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RESEARCH PAPER · Topics in Catalysis · 2002

Combining XRD and EXAFS with on-Line Catalytic Studies for in situ Characterization of Catalysts

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Combining XRD and EXAFS with on-Line Catalytic Studies for in situ Characterization of CatalystsOriginalIn situ XANES study on TiO2–SiO2 aerogels and flame made materials29Determining the active site in a catalytic process: Operando spectroscopy is more than a buzzword359Liquid phase oxidation of alcohols with oxygen: in situ monitoring of the oxidation state of Bi-promoted Pd/Al2O3Electronic supplementary information (ESI) available: XANES spectra at the Bi L3-edge. See http://www.rsc.org/suppdata/cc/b3/b304508k/34Supercritical Fluids in Catalysis: Opportunities of In Situ Spectroscopic Studies and Monitoring Phase Behavior139In situ EXAFS study of Pd/Al2O3 during aerobic oxidation of cinnamyl alcohol in an organic solvent58In situ X-ray absorption study during methane combustion over Pd/ZrO2 catalysts40High-throughput screening under demanding conditions: Cu/ZnO catalysts in high pressure methanol synthesis as an example71Mapping the chemical states of an element inside a sample using tomographic x-ray absorption spectroscopy87Application of time-resolved in-situ X-ray absorption spectroscopy in solid-state chemistry16Probing Active Sites During Palladium-Catalyzed Alcohol Oxidation in “Supercritical” Carbon Dioxide50Limits and Advantages of X-ray Absorption Near Edge Structure for Nanometer Scale Metallic Clusters125In situ EXAFS study on the oxidation state of Pd/Al2O3 and Bi–Pd/Al2O3 during the liquid-phase oxidation of 1-phenylethanol84Helical carbon nanofibers with a symmetric growth mode91In situ Characterisation of Practical Heterogeneous Catalysts10X-ray absorption spectroscopy under reaction conditions: suitability of different reaction cells for combined catalyst characterization and time-resolved studies248Nanostructured Oxides in Chemistry: Characterization and Properties1035Formylation with supercritical carbon dioxide over Ru/Al2O3 modified by phosphines: heterogeneous or homogeneous catalysis?20Axial variation of the oxidation state of Pt-Rh/Al2O3 during partial methane oxidation in a fixed-bed reactor: An in situ X-ray absorption spectroscopy study59In situ spectroscopic investigation of heterogeneous catalysts and reaction media at high pressure110Xray Absorption Spectroscopy on Heterogeneous Catalysts at the new XAS Beamline at ANKA21Synchrotron Radiation Effects on Catalytic Systems As Probed with a Combined In-Situ UV−Vis/XAFS Spectroscopic Setup78High pressurein situx-ray absorption spectroscopy cell for studying simultaneously the liquid phase and the solid/liquid interface68Modelling silicon carbide formation during heating at constant rate6Studying the Solvothermal Formation of MoO3 Fibers by Complementary In Situ EXAFS/EDXRD Techniques105Untersuchung der solvothermalen Bildung von MoO3‐Fasern mithilfe komplementärer In‐situ‐EXAFS/EDXRD‐Techniken24Selective oxidation of alcohols with oxygen on Ru–Co-hydroxyapatite: A mechanistic study53Electron microscopy and EXAFS studies on oxide-supported gold–silver nanoparticles prepared by flame spray pyrolysis76Quasi‐Homogeneous Methanol Synthesis Over Highly Active Copper Nanoparticles124Quasi‐Homogeneous Methanol Synthesis Over Highly Active Copper Nanoparticles46A colloidal ZnO/Cu nanocatalyst for methanol synthesis48Model Catalyst Surfaces Investigated by Scanning Tunneling Microscopy135Bridging nanoscience and surface science to understand heterogeneous catalysis162D-Mapping of the Catalyst Structure Inside a Catalytic Microreactor at Work: Partial Oxidation of Methane over Rh/Al 2 O 3158In Situ Extended X-ray Absorption Fine Structure Study during Selective Alcohol Oxidation over Pd/Al2O3 in Supercritical Carbon Dioxide53Distinct spatial changes of the catalyst structure inside a fixed-bed microreactor during