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RESEARCH PAPER · Inorganic Chemistry · 1997

A New Three-Dimensional Vanadium Selenite, (VO)2(SeO3)3, with Isolated and Edge-Shared VO6 Octahedra

P. Shiv Halasyamani, Dermot O’Hare

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A New Three-Dimensional Vanadium Selenite, (VO)2(SeO3)3, with Isolated and Edge-Shared VO6 OctahedraOriginalSynthesis and Characterization of Non-centrosymmetric TeSeO461Bi2TeO5: Synthesis, Structure, and Powder Second Harmonic Generation Properties123Synthesis and Structural Characterization of a New Series of Vanadoselenites, [SexV4-xO12-x](4-x)- (x = 1, 2)26Synthesis and Characterization of Te2SeO7: A Powder Second-Harmonic-Generating Study of TeO2, Te2SeO7, Te2O5, and TeSeO4212Cd(VO2)4(SeO3)3·H2O: A New Bimetallic Vanadium Selenite Compound with Heptacoordinated Cadmium Ion23SrZn(SeO3)2 Containing Novel ZnO4+2 Bicapped Tetrahedra41Some Smaller Polyoxoanions. Their Synthesis and Characterization in Solution0Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses336Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)284First coordination complex-linked vanadium selenite, [Cu(phen)]2V2Se2O11: hydrothermal synthesis and crystal structure25Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]113Hydrothermal Syntheses and Crystal Structures of Complex-Linked Three-Dimensional Coordination Vanadium Selenites: M(4,4‘-bipy)(H2O)V2Se2O10 (M = Co, Ni)44Hydrothermal syntheses and structures of two novel vanadium selenites, {[VO(OH)(H2O)](SeO3)}4·2H2O and (H3NCH2CH2NH3)[(VO)(SeO3)2]40Salt-Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite-Type Polar Framework Containing the Acentric [Si2O7]6- Polyanion in the Anti-ReO3 Type [(Ba2Mn)Cl]6+ Cage39New alkali–metal–molybdenum(VI)–selenium(IV) oxides: syntheses, structures, and characterization of A2SeMoO6 (A=Na+, K+, or Rb+)67A new 2-D selenic vanadate network decorated by a coordination complex fragment: [Cu(phen)(H2O)2][V3Se3O14] · H2O10Organically templated zinc selenites: MIL-86 or [H2N(CH2)2NH2]2·Zn4(SeO3)4 and MIL-87 or [H3N(CH2)3NH3]4·Zn4(SeO3)825A novel vanadyl selenite templated by organic salt: [(VO)(H2O)2(SeO3)]2[(H2pipe)SO4]9Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals660Salt-Inclusion Synthesis of Two New Polar Solids, Ba6Mn4Si12O34Cl3 and Ba6Fe5Si11O34Cl344Products and kinetics of non-isothermal decomposition of vanadium(IV) oxide compounds174catena-Poly[[(2,2′-bipyridyl)oxidovanadium]-di-μ2-oxido-[(2,2′-bipyridyl)oxidovanadium]-μ3-selenito-bis[(2,2′-bipyridyl)dioxidovanadium]-μ3-selenito]0ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations54Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems46Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems62KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework99Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites54Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites41Synthesis and structure of A4V6[Te24+Te6+]O24 (A = K, Rb)—two new quaternary mixed-valent tellurium oxides9[R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers34New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)50Synthesis, crystal structure and optical properties of Ba5V3O12F18A Barium Vanadium(v) Selenite Hydrate, Ba(VO2)2(SeO3)2·H2O: A Novel 3D Polymer of Cross-Linked Sheets with Embedded ···V–O–V··· 21 Helices*3New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )12Theoretical study of the local structures and the EPR parameters for RLNKB glasses with VO2+ and Cu2+ dopants28Theoretical study of local structures and EPR parameters for xV2O5-(100 − x)[0.8NaPO3-0.2ZnO]: V4+ glasses at different concentrations13Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O2Evaluation of EPR parameters for compressed and elongated local structures of VO2+ and Cu2+ spin probes in BaO-TeO2-B2O3 glasses49Theoretical investigations on the EPR parameters and local structures for V4+ in alkali niobium borate glasses13An investigation of local structures and EPR spectra for Cu2+ and VO2+ in biochar12Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization20Theoretical investigation on the EPR parameters for VO2+ doped ZnO–CdS nanocomposites4Theoretical investigations on the defect structures and g factors for W5+ in lead bismuth arsenate glasses2Studies on spin Hamiltonian parameters and local structures for v4+ in BaCl2-BaO-B2O3 glasses at various BaCl2 compositions3Influence of V2O5 on physical and spectral (optical, EPR & FTIR) studies of SrO-TeO2-TiO2-B2O3 glasses33Studies on the local structure and spin Hamiltonian parameters for V 4+ in Na 2 O–PbO–Bi 2 O 3 –SiO 2 glass ceramics1Synthesis, structure and catalytic study of a new sandwiched-type vanadoselenite4Theoretical study of the local distortions and the EPR parameters for VO2+ and Cu2+ centers in oxyfluoroborate glasses16Relationship between the gyromagnetic anisotropy and tetragonal distortion for d1 ions in octahedral clusters0Theoretical analysis on lead halides content dependences of defect structures and spin Hamiltonian parameters in lead halo borate glass composites with V2O5 dopants6Investigations of defect structures for V4+ in CBPB glasses with distinct V2O5 contents7Theoretical studies of the EPR spectra and local structures for Cu2+ and V4+ doped halo-borate glasses12A comparable study of the EPR spectra and local structures for 3d 1 ‐ and 3d 9 ‐doped halo‐borate glasses1Theoretical studies of the concentration dependences of d – d transition band, g factors, and local distortion for V 4+ in Li 2 O–PbO–B 2 O 3 –P 2 O 5 glasses4Theoretical studies on the g factors, optical absorption, and their concentration variations for Mo5+ in 40PbO–(10 − x)Y2O3–50P2O5:xMoO3 glass0Theoretical analysis on strontium-tellurium content dependencies of defect structures and spin Hamiltonian parameters for strontium-tellurium titanium borate glasses with V2O5 dopants0Theoretical investigations on the defect structures and g factors for V 4+ in 30PbO‐5Bi 2 O 3 ‐(65‐x)SiO 2 glasses at different concentrations0Critical role of dynamic structure on ion migration in H2V2O5 cathode material for rechargeable batteries1Theoretical Investigation on Local Structure Distortion of V 4+ ‐Doped DUT‐5(Al) via EPR Parameter Calculation0

