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RESEARCH PAPER · Dalton Transactions · 2015

Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinides

Yanlong Wang, Yuxiang Li, Zhuanling Bai, Chengliang Xiao, Zhiyong Liu, Wei Liu, Lanhua Chen, Weiwei He, Juan Diwu, Zhifang Chai, Thomas E. Albrecht‐Schmitt, Shuao Wang

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Design and synthesis of a chiral uranium-based microporous metal organic framework with high SHG efficiency and sequestration potential for low-valent actinidesOriginalTwo actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs14Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species93Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands39An initial demonstration of hierarchically porous niobium alkylphosphonates coordination polymers as potent radioanalytical separation materials12Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters16Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline14A hydrolytically stable uranyl organic framework for highly sensitive and selective detection of Fe 3+ in aqueous media70Actinide-based MOFs: a middle ground in solution and solid-state structural motifs110Metal–organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions1856Photonic functional metal–organic frameworks661Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride4Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective123Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation23Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework32Structural Tuning and Sensitization of Uranyl Phosphonates by Incorporation of Countercations into the Framework16An untethered C 3v -symmetric triarylphosphine oxide locked by intermolecular hydrogen bonding7Removal of toxic/radioactive metal ions by metal-organic framework-based materials20Uranyl Compounds Involving a Weakly Bonded Pseudorotaxane Linker: Combined Effect of pH and Competing Ligands on Uranyl Coordination and Speciation33Hydrothermal synthesis of two 2D uranyl coordination polymers: structure, luminescence, and photocatalytic degradation of rhodamine B16Selective Th( iv ) capture from a new metal–organic framework with O − groups26Magnetic metal organic frameworks/graphene oxide adsorbent for the removal of U(VI) from aqueous solution37Insights into the Structural Chemistry of Anhydrous and Hydrous Hexavalent Uranium and Neptunium Dinitrato, Trinitrato, and Tetranitrato Complexes16Metal-organic frameworks as a versatile platform for radionuclide management163Variability of Uranyl Carboxylates from Rigid Terophenyldicarboxylic Acid Ligands17Two 2D uranyl coordination complexes showing effective photocatalytic degradation of Rhodamine B and mechanism study25Actinyl-Carboxylate Complexes [AnO2(COOH) n (H2O) m ]2– n (An = U, Np, Pu, and Am; n = 1–3; m = 0, 2, 4; 2 n + m = 6): Electronic Structures, Interaction Features, and the Potential to Adsorbents toward Cs Ion2The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity17Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks65Temperature‐Triggered Structural Dynamics of Non‐Coordinating Guest Moieties in a Fluorescent Actinide Polyrotaxane Framework10An Azobenzene-Modified Photoresponsive Thorium–Organic Framework: Monitoring and Quantitative Analysis of Reversible trans–cis Photoisomerization30Chiral metal–organic frameworks based on asymmetric synthetic strategies and applications107Proximity Effect in Uranyl Coordination of the Cucurbit[6]uril-Bipyridinium Pseudorotaxane Ligand for Promoting Host–Guest Synergistic Chelating11An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application145Metal-organic frameworks as superior porous adsorbents for radionuclide sequestration: Current status and perspectives52High-performance removal of radionuclides by porous organic frameworks from the aquatic environment: A review50State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization20Lanthanide–uranyl phosphonates constructed from diethyl ((phenylsulfonyl)methyl)phosphonate4Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies10Impact of the proximity effect on uranyl coordination of conformationally variable weakly-bonded cucurbit[6]uril-bipyridinium pseudorotaxane2Two-dimensional metal–organic layers constructed from Hf 6 /Hf 12 -oxo clusters and a trigonal pyramidal phosphine oxide ligand6ZIF-90: PSM Assisted Acid Resistance, Accelerated Sequestration and Selective Sensing of Actinides16Microporous metal–organic frameworks: Synthesis and applications83Progress in solid state and coordination chemistry of actinides in China5f‐block MOFs: A Pathway to Heterometallic Transuranics29f‐block MOFs: A Pathway to Heterometallic Transuranics1Advanced porous adsorbents for radionuclides elimination207Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy21Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy0Structural variation in Uranyl-Phosphonate networks utilizing tetrahedral Silicon-Centered phosphonate linkers2Synthesis and Characterization of Uranyl Complexes Containing Orotate and Isoorotate0Synthesis and characterization of uranyl complexes containing orotate and isoorotate3Tripodal Tricarboxylic Acids on the Triphenylphosphine Oxide Platform0Harnessing Advanced Porous Materials, Covalent Organic Frameworks, and Porous Organic Polymers as Next-Generation Porous Frameworks for Targeted Removal of Emerging Water Contaminants59Highlighting the Advancement of Nuclear Waste Water Treatment with Modular Porous Scaffolds15A uranyl carboxyphosphonate framework exhibiting luminescence intensity, luminescence lifetime and SHG triple-response2Metal–organic framework-based second-order nonlinear optical materials: From structural design to functional applications0Uranyl-organic framework: From structure design to cutting-edge applications1

