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RESEARCH PAPER · Journal of the American Chemical Society · 2025

Atomic-Scale Dynamics of Five-Fold Twin Mediated Coalescence: Pathway-Dependent and Defect-Governed Nonclassical Growth Mechanisms

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Atomic-Scale Dynamics of Five-Fold Twin Mediated Coalescence: Pathway-Dependent and Defect-Governed Nonclassical Growth MechanismsOriginalA wide band gap selenohalide Cs 9 Si 8 Se 20 Cl with unprecedented [CsSe 7 Cl] mixed anionic units2Cd 5 Te 4 O 12 X 2 (X = Cl, Br, I): a new oxyhalide family with [CdO 4 X] mixed anionic units and adjustable optical properties4Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14[HgX 2 ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg 5 Br 11 with Strong Optical Anisotropy and Wide Bandgap12Boosting Acidic OER Performance Via Transition Metal Doping in Iridium/Ruthenium Oxides0Seed‐Engineered Growth of Sub‐100 Nm Chiral Au Nanoparticles with Enhanced Optical Chirality and Catalytic Activities4NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS26Size‐Focusing of Au Nanoparticles through Dissolution–Renucleation Process Imaged with In Situ TEM1Support‐Intensified Ir─P/O─Mo Cooperative Linkages for Robust Acidic Water Dissociation4In situ monitoring of a metal recovery process using dual imaging and diffraction0Nano-gold with in situ -grown surface-charge layer in organic framework, superlattice–chiral structures, and tailored optical properties0Nano-gold with in situ grown surface charge-layer in organic framework, superlattice-chiral structures, and tailored optical properties0Polyhedral replacement-guided design of Ce3MnGaSe7 featuring strong second-harmonic genera-tion and high laser-induced damage threshold0Te–Se replacement induced structural transition and enhanced band gaps in Cd 5 Se 4 O 12 Cl 2 and Cd 5 Se 4 O 12 Br 21Confinement-assembled ultraviolet nonlinear optical crystal from pyridine-expanded π-systems with exhibiting strong SHG and birefringence18Harnessing tetrahedral diversity: The path to superior diamond-like IR NLO crystals13Orientation-specific sintering kinetics of supersaturated Ag−Cu nanoalloy and Cu@Ag microparticles0Linear [ICl 2 ] Units Induced Giant Optical Anisotropy in AICl 2 (A = NH 4 , Rb): A Pathway to Advanced Birefringent Materials4Crystallization as a local symmetry-breaking event in a tunable soft matter0In Situ Atomic‐Scale Observation of Preferential Premelting at Oxide Crystal Defects0Crystal Growth and Characterization of Pyridinium-Based Nonlinear Optical Crystals of DAST for Wide Terahertz Frequency Detection0Interface–geometry modulated thermal instability of five-fold twinned Ag nanodecahedra0Local polarization-piezoelectric field promotes water dissociation for efficient fluorinated pollutants defluorination0Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Geometry-controlled competition between axis centering and detwinning in fivefold-twinned gold nanoparticles0In Situ TEM Observation of the Coalescence between Immiscible Au and Rh Nanoparticles to Form AuRh Heterostructures0Imperfect Oriented Attachment of Gold Nanoparticles0AlGaS3: a wide band gap ternary diamond-like infrared nonlinear optical material with high laser-induced damage threshold1Ultrafast Laser Induced Bulk Damage Dynamics and Pulse ‐ Width Criticality Mechanism on KDP Crystals0

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  3. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

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  7. NaAg3Ga8S14: A new diamond-like framework infrared nonlinear optical material derived from AgGaS2

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