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RESEARCH PAPER · Studies in surface science and catalysis · 2007

Metal-organic frameworks: the young child of the porous solids family

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Metal-organic frameworks: the young child of the porous solids familyOriginalCurly–curly, loop–loop: homoleptic metal(ii) complexes of pyridinecarbaldehyde 4′-(2,2′:6′,2″-terpyridyl)hydrazones and their coordination polymers20Synthesis and characterization of metal-benzene-tricarboxylate oxidation catalysts1Metal–organic framework MOF-5 prepared by microwave heating: Factors to be considered362How Far is the Concept of Isolated Active Sites Valid in Solid Catalysts?13Comparison of Activity and Selectivity of SSZ-33 Based Catalyst with other Zeolites in Toluene Disproportionation26Metal–organic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes117Selective gas adsorption and separation in metal–organic frameworks8932A New Family of Bimetallic Framework Materials Showing Reversible Structural Transformations7Transformation of a Chiral Nanoporous Bimetallic Cyano-Bridged Framework Triggered by Dehydration/Rehydration22Hydrothermal chemistry of vanadium oxides with aromatic di- and tri-phosphonates in the presence of secondary metal copper(II) cationic complex subunits47Solvothermal and Reflux Syntheses, Crystal Structure and Properties of Lanthanide-Thiophenedicarboxylate-Based Metal-Organic Frameworks18A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel { Mo 4 O 10 ( O 3 PR ) 4 } n 4 n - chains18Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco)162Coordination polymers of Cu(II) and Cd(II) with bifunctional chelates of the type dipicolylamino-alkylcarboxylate, (NC5H4CH2)2N(CH2) CO2H (n = 1, 2, 3 and 4)14Molecular, Electronic, and Crystal Structures of Self-Assembled Hydrothermally Synthesized Zn(II)−Mercaptonicotinate: A Combined Spectroscopic and Theoretical Approach15New Chiral and Flexible Metal−Organic Framework with a Bifunctional Spiro Linker and Zn4O-Nodes52The Fascinating Structure and the Potential of Metal–Organic Frameworks2A Highly Porous Metal–Organic Framework with Open Nickel Sites167Eine hochporöse Metall‐organische Gerüstverbindung mit zugänglichen Nickelzentren31Application of a chiral metal–organic framework in enantioselective separation168Chiral Metal‐Organic Frameworks and Their Application in Asymmetric Catalysis and Stereoselective Separation151Syntheses, structural characterization and properties of transition metal complexes of 5,5′-(1,4-phenylene)bis(1H-tetrazole) (H2bdt), 5′,5′′-(1,1′-biphenyl)-4,4′-diylbis(1H-tetrazole) (H2dbdt) and 5,5′,5′′-(1,3,5-phenylene)tris(1H-tetrazole) (H3btt)48A Family of Chiral Metal–Organic Frameworks133Solvothermal Synthesis, Structure, and Properties of Metal Organic Framework Isomers Derived from a Partially Fluorinated Link133Synthesis and characterization of a microporous copper triazolate as a water vapor adsorbent9High-Pressure in Situ 129Xe NMR Spectroscopy and Computer Simulations of Breathing Transitions in the Metal–Organic Framework Ni2(2,6-ndc)2(dabco) (DUT-8(Ni))131Novel metal-organic 1-D сoordination polymer based on pyrazine-2,5-dicarboxylate ligands: synthesis and structure investigation15A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks6Flexible and Hydrophobic Zn-Based Metal–Organic Framework77Porous zinc(II)-organic framework with potential open metal sites: Synthesis, structure and property14Binding energy of gas molecule with two pyrazine molecules as organic linker in metal–organic framework: its theoretical evaluation and understanding of determining factors11Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents40Bulk Hydrodesulfurization Catalyst Obtained by Mo(CO)6 Grafting on the Metal–Organic Framework Ni2(2,5-dihydroxoterephthalate)242-Butyne-1,4-diol hydrogenation over palladium supported on Zn2+-based – MOF and host–guest MOF/calix[4]arene materials42Hydrothermal synthesis and structures of materials of the M(II)/tetrazole/sulfate family (M(II)=Co, Ni; tetrazole=3- and 4-pyridyltetrazole and pyrazinetetrazole)21Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)170Methanol mediated crystal transformations in a solvatochromic metal organic framework constructed from Co(ii) and 4-(4-pyridyl) benzoate29Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands13Nanoparticle assemblies: main synthesis pathways and brief overview on some important applications51Synthesis and Structural Characterization of a Series of Novel Zn(II)-based MOFs with Pyridine-2,5-dicarboxylate Linkers41Hybrid Materials Based on the Embedding of Organically Modified Transition Metal Oxoclusters or Polyoxometalates into Polymers for Functional Applications: A Review113Anion-Exchange and Anthracene-Encapsulation within Copper(II) and Manganese(II)-Triazole Metal–Organic Confined Space in a Single Crystal-to-Single Crystal Transformation Fashion48In situ synthesis of novel ZIF-8 membranes on polymeric and inorganic supports66Sustainable and Very-Low-Temperature Wet-Chemistry Routes for the Synthesis of Crystalline Inorganic Nanostructures3Pursuing the Crystallization of Mono- and Polymetallic Nanosized Crystalline Inorganic Compounds by Low-Temperature Wet-Chemistry and Colloidal Routes80Synthesis and Characterizations of Two New Coordination Polymers Constructed from 1,1′-Binaphthyl Dicarboxylic Acid Derivatives with Cobalt(II) and Copper(II)2Metal-Organic Frameworks and Related Materials6Four novel metal–organic frameworks based on 3,4,7,8-tetramethyl-1,10-phenanthroline: Syntheses, structures, and thermal properties1Composites of Carbonaceous Materials and Metal-organic Frameworks0Enhanced hydrophobic MIL(Cr) metal-organic framework with high capacity and selectivity for benzene VOCs capture from high humid air154CO2 sorption behavior of imidazole, benzimidazole and benzoic acid based coordination polymers73Application of the Metal–Organic Framework [Eu(BTC)] as a Luminescent Marker for Gunshot Residues: A Synthesis, Characterization, and Toxicity Study64Surface polarity estimation of metal-organic frameworks using liquid-phase mixture adsorption8DABCO molecule in the M2(C8H4O4)2·C6H12N2 (M = Co, Ni, Cu, Zn) metal-organic frameworks29Conditions for the Formation of Microporous Metal–Organic Framework Mil-53(Al)6MOF materials as therapeutic agents, drug carriers, imaging agents and biosensors in cancer biomedicine: Recent advances and perspectives220Preparation, characterization, and toxicity assessment of carfilzomib-loaded nickel-based metal-organic framework: Evidence from in-vivo and in-vitro experiments21Metal Organic Frameworks: Current State and Analysis of Their Use as Modifiers of the Vulcanization Process and Properties of Rubber6Elaboration and properties of nanostructured Layered Double Hydroxides derived from MOFs conversion0Metal-organic frameworks: Biosensor applications for diagnosis of cancers6Impact of transition metals (M=Mn, Fe, Co, Ni, Cu, Zn) on the formation of local and crystal structure of MBTC phases3Metal–organic frameworks for high-efficiency solid-state hydrogen storage: Design, synthesis, regulation, and prospects3