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  1. Two actinide-organic frameworks constructed by a tripodal flexible ligand: Occurrence of infinite {(UO2)O2(OH)3}4n and hexanuclear {Th6O4(OH)4} motifs

    Journal of Solid State Chemistry · 2016-07-28

    Lingling Liang, Ronglan Zhang, Jianshe Zhao, Chiyang Liu, Ng Seik Weng

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  2. Recent advances in structural studies of heterometallic uranyl-containing coordination polymers and polynuclear closed species

    Dalton Transactions · 2017-01-01

    P. Thuéry, Jack McB. Harrowfield

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  3. Construction of Uranyl Organic Hybrids by Phosphonate and in Situ Generated Carboxyphosphonate Ligands

    Inorganic Chemistry · 2017-01-24

    Chao Liu, Weiting Yang, Ning Song Qu, Lei‐Jiao Li, Qing‐Jiang Pan, Zhong‐Ming Sun

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  4. An initial demonstration of hierarchically porous niobium alkylphosphonates coordination polymers as potent radioanalytical separation materials

    Journal of Chromatography A · 2017-05-08

    Kai Lv, Chu‐Ting Yang, Jun Han, Sheng Hu, Xiao-Lin Wang

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  5. Network Dimensionality of Selected Uranyl(VI) Coordination Polymers and Octopus-like Uranium(IV) Clusters

    Crystal Growth & Design · 2017-08-31

    Ralph A. Zehnder, James M. Boncella, Justin N. Cross, Stosh A. Kozimor, Marisa J. Monreal, Henry S. La Pierre, Brian L. Scott, Aaron M. Tondreau, Mat­thias Zeller

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  6. Two new uranyl complexes as visible light driven photocatalysts for degradation of tetracycline

    Polyhedron · 2017-10-14

    Ya-Nan Ren, Wei Xu, Lin-Xia Zhou, Yue‐Qing Zheng

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  7. A hydrolytically stable uranyl organic framework for highly sensitive and selective detection of Fe 3+ in aqueous media

    Dalton Transactions · 2017-11-28

    Wei Liu, Jian Xie, Linmeng Zhang, Mark A. Silver, Shuao Wang

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  8. Actinide-based MOFs: a middle ground in solution and solid-state structural motifs

    Chemical Communications · 2018-01-01

    Ekaterina A. Dolgopolova, Allison M. Rice, Natalia B. Shustova

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  9. Metal–organic framework-based materials: superior adsorbents for the capture of toxic and radioactive metal ions

    Chemical Society Reviews · 2018-01-01

    Jie Li, Xiangxue Wang, Xiangxue Wang, Guixia Zhao, Changlun Chen, Zhifang Chai, Ahmed Alsaedi, Tasawar Hayat, Xiangke Wang, Xiangke Wang

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  10. Photonic functional metal–organic frameworks

    Chemical Society Reviews · 2018-01-01

    Yuanjing Cui, Jun Zhang, Huajun He, Guodong Qian

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  11. Synthesis and crystal structures of two new uranyl coordination compounds obtained in aqueous solutions of 1-butyl-2,3-dimethylimidazolium chloride