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  1. Synthesis and Characterization of Non-centrosymmetric TeSeO4

    Inorganic Chemistry · 2001-02-10

    Yetta Porter, Nattamai S. P. Bhuvanesh, P. Shiv Halasyamani

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  2. Bi2TeO5: Synthesis, Structure, and Powder Second Harmonic Generation Properties

    Inorganic Chemistry · 2001-03-02

    Kang Min Ok, Nattamai S. P. Bhuvanesh, P. Shiv Halasyamani

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  3. Synthesis and Structural Characterization of a New Series of Vanadoselenites, [SexV4-xO12-x](4-x)- (x = 1, 2)

    Inorganic Chemistry · 2001-03-02

    H. Nakano, Tomoji Ozeki, A. Yagasaki

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  4. Synthesis and Characterization of Te2SeO7: A Powder Second-Harmonic-Generating Study of TeO2, Te2SeO7, Te2O5, and TeSeO4

    Chemistry of Materials · 2001-05-01

    Yetta Porter, Kang Min Ok, Nattamai S. P. Bhuvanesh, P. Shiv Halasyamani

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  5. Cd(VO2)4(SeO3)3·H2O: A New Bimetallic Vanadium Selenite Compound with Heptacoordinated Cadmium Ion

    Journal of Solid State Chemistry · 2001-10-01

    YongTae Kim, Yoon-Hyun Kim, Kyungsoo Park, Young‐Uk Kwon, Victor G. Young

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  6. SrZn(SeO3)2 Containing Novel ZnO4+2 Bicapped Tetrahedra

    Inorganic Chemistry · 2001-11-03

    Magnus G. Johnston, William T. A. Harrison

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  7. Some Smaller Polyoxoanions. Their Synthesis and Characterization in Solution

