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RESEARCH PAPER · European Journal of Inorganic Chemistry · 2015

A Series of Noncentrosymmetric Antimony Sulfides Ln8Sb2S15 (Ln = La, Pr, Nd) – Syntheses, Crystal and Electronic Structures, and NLO Properties

Hua‐Jun Zhao, Liujiang Zhou

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A Series of Noncentrosymmetric Antimony Sulfides Ln8Sb2S15 (Ln = La, Pr, Nd) – Syntheses, Crystal and Electronic Structures, and NLO PropertiesOriginalChemInform Abstract: A Series of Noncentrosymmetric Antimony Sulfides Ln8Sb2S15 (Ln: La, Pr, Nd) — Syntheses, Crystal and Electronic Structures, and NLO Properties.0Synthesis, Crystal Structure, and NLO Property of the Chiral Sulfide Sm4InSbS920Centrosymmetry vs noncentrosymmetry in La2Ga0.33SbS5 and Ce4GaSbS9 based on the interesting size effects of lanthanides: Syntheses, crystal structures, and optical properties13Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship338Synthesis, crystal structure, and optical properties of the noncentrosymmetric sulfide Ce 8 Sb 2 S 1512A review on the development of infrared nonlinear optical materials with triangular anionic groups38Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials90Synthesis, Crystal Structure, and Optical Property of Ce4InSbS91EuHgGeSe 4 and EuHgSnS 4 : Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses55Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering145La 12 Sb 9 S 38 : a new semiconducting lanthanum antimony polysulfide with a mixed La/Sb site4Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties10Recent advances in nonlinear optical rare earth structures63From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution22LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap23Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance64Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance57Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate70A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence13LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”37LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”5Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities2Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Antibonding States Drive Anharmonicity and Low Thermal Conductivity in Edge-Sharing Metal Chalcogenides4Synthesis, crystal structure, and optical property of La2Cl3[SbS3]2Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation0

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  1. ChemInform Abstract: A Series of Noncentrosymmetric Antimony Sulfides Ln8Sb2S15 (Ln: La, Pr, Nd) — Syntheses, Crystal and Electronic Structures, and NLO Properties.

    ChemInform · 2015-04-23

    Hua‐Jun Zhao, Liujiang Zhou

    Read original paper ↗ ·

  2. Synthesis, Crystal Structure, and NLO Property of the Chiral Sulfide Sm4InSbS9

    Zeitschrift für anorganische und allgemeine Chemie · 2015-11-17

    Hua‐Jun Zhao

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  3. Centrosymmetry vs noncentrosymmetry in La2Ga0.33SbS5 and Ce4GaSbS9 based on the interesting size effects of lanthanides: Syntheses, crystal structures, and optical properties

    Journal of Solid State Chemistry · 2016-01-25

    Hua‐Jun Zhao

    Read original paper ↗ ·

  4. Mid-Infrared Nonlinear Optical Materials Based on Metal Chalcogenides: Structure–Property Relationship

    Crystal Growth & Design · 2017-03-15

    Fei Liang, Lei Kang, Zheshuai Lin, Yicheng Wu

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  5. Synthesis, crystal structure, and optical properties of the noncentrosymmetric sulfide Ce 8 Sb 2 S 15

    Journal of Solid State Chemistry · 2017-04-11

    Hua‐Jun Zhao, Xiao-Ai Zhong

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  6. A review on the development of infrared nonlinear optical materials with triangular anionic groups

    Journal of Solid State Chemistry · 2018-11-22

    Yu Chu, Guangmao Li, Xin Su, Kui Wu, Shilie Pan

    Read original paper ↗ ·

  7. Centric-to-acentric structure transformation induced by a stereochemically active lone pair: a new insight for design of IR nonlinear optical materials

    Journal of Materials Chemistry C · 2019-01-01

    Hua Lin, Yanyan Li, Mengyue Li, Zuju Ma, Li‐Ming Wu, Xintao Wu, Qi‐Long Zhu

    Read original paper ↗ ·

  8. Synthesis, Crystal Structure, and Optical Property of Ce4InSbS9

    Journal of Structural Chemistry · 2019-09-01

    Hua‐Jun Zhao, B. Qin

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  9. EuHgGeSe 4 and EuHgSnS 4 : Two Quaternary Eu-Based Infrared Nonlinear Optical Materials with Strong Second-Harmonic-Generation Responses

    Inorganic Chemistry · 2020-11-30

    Wenhao Xing, Chunlan Tang, Naizheng Wang, Chunxiao Li, Zhuang Li, Jieyun Wu, Zheshuai Lin, Jiyong Yao, Wenlong Yin, Bin Kang

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  10. Breaking through the “3.0 eV wall” of energy band gap in mid-infrared nonlinear optical rare earth chalcogenides by charge-transfer engineering

