III) 15-metallacrown-5 complexes based on pyrazinohydroxamic acid as new multiple-binding pentagonal platform9Four Mixed 3d-4f 12-Metallacrown-4 Complexes: Syntheses, Structures and Magnetic Properties13Three-Dimensional Porous Architectures Based on MnII/III Three-Blade Paddle Wheel Metallacryptates7Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown118Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown12Aspects of NMR Characterization of Metallacrowns1

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41 direct citing papers saved.

  1. Preparation of a Chiral, 2-Dimensional Network Containing Metallacrown and Copper Benzoate Building Blocks

    Inorganic Chemistry · 2000-07-21

    Jeffrey J. Bodwin, Vincent L. Pecoraro

    Read original paper ↗ ·

  2. ChemInform Abstract: Formation of Chiral Solids via a Molecular Building Block Approach

    ChemInform · 2000-10-17

    Vincent L. Pecoraro, Jeffrey J. Bodwin, Annabel D. Cutland

    Read original paper ↗ ·

  3. Hydrothermal Syntheses and Crystal Structures of Ni(II), Co(II), and Cu(II), Bis(trans-4-pyridylacrylate) Interpenetration Networks

    Journal of Solid State Chemistry · 2001-02-01

    Yen-Hsiang Liu, Chia-Shiang Lin, Shiang-Ying Chen, Hui‐Lien Tsai, Chuen‐Her Ueng, Kuang‐Lieh Lu

    Read original paper ↗ ·

  4. Preparation of Site-Differentiated Mixed Ligand and Mixed Ligand/Mixed Metal Metallacrowns

    Inorganic Chemistry · 2001-02-23

    George Psomas, Ann Joern Stemmler, C. Dendrinou-Samara, Jeffrey J. Bodwin, Manuela Schneider, Maria V. Alexiou, Jeff W. Kampf, Dimitris P. Kessissoglou, Vincent L. Pecoraro

    Read original paper ↗ ·

  5. Assembly of a Robust, Thermally Stable Porous Cobalt(II) Nicotinate Framework Based on a Dicobalt Carboxylate Unit

    Inorganic Chemistry · 2001-10-31

    Yen‐Hsiang Liu, Hui‐Lien Tsai, Yi-Long Lu, Yuh‐Sheng Wen, Ju‐Chun Wang, Kuang‐Lieh Lu

    Read original paper ↗ ·

  6. [CdII(bpdc)·H2O]n: A Robust, Thermally Stable Porous Framework through a Combination of a 2-D Grid and a Cadmium Dicarboxylate Cluster Chain (H2bpdc = 2,2‘-Bipyridyl-4,4‘-dicarboxylic Acid)

    Inorganic Chemistry · 2002-04-11

    Yen‐Hsiang Liu, Yi-Long Lu, Huang‐Chun Wu, Ju‐Chun Wang, Kuang‐Lieh Lu

    Read original paper ↗ ·

  7. Nature of the Reactants and Influence of Water on the Supramolecular Assembly

    Inorganic Chemistry · 2003-07-29

    Xiaobai Wang, Jagadese J. Vittal

    Read original paper ↗ ·

  8. An Unprecedented 8-Fold Interpenetrating Diamondoid-like Coordination Polymer Containing a Cu+4(RCO2)4 Cluster as Connecting Node

    Inorganic Chemistry · 2003-08-16

    Xi-Sen Wang, Hong Lin Zhao, Zhi‐Rong Qu, Qiong Ye, Jing Zhang, Ren‐Gen Xiong, Xiao‐Zeng You, Hoong‐Kun Fun

    Read original paper ↗ ·

  9. Homochiral Zn and Cd Coordination Polymers Containing Amino Acid−Tetrazole Ligands

    Inorganic Chemistry · 2003-11-01

    Zhi‐Rong Qu, Hong Lin Zhao, Xi-Sen Wang, Yong-Hua Li, Yu‐Mei Song, Yujuan Liu, Qiong Ye, Ren‐Gen Xiong, Brendan F. Abrahams, Zi‐Ling Xue, Xiao‐Zeng You

