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RESEARCH PAPER · Chemical Society Reviews · 2007

Hybrid porous solids: past, present, future

Gérard Férey

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Hybrid porous solids: past, present, futureOriginalSize-Selective Lewis Acid Catalysis in a Microporous Metal-Organic Framework with Exposed Mn2+ Coordination Sites834Amine Grafting on Coordinatively Unsaturated Metal Centers of MOFs: Consequences for Catalysis and Metal Encapsulation1243A Luminescent Microporous Metal−Organic Framework for the Recognition and Sensing of Anions1014A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability7336A Luminescent Metal–Organic Framework with Lewis Basic Pyridyl Sites for the Sensing of Metal Ions1093Application of metal–organic frameworks with coordinatively unsaturated metal sites in storage and separation of methane and carbon dioxide689Industrial applications of metal–organic frameworks2341Infinite coordination polymer nano- and microparticle structures788Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences1654Magnetic metal–organic frameworks2448Polymerization reactions in porous coordination polymers646Postsynthetic modification of metal–organic frameworks1973Selective gas adsorption and separation in metal–organic frameworks8932Thin films of metal–organic frameworks893A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives1237Porous Chromium Terephthalate MIL‐101 with Coordinatively Unsaturated Sites: Surface Functionalization, Encapsulation, Sorption and Catalysis978Cation-Triggered Drug Release from a Porous Zinc−Adeninate Metal−Organic Framework1076Potential applications of metal-organic frameworks1659A New Photoactive Crystalline Highly Porous Titanium(IV) Dicarboxylate1440Lanthanide-Based Luminescent Hybrid Materials3349Molecular engineering for synthesizing novel structures of metal–organic frameworks with multifunctional properties679Metal–Organic Frameworks: Opportunities for Catalysis1888Multiferroic Behavior Associated with an Order−Disorder Hydrogen Bonding Transition in Metal−Organic Frameworks (MOFs) with the Perovskite ABX3 Architecture798Virtual High Throughput Screening Confirmed Experimentally: Porous Coordination Polymer Hydration1004Zeolitic Imidazolate Framework Membrane with Molecular Sieving Properties by Microwave-Assisted Solvothermal Synthesis1250Gas storage in porous metal–organic frameworks for clean energy applications1349Recent advances in crystal engineering746Soft porous crystals2436Molecular Sieve Membrane: Supported Metal–Organic Framework with High Hydrogen Selectivity645Screening of Metal−Organic Frameworks for Carbon Dioxide Capture from Flue Gas Using a Combined Experimental and Modeling Approach907Porous metal–organic-framework nanoscale carriers as a potential platform for drug delivery and imaging4260Isoreticular synthesis and modification of frameworks with the UiO-66 topology822MOFs, MILs and more: concepts, properties and applications for porous coordination networks (PCNs)1185Adsorptive removal of methyl orange from aqueous solution with metal-organic frameworks, porous chromium-benzenedicarboxylates695Exploitation of Intrinsic Microporosity in Polymer-Based Materials774Metal−Organic Frameworks as Sensors: A ZIF-8 Based Fabry−Pérot Device as a Selective Sensor for Chemical Vapors and Gases1082Surface nano-architecture of a metal–organic framework899Controlled Reducibility of a Metal–Organic Framework with Coordinatively Unsaturated Sites for Preferential Gas Sorption634Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials1426BioMOFs: Metal–Organic Frameworks for Biological and Medical Applications1250Carbon Dioxide Capture: Prospects for New Materials4033Water Stable Zr–Benzenedicarboxylate Metal–Organic Frameworks as Photocatalysts for Hydrogen Generation866Metal–Organic Frameworks from Edible Natural Products781Engineering Homochiral Metal‐Organic Frameworks for Heterogeneous Asymmetric Catalysis and Enantioselective Separation872De novo synthesis of a metal–organic framework material featuring ultrahigh surface area and gas storage capacities1741Adsorptive removal of methyl orange and methylene blue from aqueous solution with a metal-organic framework material, iron terephthalate (MOF-235)1159A High‐Performance Gas‐Separation Membrane Containing Submicrometer‐Sized Metal–Organic Framework Crystals678Postsynthetic modification of metal–organic frameworks—a progress report1173Tuning the Topology