    Nanostructure science and technology · 2002-01-01

    Hiroyuki Nakano, Tomoji Ozeki, A. Yagasaki

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  8. Structural Modulation of Molybdenyl Iodate Architectures by Alkali Metal Cations in AMoO3(IO3) (A = K, Rb, Cs): A Facile Route to New Polar Materials with Large SHG Responses

    Journal of the American Chemical Society · 2002-02-08

    Richard E. Sykora, Kang Min Ok, P. Shiv Halasyamani, Thomas E. Albrecht‐Schmitt

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  9. Hydrothermal Syntheses, Structures, and Properties of the New Uranyl Selenites Ag2(UO2)(SeO3)2, M[(UO2)(HSeO3)(SeO3)] (M = K, Rb, Cs, Tl), and Pb(UO2)(SeO3)2

    Inorganic Chemistry · 2002-02-13

    Philip M. Almond, Thomas E. Albrecht‐Schmitt

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  10. First coordination complex-linked vanadium selenite, [Cu(phen)]2V2Se2O11: hydrothermal synthesis and crystal structure

    Journal of the Chemical Society Dalton Transactions · 2002-03-28

    Zhan Shi, Dong Zhang, Shouhua Feng, Guanghua Li, Zhimin Dai, Wensheng Fu, Xiaobo Chen, Jia Hua

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  11. Hydrothermal Preparation, Structures, and NLO Properties of the Rare Earth Molybdenyl Iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]

    Inorganic Chemistry · 2002-12-10

    Thomas C. Shehee, Richard E. Sykora, Kang Min Ok, P. Shiv Halasyamani, Thomas E. Albrecht‐Schmitt

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  12. Hydrothermal Syntheses and Crystal Structures of Complex-Linked Three-Dimensional Coordination Vanadium Selenites: M(4,4‘-bipy)(H2O)V2Se2O10 (M = Co, Ni)

    Inorganic Chemistry · 2003-01-11

    Zhimin Dai, Xiaobo Chen, Zhan Shi, Dong Zhang, Guanghua Li, Shouhua Feng

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  13. Hydrothermal syntheses and structures of two novel vanadium selenites, {[VO(OH)(H2O)](SeO3)}4·2H2O and (H3NCH2CH2NH3)[(VO)(SeO3)2]

    Journal of Solid State Chemistry · 2003-04-01

    Zhimin Dai, Zhan Shi, Guanghua Li, Xiaobo Chen, Xiaoying Lu, XU Yao-hua, Shouhua Feng

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  14. Salt-Inclusion Synthesis of Ba2MnSi2O7Cl. A Fresnoite-Type Polar Framework Containing the Acentric [Si2O7]6- Polyanion in the Anti-ReO3 Type [(Ba2Mn)Cl]6+ Cage

    Inorganic Chemistry · 2003-05-30

    Xunhua Mo, Shiou‐Jyh Hwu

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  15. New alkali–metal–molybdenum(VI)–selenium(IV) oxides: syntheses, structures, and characterization of A2SeMoO6 (A=Na+, K+, or Rb+)

    Journal of Solid State Chemistry · 2003-07-22

    Yetta Porter, P. Shiv Halasyamani

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  16. A new 2-D selenic vanadate network decorated by a coordination complex fragment: [Cu(phen)(H2O)2][V3Se3O14] · H2O

    Inorganic Chemistry Communications · 2003-07-31

    Gejihu De, Yangguang Li, Rudan Huang, Enbo Wang, Mei Yuan, Changwen Hu, Lin Xu

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  17. Organically templated zinc selenites: MIL-86 or [H2N(CH2)2NH2]2·Zn4(SeO3)4 and MIL-87 or [H3N(CH2)3NH3]4·Zn4(SeO3)8

    Solid State Sciences · 2004-02-01

    Franck Millange, Christian Serre, Tony Cabourdin, Jérôme Marrot, Gérard Férey

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  18. A novel vanadyl selenite templated by organic salt: [(VO)(H2O)2(SeO3)]2[(H2pipe)SO4]

    Journal of Chemical Crystallography · 2004-08-01

    Zhaoxun Lian, Chang‐Cang Huang, Han-Hui Zhang, Hongfang Yang, Yong Zhang, Xinfu Yang