    Read original paper ↗ ·

  10. [MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide‐Bridged Nanosized Molecular Wheel

    Angewandte Chemie International Edition · 2005-11-03

    Zhong‐Hai Ni, Hui‐Zhong Kou, Lifang Zhang, Chunhua Ge, Ai‐Li Cui, Ru‐Ji Wang, Yadong Li, Osamu Sato

    Read original paper ↗ ·

  11. [MnIII(salen)]6[FeIII(bpmb)(CN)2]6⋅7 H2O: A Cyanide‐Bridged Nanosized Molecular Wheel

    Angewandte Chemie · 2005-11-03

    Zhong‐Hai Ni, Hui‐Zhong Kou, Lifang Zhang, Chunhua Ge, Ai‐Li Cui, Ru‐Ji Wang, Yadong Li, Osamu Sato

    Read original paper ↗ ·

  12. Metallacrown-based compartments: selective encapsulation of three isonicotinate anions in non-centrosymmetric solids

    Chemical Communications · 2007-01-01

    Gellert Mezei, Jeff W. Kampf, Shilie Pan, Kenneth Reinhard Poeppelmeier, B. Watkins, Vincent L. Pecoraro

    Read original paper ↗ ·

  13. Old materials with new tricks: multifunctional open-framework materials

    Chemical Society Reviews · 2007-01-01

    Daniel Maspoch, Daniel Ruiz‐Molina, Jaume Veciana

    Read original paper ↗ ·

  14. Controlling the Polymorph of LnIII(NO3)3-x(OH)x[15-MCCuII(N)S-pheHA-5] Complexes through Solvent Type and LnIII Ion Choice

    Crystal Growth & Design · 2007-05-12

    Curtis M. Zaleski, Annabel D. Cutland-Van Noord, Jeff W. Kampf, Vincent L. Pecoraro

    Read original paper ↗ ·

  15. Substituent Effect on Formation of Heterometallic Molecular Wheels: Synthesis, Crystal Structure, and Magnetic Properties

    Inorganic Chemistry · 2007-06-28

    Zhong-Hai Ni, Li‐Fang Zhang, V. Tangoulis, Wolfgang Wernsdorfer, Ai-Li Cui, Osamu Sato, Hui‐Zhong Kou

    Read original paper ↗ ·

  16. Preparation and Reactivity of 4,4′-diaminostilbene-2,2′disulphonate

    Journal of Chemical Crystallography · 2007-07-17

    N.C. Rader, Heather A. Nees, P.S. Szalay, Mat­thias Zeller, Allen D. Hunter

    Read original paper ↗ ·

  17. Structural and Functional Evolution of Metallacrowns

    Chemical Reviews · 2007-11-01

    Gellert Mezei, Curtis M. Zaleski, Vincent L. Pecoraro

    Read original paper ↗ ·

  18. Periodic Nanostructures Based on Metal–Organic Frameworks (MOFs): En Route to Zeolite‐Like Metal–Organic Frameworks (ZMOFs)

    Unknown journal · 2008-02-20

    Mohamed Eddaoudi, Jarrod F. Eubank

    Read original paper ↗ ·

  19. Copper(II)–lanthanide(III) 15-metallacrown-5 complexes based on pyrazinohydroxamic acid as new multiple-binding pentagonal platforms with Lewis amphoteric nature

    Polyhedron · 2008-06-09

    E.V. Govor, A.B. Lysenko, Alexander N. Chernega, Judith A. K. Howard, Andriy A. Mokhir, Joachim Sieler, K.V. Domasevitch

    Read original paper ↗ ·

  20. A 2D Layered Metal–Organic Framework Constructed by Using a Hexanuclear Manganese Metallamacrocycle as a Supramolecular Building Block