and Functionality of Metal−Organic Frameworks by Ligand Design1094Visualisation and characterisation of voids in crystalline materials646Why hybrid porous solids capture greenhouse gases?652Applications of advanced hybrid organic–inorganic nanomaterials: from laboratory to market1462Evaluating metal–organic frameworks for post-combustion carbon dioxide capture via temperature swing adsorption1072Mechanical properties of hybrid inorganic–organic framework materials: establishing fundamental structure–property relationships760MOF thin films: existing and future applications1395Porous metal–organic frameworks as platforms for functional applications859Role of solvents in coordination supramolecular systems665Underlying nets in three-periodic coordination polymers: topology, taxonomy and prediction from a computer-aided analysis of the Cambridge Structural Database709Synergistic Catalysis of Au@Ag Core−Shell Nanoparticles Stabilized on Metal−Organic Framework931Molecular decoding using luminescence from an entangled porous framework773Carbon dioxide capture-related gas adsorption and separation in metal-organic frameworks2019Disclosing the Complex Structure of UiO-66 Metal Organic Framework: A Synergic Combination of Experiment and Theory1919Solvatochromic Behavior of a Nanotubular Metal−Organic Framework for Sensing Small Molecules689New Microporous Metal−Organic Framework Demonstrating Unique Selectivity for Detection of High Explosives and Aromatic Compounds1137Controlling Zeolitic Imidazolate Framework Nano- and Microcrystal Formation: Insight into Crystal Growth by Time-Resolved In Situ Static Light Scattering916Opening the Gate: Framework Flexibility in ZIF-8 Explored by Experiments and Simulations1211Porous Organic Polymers in Catalysis: Opportunities and Challenges932Immobilization of MP-11 into a Mesoporous Metal–Organic Framework, MP-11@mesoMOF: A New Platform for Enzymatic Catalysis658Luminescent Functional Metal–Organic Frameworks5697A Microporous Hydrogen-Bonded Organic Framework for Highly Selective C 2 H 2 /C 2 H 4 Separation at Ambient Temperature812Ligand design for functional metal–organic frameworks855Light-Harvesting Metal–Organic Frameworks (MOFs): Efficient Strut-to-Strut Energy Transfer in Bodipy and Porphyrin-Based MOFs795Metal–Organic Frameworks for Separations6316Mesoporous metal–organic framework materials933Development and Evaluation of Porous Materials for Carbon Dioxide Separation and Capture1208Large-scale screening of hypothetical metal–organic frameworks1431Homochiral Metal–Organic Frameworks for Asymmetric Heterogeneous Catalysis2856Synthesis of Metal-Organic Frameworks (MOFs): Routes to Various MOF Topologies, Morphologies, and Composites5045Progress in adsorption-based CO 2 capture by metal–organic frameworks1339Metal–Organic Frameworks in Biomedicine4168Carbon Dioxide Capture in Metal–Organic Frameworks6408Catalysis by metal nanoparticles embedded on metal–organic frameworks1036Deep eutectic solvents: syntheses, properties and applications4879Metal organic frameworks for electrochemical applications870Methane storage in advanced porous materials812Commensurate Adsorption of Hydrocarbons and Alcohols in Microporous Metal Organic Frameworks1035Imparting functionality to a metal–organic framework material by controlled nanoparticle encapsulation2148Metal–Organic Frameworks for Analytical Chemistry: From Sample Collection to Chromatographic Separation674Hydrothermal synthesis of zeolitic imidazolate framework-67 (ZIF-67) nanocrystals848Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?1958Dynamic magnetic MOFs618Adsorptive removal of hazardous materials using metal-organic frameworks (MOFs): A review1398A review of potential materials for thermal energy storage in building applications643A facile synthesis of UiO-66, UiO-67 and their derivatives1756Spin state switching in iron coordination compounds755Reactivity of Surface Species in Heterogeneous Catalysts Probed by In Situ X-ray Absorption Techniques643X-ray analysis on the nanogram to microgram scale using porous complexes885Separation of Hexane Isomers in a Metal-Organic Framework with Triangular Channels710Unusual and Highly Tunable Missing-Linker Defects in Zirconium Metal–Organic Framework UiO-66 and Their Important Effects on Gas Adsorption1457Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework1008Methane Storage in Metal–Organic Frameworks: Current Records, Surprise Findings, and Challenges1018Studies on