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  19. Asymmetric Cation Coordination in Oxide Materials: Influence of Lone-Pair Cations on the Intra-octahedral Distortion in d0 Transition Metals

    Chemistry of Materials · 2004-08-13

    P. Shiv Halasyamani

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  20. Salt-Inclusion Synthesis of Two New Polar Solids, Ba6Mn4Si12O34Cl3 and Ba6Fe5Si11O34Cl3

    Inorganic Chemistry · 2005-04-06

    Xunhua Mo, Erin Ferguson, Shiou‐Jyh Hwu

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  21. Products and kinetics of non-isothermal decomposition of vanadium(IV) oxide compounds

    Journal of Thermal Analysis and Calorimetry · 2007-02-25

    Lyubomir T. Vlaev, Velyana G. Georgieva, Svetlana D. Genieva

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  22. catena-Poly[[(2,2′-bipyridyl)oxidovanadium]-di-μ2-oxido-[(2,2′-bipyridyl)oxidovanadium]-μ3-selenito-bis[(2,2′-bipyridyl)dioxidovanadium]-μ3-selenito]

    Acta Crystallographica Section C Crystal Structure Communications · 2007-10-24

    Zhao Lian, Ping Liu, Jia-Min Zhang, Tian-Xi Wang, Tian-Jun Lou

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  23. ZnVSe2O7 and Cd6V2Se5O21: New d10 Transition-Metal Selenites with V(IV) or V(V) Cations

    Inorganic Chemistry · 2008-06-24

    Hai-Long Jiang, Fang Kong, Yang Fan, Jiang‐Gao Mao

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  24. Explorations of new phases in the GaIII/InIII–MoVI–SeIV/TeIV–O systems

    Dalton Transactions · 2009-01-01

    Fang Kong, Chun‐Li Hu, Ting Hu, Yong Lian Zhou, Jiang‐Gao Mao

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  25. Explorations of new second-order NLO materials in the AgI-MoVI/WVI-TeIV-O systems

    Dalton Transactions · 2009-01-01

    Yong Lian Zhou, Chun‐Li Hu, Ting Hu, Fang Kong, Jiang‐Gao Mao

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  26. KMBP2O8 (M = Sr, Ba): A New Kind of Noncentrosymmetry Borophosphate with the Three-Dimensional Diamond-like Framework

    Inorganic Chemistry · 2009-06-09

    Dan Zhao, Wen‐Dan Cheng, Hao Zhang, Shuping Huang, Zhi Xie, Weilong Zhang, Song-Lin Yang

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  27. Syntheses, Crystal Structures, and Properties of Five New Transition Metal Molybdenum(VI) Selenites and Tellurites

    Inorganic Chemistry · 2009-11-17

    Suyun Zhang, Hai‐Long Jiang, Chuan‐Fu Sun, Jiang‐Gao Mao

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  28. Syntheses and Crystal Structures of a Series of Alkaline Earth Vanadium Selenites and Tellurites

    Inorganic Chemistry · 2010-11-23

    Suyun Zhang, Chun‐Li Hu, Chuan‐Fu Sun, Jiang‐Gao Mao

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  29. Synthesis and structure of A4V6[Te24+Te6+]O24 (A = K, Rb)—two new quaternary mixed-valent tellurium oxides

    Dalton Transactions · 2011-01-01

    Tianxiang Zhu, Jingui Qin, P. Shiv Halasyamani

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  30. [R-C7H16N2][V2Te2O10] and [S-C7H16N2][V2Te2O10]; new polar templated vanadium tellurite enantiomers

    Journal of Solid State Chemistry · 2011-04-20

    Ethan C. Glor, Samuel M. Blau, Jeongho Yeon, Mat­thias Zeller, P. Shiv Halasyamani, Joshua Schrier, Alexander J. Norquist

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  31. New Vanadium Selenites: Centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and Noncentrosymmetric and Polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+)

    Inorganic Chemistry · 2011-12-06

    Jeongho Yeon, Sang‐Hwan Kim, Sau Doan Nguyen, Hana Lee, P. Shiv Halasyamani

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  32. Synthesis, crystal structure and optical properties of Ba5V3O12F