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  1. Curly–curly, loop–loop: homoleptic metal(ii) complexes of pyridinecarbaldehyde 4′-(2,2′:6′,2″-terpyridyl)hydrazones and their coordination polymers

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  2. Synthesis and characterization of metal-benzene-tricarboxylate oxidation catalysts

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  3. Metal–organic framework MOF-5 prepared by microwave heating: Factors to be considered

    Microporous and Mesoporous Materials · 2008-05-26

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  4. How Far is the Concept of Isolated Active Sites Valid in Solid Catalysts?

    Topics in Catalysis · 2008-09-22

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  5. Comparison of Activity and Selectivity of SSZ-33 Based Catalyst with other Zeolites in Toluene Disproportionation

    Topics in Catalysis · 2008-12-22

    Sulaiman S. Al‐Khattaf, Zuzana Musilová-Pavlačková, Mohammed Ashraf Ali, Jiřı́ Čejka

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  6. Metal–organic frameworks as high-potential adsorbents for liquid-phase separations of olefins, alkylnaphthalenes and dichlorobenzenes

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  7. Selective gas adsorption and separation in metal–organic frameworks

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  8. A New Family of Bimetallic Framework Materials Showing Reversible Structural Transformations

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  9. Transformation of a Chiral Nanoporous Bimetallic Cyano-Bridged Framework Triggered by Dehydration/Rehydration

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  10. Hydrothermal chemistry of vanadium oxides with aromatic di- and tri-phosphonates in the presence of secondary metal copper(II) cationic complex subunits

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  11. Solvothermal and Reflux Syntheses, Crystal Structure and Properties of Lanthanide-Thiophenedicarboxylate-Based Metal-Organic Frameworks