    Journal of Coordination Chemistry · 2018-05-18

    Fangyuan Wang, Lei Mei, Wei‐Qun Shi, Taiwei Chu

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  12. Hierarchical Materials as Tailored Nuclear Waste Forms: A Perspective

    Chemistry of Materials · 2018-06-22

    Hans‐Conrad zur Loye, Theodore M. Besmann, Jake Amoroso, Kyle S. Brinkman, Agnès Grandjean, Charles H. Henager, Shenyang Hu, Scott T. Misture, Simon Robert Phillpot, Natalia B. Shustova, Hui Wang, Robert J. Koch, Gregory W. Morrison, Ekaterina A. Dolgopolova

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  13. Large-Pore Layered Networks, Polycatenated Frameworks, and Three-Dimensional Frameworks of Uranyl Tri(biphenyl)amine/Tri(phenyl)amine Tricarboxylate: Solvent-/Ligand-Dependent Dual Regulation

    Crystal Growth & Design · 2018-06-26

    Shuai Wang, Lei Mei, Jipan Yu, Kong‐Qiu Hu, Zhirong Liu, Zhifang Chai, Wei‐Qun Shi

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  14. Guest-Dependent Single-Crystal-to-Single-Crystal Phase Transitions in a Two-Dimensional Uranyl-Based Metal–Organic Framework

    Crystal Growth & Design · 2018-12-20

    Sylvia L. Hanna, Xuan Zhang, Ken‐ichi Otake, Riki J. Drout, Peng Li, Timur İslamoğlu, Omar K. Farha

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  15. Structural Tuning and Sensitization of Uranyl Phosphonates by Incorporation of Countercations into the Framework

    Inorganic Chemistry · 2018-12-27

    Si‐Fu Tang, Xiaomin Hou

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  16. An untethered C 3v -symmetric triarylphosphine oxide locked by intermolecular hydrogen bonding

    Chemical Communications · 2019-01-01

    Timothy G. Carroll, Camden Hunt, Rachel Garwick, Guang Xin Wu, Roman Dobrovetsky, Gabriel Ménard

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  17. Removal of toxic/radioactive metal ions by metal-organic framework-based materials

    Interface science and technology · 2019-01-01

    Jie Li, Wenling Ye, Changlun Chen

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  18. Uranyl Compounds Involving a Weakly Bonded Pseudorotaxane Linker: Combined Effect of pH and Competing Ligands on Uranyl Coordination and Speciation

    Inorganic Chemistry · 2019-02-11

    Li Fei, Lei Mei, Kong‐Qiu Hu, Shu‐wen An, Si Wu, Ning Liu, Zhifang Chai, Wei‐Qun Shi

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  19. Hydrothermal synthesis of two 2D uranyl coordination polymers: structure, luminescence, and photocatalytic degradation of rhodamine B

    CrystEngComm · 2020-01-01

    Xiao‐Lan Tong, Shan Wang, HongXia Gao, Yingchong Ge, Jun Qing Zuo, Fen Liu, Jianhua Ding, Jian‐Bo Xiong

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  20. Selective Th( iv ) capture from a new metal–organic framework with O − groups

    Dalton Transactions · 2020-01-01

    Xiang‐Guang Guo, Jia Su, Wenqi Xie, Shuainan Ni, Yun Gao, Xiang Su, Xiaoqi Sun

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  21. Magnetic metal organic frameworks/graphene oxide adsorbent for the removal of U(VI) from aqueous solution

    Applied Radiation and Isotopes · 2020-04-02

    Zheng Wang, Donglin Zhao, Changnian Wu, Shaohua Chen, Yangyang Wang, Changlun Chen

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  22. Insights into the Structural Chemistry of Anhydrous and Hydrous Hexavalent Uranium and Neptunium Dinitrato, Trinitrato, and Tetranitrato Complexes

    Inorganic Chemistry · 2020-05-06

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  23. Metal-organic frameworks as a versatile platform for radionuclide management

    Coordination Chemistry Reviews · 2020-09-15

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  24. Variability of Uranyl Carboxylates from Rigid Terophenyldicarboxylic Acid Ligands