    European Journal of Inorganic Chemistry · 2008-11-04

    Jeungwook Choi, Jaejoon Park, Mira Park, Dohyun Moon, Myoung Soo Lah

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  21. 2D Layered metal–organic frameworks built using a hexanuclear metallamacrocycle and an octanuclear metallamacrocycle as supramolecular building blocks

    CrystEngComm · 2009-01-01

    Dohyun Moon, Jiheh Song, Myoung Soo Lah

    Read original paper ↗ ·

  22. Polymorphism and Inclusion Properties of Three-Dimensional Metal-Organometallic Frameworks Derived from a Terephthalate Sandwich Compound

    Inorganic Chemistry · 2009-05-27

    S.A. Kumalah, K.T. Holman

    Read original paper ↗ ·

  23. An extremely rare example of asymmetric tetranuclear core {M 4 (μ 3 -X) 2 (μ-X) 4 } in a novel alkoxo-bridged heterometallic Cr/Cd complex

    Dalton Transactions · 2009-12-21

    Valentyna V. Semenaka, Oksana V. Nesterova, Vladimir N. Kokozay, Viktoriya V. Dyakonenko, Олег В. Шишкин, Roman Boča, Julia Jezierska

    Read original paper ↗ ·

  24. Chiral Metallacrown Supramolecular Compartments that Template Nanochannels: Self‐Assembly and Guest Absorption

    Chemistry - An Asian Journal · 2009-12-23

    Choong‐Sun Lim, Joseph Jankolovits, Jeff W. Kampf, Vincent L. Pecoraro

    Read original paper ↗ ·

  25. Use of 2-pyrimidineamidoxime to generate polynuclear homo-/heterometallic assemblies: synthesis, crystal structures and magnetic study with theoretical investigations on the exchange mechanism

    Dalton Transactions · 2010-01-01

    Bappaditya Gole, Rajesh Chakrabarty, Sandip Mukherjee, You Song, Partha Sarathi Mukherjee

    Read original paper ↗ ·

  26. Voltammetric Characterization of Redox‐Inactive Guest Binding to LnIII[15‐Metallacrown‐5] Hosts Based on Competition with a Redox Probe

    Chemistry - A European Journal · 2010-05-12

    Joseph Jankolovits, Jeff W. Kampf, Stephen Maldonado, Vincent L. Pecoraro

    Read original paper ↗ ·

  27. Gd(III)[15-Metallacrown-5] Recognition of Chiral α-Amino Acid Analogues

    Inorganic Chemistry · 2011-05-03

    Choong‐Sun Lim, Joseph Jankolovits, Peng Jun Zhao, Jeff W. Kampf, Vincent L. Pecoraro

    Read original paper ↗ ·

  28. Metallacrowns of copper(II) and aminohydroxamates: Thermodynamics of self assembly and host–guest equilibria

    Coordination Chemistry Reviews · 2011-06-26

    Matteo Tegoni, Maurizio Remelli

    Read original paper ↗ ·

  29. Effects of the Central Lanthanide Ion Crystal Radius on the 15-MCCuII(N)pheHA-5 Structure

    Inorganic Chemistry · 2011-07-18

    Curtis M. Zaleski, Choong‐Sun Lim, Annabel D. Cutland-Van Noord, Jeff W. Kampf, Vincent L. Pecoraro

    Read original paper ↗ ·

  30. Influencing the Size and Anion Selectivity of Dimeric Ln3+[15-Metallacrown-5] Compartments through Systematic Variation of the Host Side Chains and Central Metal

    Inorganic Chemistry · 2012-02-06

    Joseph Jankolovits, Choong‐Sun Lim, Gellert Mezei, Jeff W. Kampf, Vincent L. Pecoraro

    Read original paper ↗ ·

  31. Transposition of chirality from diphosphonate metal–organic framework precursors onto porous lanthanide pyrophosphates

    Chemical Communications · 2013-01-01

    Fa‐Nian Shi, Filipe A. Almeida Paz, Paulo J. A. Ribeiro-Claro, João Rocha

    Read original paper ↗ ·

  32. Isolation of Elusive Tetranuclear and Pentanuclear M(II)–Hydroximate Intermediates in the Assembly of Lanthanide [15-Metallacrown-5] Complexes