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  12. A bimetallic oxide framework, [{Cu(bpy)}2Mo4O10(O3PCH2C6H4CH2PO3)2], constructed from novel { Mo 4 O 10 ( O 3 PR ) 4 } n 4 n - chains

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  13. Monitoring adsorption-induced switching by 129Xe NMR spectroscopy in a new metal–organic framework Ni2(2,6-ndc)2(dabco)

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  14. Coordination polymers of Cu(II) and Cd(II) with bifunctional chelates of the type dipicolylamino-alkylcarboxylate, (NC5H4CH2)2N(CH2) CO2H (n = 1, 2, 3 and 4)

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  15. Molecular, Electronic, and Crystal Structures of Self-Assembled Hydrothermally Synthesized Zn(II)−Mercaptonicotinate: A Combined Spectroscopic and Theoretical Approach

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  16. New Chiral and Flexible Metal−Organic Framework with a Bifunctional Spiro Linker and Zn4O-Nodes

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  17. The Fascinating Structure and the Potential of Metal–Organic Frameworks

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  18. A Highly Porous Metal–Organic Framework with Open Nickel Sites

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  19. Eine hochporöse Metall‐organische Gerüstverbindung mit zugänglichen Nickelzentren

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  20. Application of a chiral metal–organic framework in enantioselective separation

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  21. Chiral Metal‐Organic Frameworks and Their Application in Asymmetric Catalysis and Stereoselective Separation

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  22. Syntheses, structural characterization and properties of transition metal complexes of 5,5′-(1,4-phenylene)bis(1H-tetrazole) (H2bdt), 5′,5′′-(1,1′-biphenyl)-4,4′-diylbis(1H-tetrazole) (H2dbdt) and 5,5′,5′′-(1,3,5-phenylene)tris(1H-tetrazole) (H3btt)

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  23. A Family of Chiral Metal–Organic Frameworks

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  24. Solvothermal Synthesis, Structure, and Properties of Metal Organic Framework Isomers Derived from a Partially Fluorinated Link

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  26. High-Pressure in Situ 129Xe NMR Spectroscopy and Computer Simulations of Breathing Transitions in the Metal–Organic Framework Ni2(2,6-ndc)2(dabco) (DUT-8(Ni))

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  28. A bimetallic oxide network constructed from oxomolybdoarsonate clusters and copper(II)-tetrapyridylpyrazine building blocks

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  30. Porous zinc(II)-organic framework with potential open metal sites: Synthesis, structure and property

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  31. Binding energy of gas molecule with two pyrazine molecules as organic linker in metal–organic framework: its theoretical evaluation and understanding of determining factors

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  32. Chiral recognition in metal–organic frameworks studied by solid-state NMR spectroscopy using chiral solvating agents

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  33. Bulk Hydrodesulfurization Catalyst Obtained by Mo(CO)6 Grafting on the Metal–Organic Framework Ni2(2,5-dihydroxoterephthalate)

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  34. 2-Butyne-1,4-diol hydrogenation over palladium supported on Zn2+-based – MOF and host–guest MOF/calix[4]arene materials

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  35. Hydrothermal synthesis and structures of materials of the M(II)/tetrazole/sulfate family (M(II)=Co, Ni; tetrazole=3- and 4-pyridyltetrazole and pyrazinetetrazole)

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  36. Solid-State NMR Spectroscopy of Metal–Organic Framework Compounds (MOFs)

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  37. Methanol mediated crystal transformations in a solvatochromic metal organic framework constructed from Co(ii) and 4-(4-pyridyl) benzoate

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  38. Hydrothermal syntheses and structural chemistry of Mn(II), Co(II) and Ni(II) coordination polymers with xylyl-diphosphonate ligands

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  39. Nanoparticle assemblies: main synthesis pathways and brief overview on some important applications

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  40. Synthesis and Structural Characterization of a Series of Novel Zn(II)-based MOFs with Pyridine-2,5-dicarboxylate Linkers

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  41. Hybrid Materials Based on the Embedding of Organically Modified Transition Metal Oxoclusters or Polyoxometalates into Polymers for Functional Applications: A Review

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  42. Anion-Exchange and Anthracene-Encapsulation within Copper(II) and Manganese(II)-Triazole Metal–Organic Confined Space in a Single Crystal-to-Single Crystal Transformation Fashion

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  47. Metal-Organic Frameworks and Related Materials

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  49. Composites of Carbonaceous Materials and Metal-organic Frameworks

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  50. Enhanced hydrophobic MIL(Cr) metal-organic framework with high capacity and selectivity for benzene VOCs capture from high humid air

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