the partial oxidation of methane over Rh/Al2O377Combination of flame synthesis and high-throughput experimentation: The preparation of alumina-supported noble metal particles and their application in the partial oxidation of methane75X-ray diffraction study of Co3O4 activation under ethanol steam-reforming91Comparative in situ XAS investigations during aerobic oxidation of alcohols over ruthenium, platinum and palladium catalysts in supercritical CO227Insight into the structure of supported palladium catalysts during the total oxidation of methane125Lithographic Techniques in Nanocatalysis7Parallel structural screening of solid materials30Watching the crystallisation of complex oxides by in situ X-ray techniques28Diffraction and Extended X‐Ray Absorption Fine Structure (EXAFS)3A versatilein situspectroscopic cell for fluorescence/transmission EXAFS and X-ray diffraction of heterogeneous catalysts in gas and liquid phase55In SituEXAFS Characterization of Nanoparticulate Catalysts26Methanol Synthesis122Oxide–Support Interactions2A molecular view of heterogeneous catalysis143Catalysts at work: From integral to spatially resolved X-ray absorption spectroscopy100Chapter 5 X‐ray Diffraction38Chapter 6 Characterization of Catalysts in Reactive Atmospheres by X‐ray Absorption Spectroscopy98Operando X-ray absorption spectroscopy studies on Pd-SnO2 based sensors112Use of In Situ XAS Techniques for Catalysts' Characterization and Design2Visualizing a Catalyst at Work during the Ignition of the Catalytic Partial Oxidation of Methane63Recent progress in the use of in situ X-ray methods for the study of heterogeneous catalysts in packed-bed capillary reactors29X-ray Absorption Spectroscopic Microscopy: From the Micro- to the Nanoscale7Linking Simultaneous In Situ WAXS/SAXS/Raman with Raman/ATR/UV–vis Spectroscopy: Comprehensive Insight into the Synthesis of Molybdate Catalyst Precursors35Axial Changes of Catalyst Structure and Temperature in a Fixed-Bed Microreactor During Noble Metal Catalysed Partial Oxidation of Methane23A DFT study of the effect of copper promotion upon iron oxide surface species10Insight into the structure of Pd/ZrO2during the total oxidation of methane using combined in situ XRD, X-ray absorption and Raman spectroscopy15Novel XAFS capabilities at ELETTRA synchrotron light source233Shining X-rays on catalysts at work16Combined XRD and XANES studies of a Re-promoted Co/γ-Al2O3 catalyst at Fischer–Tropsch synthesis conditions106Combining in situ characterization methods in one set-up: looking with more eyes into the intricate chemistry of the synthesis and working of heterogeneous catalysts135Hard and soft X-ray microscopy and tomography in catalysis: bridging the different time and length scales181Combination of optical and X-ray techniques in the study of amorphous semiconductors under high pressure: an upgrade setup for combined XAS and XRD measurements10Deactivation of cobalt based Fischer–Tropsch catalysts: A review593Copper promotion of high temperature shift9Combined XRD and XAS16An in situ cell for investigation of the catalyst structure using synchrotron radiation18Struktur und Verhalten von Platin in SnO2‐basierten Gassensoren unter realistischen Arbeitsbedingungen8The Structure and Behavior of Platinum in SnO2‐Based Sensors under Working Conditions103Development of capabilities for "in situ" analysis of nanoparticles at the MCX powder diffraction beamline0In situdiffuse reflectance IR spectroscopy and X-ray absorption spectroscopy for fast catalytic processes47Bestimmung der Struktur, Zusammensetzung und Dynamiken molekularer Oberflächen unter Reaktionsbedingungen bei hohen Drücken und an der Fest‐flüssig‐Phasengrenzfläche6Determination of Molecular Surface Structure, Composition, and Dynamics under Reaction Conditions at High Pressures and at the Solid–Liquid Interface54Combining X-ray Absorption and X-ray Diffraction Techniques for in Situ Studies of Chemical Transformations in Heterogeneous Catalysis: Advantages