    Journal of Molecular Structure · 2013-10-15

    Jing Kang, Yun Mo Yang, Shilie Pan, Hongwei Yu, Zhongxiang Zhou

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  33. A Barium Vanadium(v) Selenite Hydrate, Ba(VO2)2(SeO3)2·H2O: A Novel 3D Polymer of Cross-Linked Sheets with Embedded ···V–O–V··· 21 Helices*

    Australian Journal of Chemistry · 2014-09-17

    Kieryn L. Kilminster, Francis Lincoln, Brian W. Skelton, ALLAN HENRY WHITE

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  34. New vanadium tellurites: Syntheses, structures, optical properties of noncentrosymmetric VTeO 4 (OH), centrosymmetric Ba 2 V 4 O 8 (Te 3 O 10 )

    Journal of Solid State Chemistry · 2017-02-16

    Mingli Liang, Matthew L. Marsh, Xian-Xing Shang, Jiang‐Gao Mao, Thomas E. Albrecht‐Schmitt, Fang Kong

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  35. Theoretical study of the local structures and the EPR parameters for RLNKB glasses with VO2+ and Cu2+ dopants

    Journal of Physics and Chemistry of Solids · 2017-10-12

    Chang‐Chun Ding, Shao-Yi Wu, Li‐Na Wu, Lijuan Zhang, Peng Li, Minghe Wu, Baohua Teng

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  36. Theoretical study of local structures and EPR parameters for xV2O5-(100 − x)[0.8NaPO3-0.2ZnO]: V4+ glasses at different concentrations

    Journal of Non-Crystalline Solids · 2017-11-05

    Chang‐Chun Ding, Shao-Yi Wu, Peng Li, Li‐Na Wu, Zhihong Zhang, Qin-Sheng Zhu, Minghe Wu, Baohua Teng

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  37. Mild Synthesis and Structural Characterization of a Novel Vanadyl Selenite-Hydrogen Selenite Phase, Na[VO(SeO3)(HSeO3)]·1,5H2O

    Crystals · 2018-05-15

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  38. Evaluation of EPR parameters for compressed and elongated local structures of VO2+ and Cu2+ spin probes in BaO-TeO2-B2O3 glasses

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  39. Theoretical investigations on the EPR parameters and local structures for V4+ in alkali niobium borate glasses

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  40. An investigation of local structures and EPR spectra for Cu2+ and VO2+ in biochar

    Current Applied Physics · 2019-11-15

    Chang‐Chun Ding, Xiaohong Chu, Zhixiang Fan, Jia Fu

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  41. Selenite bromide nonlinear optical materials Pb 2 GaF 2 (SeO 3 ) 2 Br and Pb 2 NbO 2 (SeO 3 ) 2 Br: synthesis and characterization

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  42. Theoretical investigation on the EPR parameters for VO2+ doped ZnO–CdS nanocomposites

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  43. Theoretical investigations on the defect structures and g factors for W5+ in lead bismuth arsenate glasses

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  44. Studies on spin Hamiltonian parameters and local structures for v4+ in BaCl2-BaO-B2O3 glasses at various BaCl2 compositions

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  45. Influence of V2O5 on physical and spectral (optical, EPR & FTIR) studies of SrO-TeO2-TiO2-B2O3 glasses

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  46. Studies on the local structure and spin Hamiltonian parameters for V 4+ in Na 2 O–PbO–Bi 2 O 3 –SiO 2 glass ceramics

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  47. Synthesis, structure and catalytic study of a new sandwiched-type vanadoselenite

    Inorganic Chemistry Communications · 2020-12-18

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  48. Theoretical study of the local distortions and the EPR parameters for VO2+ and Cu2+ centers in oxyfluoroborate glasses

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    Y.D. Li, B. J. Chen, H. M. Zhang, Cuidi Feng

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  49. Relationship between the gyromagnetic anisotropy and tetragonal distortion for d1 ions in octahedral clusters

    Spectroscopy Letters · 2021-02-27

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  50. Theoretical analysis on lead halides content dependences of defect structures and spin Hamiltonian parameters in lead halo borate glass composites with V2O5 dopants

    Composites Part A Applied Science and Manufacturing · 2021-04-16

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