    Materials Horizons · 2021-01-01

    Dajiang Mei, Wangzhu Cao, Naizheng Wang, Xingxing Jiang, Jun Zhao, Weikang Wang, Junhui Dang, Shiyan Zhang, Yuandong Wu, Pinhua Rao, Zheshuai Lin

    Read original paper ↗ ·

  11. La 12 Sb 9 S 38 : a new semiconducting lanthanum antimony polysulfide with a mixed La/Sb site

    Journal of Materials Chemistry C · 2021-01-01

    Luke T. Menezes, Zoltan Wolfgang Richter-Bisson, Abdeljalil Assoud, Holger Kleinke

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  12. Structural diversities in centrosymmetric La 8 S 4 Cl 8 La 12 S 8 Cl 4 [SbS 3 ] 8 and non-centrosymmetric Ln 12 S 8 Cl 8 [SbS 3 ] 4 (Ln = La and Ce): syntheses, crystal and electronic structures, and optical properties

    Dalton Transactions · 2021-01-01

    Hua‐Jun Zhao, Pengfei Liu, Li‐Ming Wu

    Read original paper ↗ ·

  13. Recent advances in nonlinear optical rare earth structures

    Journal of Rare Earths · 2021-07-15

    Jun Zhao, Dajiang Mei, Weikang Wang, Yuandong Wu, Dongfeng Xue

    Read original paper ↗ ·

  14. From Cc to P 6 3 mc : Structural Variation in La 3 S 2 Cl 2 [SbS 3 ] and La 3 OSCl 2 [SbS 3 ] Induced by the Isovalent Anion Substitution

    Crystal Growth & Design · 2022-01-17

    Hua‐Jun Zhao, Hedi Yang, Pengfei Liu, Hua Lin

    Read original paper ↗ ·

  15. LaAeAl 3 S 7 (Ae = Ca, Sr): Cairo pentagonal layered thioaluminates achieving a good balance between a strong second harmonic generation response and a wide bandgap

    Inorganic Chemistry Frontiers · 2023-01-01

    Jingjing Xu, Kui Wu, Bingbing Zhang, Haohai Yu, Huaijin Zhang

    Read original paper ↗ ·

  16. Rational Design of a Rare‐Earth Oxychalcogenide Nd3[Ga3O3S3][Ge2O7] with Superior Infrared Nonlinear Optical Performance

    Small · 2023-02-12

    Mao‐Yin Ran, Shenghua Zhou, Wenbo Wei, Bingxuan Li, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  17. Recent advances in IR nonlinear optical chalcogenides with well-balanced comprehensive performance

    Materials Today Physics · 2023-05-26

    Hedi Yang, Mao‐Yin Ran, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  18. Rare-earth-based chalcogenides and their derivatives: an encouraging IR nonlinear optical material candidate

    Chemical Science · 2024-01-01

    Ping Feng, Jiaxiang Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  19. A Rare Earth Chalcogenide Nonlinear Optical Crystal KLaGeS4: Achieving Good Balance among Band Gap, Second Harmonic Generation Effect, and Birefringence

    Inorganic Chemistry · 2024-06-03

    Yang Liu, Xiangming Li, Shuchang Wu, Mengjie Ma, Xiao‐Ming Jiang, Yuandong Wu, Dajiang Mei

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  20. LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”

    Angewandte Chemie International Edition · 2024-09-21

    Qianqian Liu, Xin Liu, Mei-Ze Li, Rui‐Xi Wang, Bingxuan Li, Li‐Ming Wu, Ling Chen

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  21. LiLnGeS 4 (Ln=La−Nd): Designing High Performance Infrared Nonlinear Optical Sulfides through “Band Reformation of AGS”

    Angewandte Chemie · 2024-09-21

    Qianqian Liu, Xin Liu, Mei-Ze Li, Rui‐Xi Wang, Bingxuan Li, Li‐Ming Wu, Ling Chen

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  22. Non-centrosymmetric Y3FeGaSe7 and Y3Mn0·5SiSe7 with extremely low thermal conductivities

    Journal of Physics and Chemistry of Solids · 2025-04-19

    Sweta Yadav, Sambit S.S. Rout, Omair Shahid, Gohil Singh Thakur, Manish K. Niranjan, Jai Prakash

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  23. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  24. Antibonding States Drive Anharmonicity and Low Thermal Conductivity in Edge-Sharing Metal Chalcogenides

    ACS Applied Materials & Interfaces · 2025-10-25

    Harpriya Minhas, Rahul Kumar Sharma, Biswarup Pathak

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  25. Synthesis, crystal structure, and optical property of La2Cl3[SbS3]

    Journal of Solid State Chemistry · 2025-11-20

    Hua‐Jun Zhao

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  26. Coordination chemistry of Sb(III)-based optical crystals: from lone-pair-induced distortion to birefringence and second-harmonic generation

    Coordination Chemistry Reviews · 2026-10-06

    Liyi Zhang, Pei Liu, Liling Cao, Ling Huang, Xuehua Dong, Guohong Zou

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