and Limitations103Dynamic Cu/Zn Interaction in SiO2Supported Methanol Synthesis Catalysts Unraveled by in Situ XAFS62Lab Scale Fixed-Bed Reactor for Operando X-Ray Absorption Spectroscopy for Structure Activity Studies of Supported Metal Oxide Catalysts6Oscillatory Behavior during the Catalytic Partial Oxidation of Methane: Following Dynamic Structural Changes of Palladium Using the QEXAFS Technique53An Au clusters related spill-over sensitization mechanism in SnO2-based gas sensors identified by operando HERFD-XAS, work function changes, DC resistance and catalytic conversion studies123In situ neutron diffraction under high pressure—Providing an insight into working catalysts23X‐Ray Diffraction and Small Angle X‐Ray Scattering23In Situ Time-Resolved XAFS Study of the Reaction Mechanism of Bromobenzene Homocoupling Mediated by [Ni(cod)(bpy)]19X‐Ray Absorption Spectroscopy – the Method and Its Applications31Review of Pt-Based Bimetallic Catalysis: From Model Surfaces to Supported Catalysts1253Application of Operando XAS, XRD, and Raman Spectroscopy for Phase Speciation in Water Gas Shift Reaction Catalysts68Synchrotron Techniques for In Situ Catalytic Studies: Capabilities, Challenges, and Opportunities136Imaging Catalysts at Work: A Hierarchical Approach from the Macro‐ to the Meso‐ and Nano‐scale164Alloys on the Nanoscale6Charge competition with oxygen molecules determines the growth of gold particles on doped CaO films13In situ/operando studies for the production of hydrogen through the water-gas shift on metal oxide catalysts91Gaining insight into the kinetics of partial oxidation of light hydrocarbons on Rh, through a multiscale methodology based on advanced experimental and modeling techniques9Reactivity of Surface Species in Heterogeneous Catalysts Probed by In Situ X-ray Absorption Techniques643Exhaust Gas Aftertreatment in Mobile Systems: Status, Challenges, and Perspectives95In Situ Study of Catalytic Processes: Neutron Diffraction of a Methanol Synthesis Catalyst at Industrially Relevant Pressure75In‐situ‐Untersuchung von katalytischen Prozessen bei industriell relevanten Drücken: Neutronenbeugung an einem Methanolsynthesekatalysator19Characterization of Metal-Oxide Catalysts in Operando Conditions by Combining X-ray Absorption and Raman Spectroscopies in the Same Experiment17High-resolution chemical imaging of gold nanoparticles using hard x-ray ptychography48QEXAFS in Catalysis Research: Principles, Data Analysis, and Applications8Spatially Resolved X‐ray Absorption Spectroscopy7In Situ Observation of Cu–Ni Alloy Nanoparticle Formation by X‐Ray Diffraction, X‐Ray Absorption Spectroscopy, and Transmission Electron Microscopy: Influence of Cu/Ni Ratio79Determination of the electronic and structural configuration of coordination compounds by synchrotron-radiation techniques109Performance and characteristics of a high pressure, high temperature capillary cell with facile construction for operando x-ray absorption spectroscopy22Selective Catalytic Reduction of NO Over Fe-ZSM-5: Mechanistic Insights by Operando HERFD-XANES and Valence-to-Core X-ray Emission Spectroscopy153In situ studies of structural changes in DME synthesis catalyst with synchrotron powder diffraction4A laboratory-based hard x-ray monochromator for high-resolution x-ray emission spectroscopy and x-ray absorption near edge structure measurements175Aging of a Pt/Al 2 O 3 exhaust gas catalyst monitored by quasi in situ X-ray micro computed tomography22Catalyst characterisation techniques and reaction cells operating at realistic conditions; towards acquisition of kinetically relevant information62Identification of the iron oxidation state and coordination geometry in iron oxide- and zeolite-based catalysts using pre-edge XAS analysis80Methanation of CO2: Structural response of a Ni-based catalyst under fluctuating reaction conditions unraveled by operando spectroscopy177Structure–function relationships of conventionally and flame made Pd-doped sensors