Photocatalytic CO 2 Reduction over NH 2 ‐Uio‐66(Zr) and Its Derivatives: Towards a Better Understanding of Photocatalysis on Metal–Organic Frameworks667Evaluating metal–organic frameworks for natural gas storage1239Lanthanide metal-organic frameworks for luminescent sensing and light-emitting applications1135Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices1233Functional materials derived from open framework templates/precursors: synthesis and applications687Metal–organic frameworks based on flexible ligands (FL-MOFs): structures and applications874Metal–organic frameworks: a new promising class of materials for a high performance supercapacitor electrode635Tuning the structure and function of metal–organic frameworks via linker design2252Core–Shell Palladium Nanoparticle@Metal–Organic Frameworks as Multifunctional Catalysts for Cascade Reactions685Organic Thermoelectric Materials: Emerging Green Energy Materials Converting Heat to Electricity Directly and Efficiently999Beyond post-synthesis modification: evolution of metal–organic frameworks via building block replacement877Two-Dimensional Metal–Organic Framework with Wide Channels and Responsive Turn-On Fluorescence for the Chemical Sensing of Volatile Organic Compounds657Tuned to Perfection: Ironing Out the Defects in Metal–Organic Framework UiO-66845A supermolecular building approach for the design and construction of metal–organic frameworks827Understanding TiO 2 Photocatalysis: Mechanisms and Materials5992Removal of hazardous organics from water using metal-organic frameworks (MOFs): Plausible mechanisms for selective adsorptions1428Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties773Metal–organic framework nanosheets in polymer composite materials for gas separation2136Facile synthesis of amino-functionalized titanium metal-organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction745Multifunctional metal–organic frameworks: from academia to industrial applications1003Basic concepts and recent advances in nitrophenol reduction by gold- and other transition metal nanoparticles827MIL-53(Fe) as a highly efficient bifunctional photocatalyst for the simultaneous reduction of Cr(VI) and oxidation of dyes690Highly Water-Stable Zirconium Metal–Organic Framework UiO-66 Membranes Supported on Alumina Hollow Fibers for Desalination802Metal–organic frameworks for energy storage: Batteries and supercapacitors1298MOF Crystal Chemistry Paving the Way to Gas Storage Needs: Aluminum-Based soc -MOF for CH4, O2, and CO2 Storage839Chemical, thermal and mechanical stabilities of metal–organic frameworks2204Co@Co 3 O 4 Encapsulated in Carbon Nanotube‐Grafted Nitrogen‐Doped Carbon Polyhedra as an Advanced Bifunctional Oxygen Electrode1139Metal–Organic Framework (MOF) Compounds: Photocatalysts for Redox Reactions and Solar Fuel Production1109A metal-organic framework–based splitter for separating propylene from propane1193Proton-conducting crystalline porous materials697An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors1210Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship1324Hybridization of MOFs and polymers927Metal‐Organic Framework Nanoparticles in Photodynamic Therapy: Current Status and Perspectives622Development of a Cambridge Structural Database Subset: A Collection of Metal–Organic Frameworks for Past, Present, and Future1082Recent Advances in Ultrathin Two-Dimensional Nanomaterials5100Complex Nanostructures from Materials based on Metal–Organic Frameworks for Electrochemical Energy Storage and Conversion733The application of ZIF-67 and its derivatives: adsorption, separation, electrochemistry and catalysts725Catalysis and photocatalysis by metal organic frameworks1505Metal–organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions1856In Situ, Time-Resolved, and Mechanistic Studies of Metal–Organic Framework Nucleation and Growth610Metal–Organic Framework Nanoparticles833Catalysis by Metal Organic Frameworks: Perspective and Suggestions for Future Research932A review on production of metal organic frameworks (MOF) for CO2 adsorption723Emerging trends in porous materials for CO 2 capture and conversion843Water and Metal–Organic Frameworks: From Interaction toward Utilization614Post-combustion carbon capture652Two-Dimensional Metal-Organic Framework Materials: Synthesis, Structures, Properties and Applications928Adsorption of Carbon Dioxide for Post-combustion Capture: A Review651

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