    Inorganic Chemistry · 2013-04-11

    Joseph Jankolovits, Jeff W. Kampf, Vincent L. Pecoraro

    Read original paper ↗ ·

  33. 22-Azametallacrown-8 complex with a triazole-bridged ligand: synthesis, structure and magnetic properties

    Dalton Transactions · 2014-09-26

    Hua Yang, Qingxia Yao, Yun‐Wu Li, Dacheng Li, Jianmin Dou

    Read original paper ↗ ·

  34. One-Dimensional Coordination Polymers of 12-Metallacrown-4 Complexes: {Na2(L)2[12- $${\rm{M}}{{\rm{C}}_{{\rm{M}}{{\rm{n}}^{{\rm{III}}}}{\rm{(N)shi}}}}$$ M C M n III ( N ) shi -4]} n , where L is Either −O2CCH2CH3 or −O2CCH2CH2CH3

    Journal of Chemical Crystallography · 2014-12-12

    Kelsey Mengle, Emily J. Longenecker, Mat­thias Zeller, Curtis M. Zaleski

    Read original paper ↗ ·

  35. A breathing chiral molecular solid for enantioseparation via single-crystal-to-single-crystal transformation

    中国科学通报：英文版 · 2015-01-23

    Jun‐Liang Liu, Wei Liu, Guo‐Zhang Huang, Ming‐Liang Tong

    Read original paper ↗ ·

  36. Heterometal–organic frameworks: Three novel copper(II)–lanthanide(III) 15-metallacrown-5 complexes based on pyrazinohydroxamic acid as new multiple-binding pentagonal platform

    Chinese Chemical Letters · 2015-12-17

    Yu Wang, Wen-Shi Wu, Miao‐Ling Huang

    Read original paper ↗ ·

  37. Four Mixed 3d-4f 12-Metallacrown-4 Complexes: Syntheses, Structures and Magnetic Properties

    Journal of Cluster Science · 2016-09-29

    Yaru Qin, Qian Gao, Yanmei Chen, Wei Liu, Feng Lin, Xiang-Fei Zhang, Yaping Dong, Yahong Li

    Read original paper ↗ ·

  38. Three-Dimensional Porous Architectures Based on MnII/III Three-Blade Paddle Wheel Metallacryptates

    Crystal Growth & Design · 2019-01-31

    Vittoria Marzaroli, Giulia Spigolon, Giuseppe Lococciolo, Martina Quaretti, Clarissa Salviati, Jeff W. Kampf, Giulia Licini, Luciano Marchiò, Vincent L. Pecoraro, Matteo Tegoni

    Read original paper ↗ ·

  39. Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown

    Angewandte Chemie International Edition · 2020-11-20

    Jin Wang, Quan‐Wen Li, Si‐Guo Wu, Yan‐Cong Chen, Rui‐Chen Wan, Guo‐Zhang Huang, Yang Liu, Jun‐Liang Liu, Daniel Reta, Marcus J. Giansiracusa, Zhenxing Wang, Nicholas F. Chilton, Ming‐Liang Tong

    Read original paper ↗ ·

  40. Opening Magnetic Hysteresis by Axial Ferromagnetic Coupling: From Mono‐Decker to Double‐Decker Metallacrown

    Angewandte Chemie · 2020-11-20

    Jin Wang, Quan‐Wen Li, Si‐Guo Wu, Yan‐Cong Chen, Rui‐Chen Wan, Guo‐Zhang Huang, Yang Liu, Jun‐Liang Liu, Daniel Reta, Marcus J. Giansiracusa, Zhenxing Wang, Nicholas F. Chilton, Ming‐Liang Tong

    Read original paper ↗ ·

  41. Aspects of NMR Characterization of Metallacrowns

    Springer eBooks · 2022-01-01

    Matteo Melegari, Matteo Tegoni

    Read original paper ↗ ·
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