studied by X-ray absorption spectroscopy and DC-resistance26Lithographically fabricated silicon microreactor for in situ characterization of heterogeneous catalysts—Enabling correlative characterization techniques9Operando spatially and time-resolved X-ray absorption spectroscopy and infrared thermography during oscillatory CO oxidation108Iron-Based Catalysts for the High-Temperature Water–Gas Shift (HT-WGS) Reaction: A Review384A flexible gas flow reaction cell for in situ x-ray absorption spectroscopy studies3Operando X-Ray Photoelectron Spectroscopy Studies of Aqueous Electrocatalytic Systems30In Situ Ptychography of Heterogeneous Catalysts using Hard X-Rays: High Resolution Imaging at Ambient Pressure and Elevated Temperature34The CAT-ACT Beamline at ANKA: A new high energy X-ray spectroscopy facility for CATalysis and ACTinide research19A micropacked-bed multi-reactor system with in situ raman analysis for catalyst evaluation19Interplay of Pt and Crystal Facets of TiO2: CO Oxidation Activity and Operando XAS/DRIFTS Studies153Cell Designs for In Situ and Operando Studies22Quick XAFS4A decade+ of operando spectroscopy studies153Design and testing of an operando-Raman annular reactor for kinetic studies in heterogeneous catalysis12The Effect of Electrical Polarization on Electronic Structure in LSM Electrodes: An Operando XAS, RIXS and XES Study13Supported Catalysts for CO2 Methanation: A Review717In Situ Multimodal 3D Chemical Imaging of a Hierarchically Structured Core@Shell Catalyst55CAT-ACT—A new highly versatile x-ray spectroscopy beamline for catalysis and radionuclide science at the KIT synchrotron light facility ANKA134CaRMeN: a tool for analysing and deriving kinetics in the real world30Dual reactor for in situ/operando fluorescent mode XAS studies of sample containing low-concentration 3d or 5d metal elements17Probing the Evolution of Palladium Species in Pd@MOF Catalysts during the Heck Coupling Reaction: An Operando X-ray Absorption Spectroscopy Study97Restricted Open-Shell Configuration Interaction Singles Study on M- and L-edge X-ray Absorption Spectroscopy of Solid Chemical Systems25Operando X-ray absorption spectroscopy study of the Fischer–Tropsch reaction with a Co catalyst8In situ XAS study of the local structure and oxidation state evolution of palladium in a reduced graphene oxide supported Pd( ii ) carbene complex during an undirected C–H acetoxylation reaction23Development of in situ cell for simultaneous XAFS/XRD measurements at high temperatures7Moving Frontiers in Transition Metal Catalysis: Synthesis, Characterization and Modeling50Methane Reforming on Single Atom Catalysts0Dynamics of Reactive Species and Reactant-Induced Reconstruction of Pt Clusters in Pt/Al 2 O 3 Catalysts74A versatile nanoreactor for complementary in situ X-ray and electron microscopy studies in catalysis and materials science27Chemical and texture promoters in Cu-Fe-Al oxide nanocomposite catalysts for combustion of solid fuel gasification products23Bridging the gap between industry and synchrotron: an operando study at 30 bar over 300 h during Fischer–Tropsch synthesis26Silicon microfabricated reactor for operando XAS/DRIFTS studies of heterogeneous catalytic reactions12Structural dynamics in Ni–Fe catalysts during CO 2 methanation – role of iron oxide clusters89Structural dynamics of an iron molybdate catalyst under redox cycling conditions studied with in situ multi edge XAS and XRD48Activity and Structural Changes of Fe‐based Catalysts during CO 2 Hydrogenation towards CH 4 – A Mini Review57The Consortium for Operando and Advanced Catalyst Characterization via Electronic Spectroscopy and Structure (Co-ACCESS) at Stanford Synchrotron Radiation Lightsource (SSRL)6In situ characterization of Fischer–Tropsch catalysts: a review44Dynamically Operated Fischer–Tropsch Synthesis in PtL—Part 2: Coping with Real PV Profiles11Influence of the Calcination Temperature on the properties of The Alumina as Catalyst Support for Catalysis2