    Inorganic Chemistry · 2020-10-22

    Xiaomin Hou, Si‐Fu Tang

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  25. Two 2D uranyl coordination complexes showing effective photocatalytic degradation of Rhodamine B and mechanism study

    Chinese Chemical Letters · 2020-11-30

    Xiao‐Lan Tong, Shan Wang, Jun Qing Zuo, Yingchong Ge, Qiang Gao, Sui‐Jun Liu, Jianhua Ding, Fen Liu, Jianqiang Luo, Jian‐Bo Xiong

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  26. Actinyl-Carboxylate Complexes [AnO2(COOH) n (H2O) m ]2– n (An = U, Np, Pu, and Am; n = 1–3; m = 0, 2, 4; 2 n + m = 6): Electronic Structures, Interaction Features, and the Potential to Adsorbents toward Cs Ion

    ACS Omega · 2020-12-03

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  27. The first actinide polyiodate: a complex multifunctional compound with promising X-ray luminescence properties and proton conductivity

    Chemical Communications · 2020-12-17

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  28. Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

    Chemical Science · 2021-01-01

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  29. Temperature‐Triggered Structural Dynamics of Non‐Coordinating Guest Moieties in a Fluorescent Actinide Polyrotaxane Framework

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  30. An Azobenzene-Modified Photoresponsive Thorium–Organic Framework: Monitoring and Quantitative Analysis of Reversible trans–cis Photoisomerization

    Inorganic Chemistry · 2021-06-07

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  31. Chiral metal–organic frameworks based on asymmetric synthetic strategies and applications

    Coordination Chemistry Reviews · 2021-06-28

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  32. Proximity Effect in Uranyl Coordination of the Cucurbit[6]uril-Bipyridinium Pseudorotaxane Ligand for Promoting Host–Guest Synergistic Chelating

    Inorganic Chemistry · 2021-07-02

    Feize Li, Jun‐shan Geng, Kong‐Qiu Hu, Jipan Yu, Ning Liu, Zhifang Chai, Lei Mei, Wei‐Qun Shi

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  33. An updated status and trends in actinide metal-organic frameworks (An-MOFs): From synthesis to application

    Coordination Chemistry Reviews · 2021-07-07

    Kai Lv, Sebastian Fichter, Mei Gu, Juliane März, Moritz Schmidt

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  34. Metal-organic frameworks as superior porous adsorbents for radionuclide sequestration: Current status and perspectives

    Journal of Chromatography A · 2021-08-25

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  35. High-performance removal of radionuclides by porous organic frameworks from the aquatic environment: A review

    Journal of Environmental Radioactivity · 2021-09-01

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  36. State-of-the-art progress for the selective crystallization of actinides, synthesis of actinide compounds and their functionalization

    Journal of Hazardous Materials · 2021-11-25

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  37. Lanthanide–uranyl phosphonates constructed from diethyl ((phenylsulfonyl)methyl)phosphonate

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  38. Advances and perspectives of actinide chemistry from ex situ high pressure and high temperature chemical studies

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  39. Impact of the proximity effect on uranyl coordination of conformationally variable weakly-bonded cucurbit[6]uril-bipyridinium pseudorotaxane

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  40. Two-dimensional metal–organic layers constructed from Hf 6 /Hf 12 -oxo clusters and a trigonal pyramidal phosphine oxide ligand

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  41. ZIF-90: PSM Assisted Acid Resistance, Accelerated Sequestration and Selective Sensing of Actinides

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  42. Microporous metal–organic frameworks: Synthesis and applications

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  43. Progress in solid state and coordination chemistry of actinides in China

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  44. f‐block MOFs: A Pathway to Heterometallic Transuranics

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  45. f‐block MOFs: A Pathway to Heterometallic Transuranics

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  46. Advanced porous adsorbents for radionuclides elimination

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  47. Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy

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  48. Assembling a Heterobimetallic Actinide Metal‐Organic Framework by a Reaction‐Induced Preorganization Strategy

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  49. Structural variation in Uranyl-Phosphonate networks utilizing tetrahedral Silicon-Centered phosphonate linkers

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  50. Synthesis and Characterization of Uranyl Complexes Containing Orotate and Isoorotate

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