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  1. In situ XANES study on TiO2–SiO2 aerogels and flame made materials

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  2. Determining the active site in a catalytic process: Operando spectroscopy is more than a buzzword

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  3. Liquid phase oxidation of alcohols with oxygen: in situ monitoring of the oxidation state of Bi-promoted Pd/Al2O3Electronic supplementary information (ESI) available: XANES spectra at the Bi L3-edge. See http://www.rsc.org/suppdata/cc/b3/b304508k/

    Chemical Communications · 2003-01-01

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  4. Supercritical Fluids in Catalysis: Opportunities of In Situ Spectroscopic Studies and Monitoring Phase Behavior

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  5. In situ EXAFS study of Pd/Al2O3 during aerobic oxidation of cinnamyl alcohol in an organic solvent

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  6. In situ X-ray absorption study during methane combustion over Pd/ZrO2 catalysts

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  7. High-throughput screening under demanding conditions: Cu/ZnO catalysts in high pressure methanol synthesis as an example

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  8. Mapping the chemical states of an element inside a sample using tomographic x-ray absorption spectroscopy

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  9. Application of time-resolved in-situ X-ray absorption spectroscopy in solid-state chemistry

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  10. Probing Active Sites During Palladium-Catalyzed Alcohol Oxidation in “Supercritical” Carbon Dioxide

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  11. Limits and Advantages of X-ray Absorption Near Edge Structure for Nanometer Scale Metallic Clusters

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  12. In situ EXAFS study on the oxidation state of Pd/Al2O3 and Bi–Pd/Al2O3 during the liquid-phase oxidation of 1-phenylethanol

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  14. In situ Characterisation of Practical Heterogeneous Catalysts

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  15. X-ray absorption spectroscopy under reaction conditions: suitability of different reaction cells for combined catalyst characterization and time-resolved studies

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  17. Formylation with supercritical carbon dioxide over Ru/Al2O3 modified by phosphines: heterogeneous or homogeneous catalysis?

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  18. Axial variation of the oxidation state of Pt-Rh/Al2O3 during partial methane oxidation in a fixed-bed reactor: An in situ X-ray absorption spectroscopy study

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  19. In situ spectroscopic investigation of heterogeneous catalysts and reaction media at high pressure

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  20. Xray Absorption Spectroscopy on Heterogeneous Catalysts at the new XAS Beamline at ANKA

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  23. Modelling silicon carbide formation during heating at constant rate

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  34. In Situ Extended X-ray Absorption Fine Structure Study during Selective Alcohol Oxidation over Pd/Al2O3 in Supercritical Carbon Dioxide

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  35. Distinct spatial changes of the catalyst structure inside a fixed-bed microreactor during the partial oxidation of methane over Rh/Al2O3

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  36. Combination of flame synthesis and high-throughput experimentation: The preparation of alumina-supported noble metal particles and their application in the partial oxidation of methane

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  37. X-ray diffraction study of Co3O4 activation under ethanol steam-reforming

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  38. Comparative in situ XAS investigations during aerobic oxidation of alcohols over ruthenium, platinum and palladium catalysts in supercritical CO2

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  39. Insight into the structure of supported palladium catalysts during the total oxidation of methane

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  40. Lithographic Techniques in Nanocatalysis

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  42. Watching the crystallisation of complex oxides by in situ X-ray techniques

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  43. Diffraction and Extended X‐Ray Absorption Fine Structure (EXAFS)

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  44. A versatilein situspectroscopic cell for fluorescence/transmission EXAFS and X-ray diffraction of heterogeneous catalysts in gas and liquid phase

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  46. Methanol Synthesis

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  47. Oxide–Support Interactions

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  48. A molecular view of heterogeneous catalysis

    The Journal of Chemical Physics · 2008-05-12

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  49. Catalysts at work: From integral to spatially resolved X-ray absorption spectroscopy

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  50. Chapter 5 X‐ray Diffraction

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