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RESEARCH PAPER · Coordination Chemistry Reviews · 2024

Recent progress in nonlinear optical molybdenum/tungsten tellurites: Structures, crystal growth and characterizations

Jingfang Zhou, Qian Wu, Aimin Ji, Zhen Jia, Mingjun Xia

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Recent progress in nonlinear optical molybdenum/tungsten tellurites: Structures, crystal growth and characterizationsOriginal(C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence12Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups11Design and Synthesis of Two Sn-Centered Mixed Halide Crystals with Enhanced Birefringence8Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence3From (C6H5N2)2CdCl4 to (C6H5N2)2ZnCl4, Chirality Transformation to Realize a Nonlinear Optical Organic–Inorganic Hybrid Halide with Balanced Comprehensive Performance19LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride10La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence13Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy34(CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units10Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids8Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy8Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals14Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals3Transition‐Metal Azo Schiff Base Complexes: Nonlinear Optics Across Solutions, Thin Films and Nanocomposites9Enabling Efficient Oxygen Reduction Reaction with Pt Single Atoms on Carbide: A Phosphorus-Doped Mo 2 C Interface Strategy10Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons12Heterocationic strategy to design a nonlinear optical crystal with a polar anti-perovskite structure7ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems2Amino Acid Modification in One-Dimensional Cadmium Thiocyanates for Enhancing Second-Harmonic Generation Response2Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses3A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination1Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation1Charge-order-induced directional enhancement of non-diagonal second-order nonlinear optical tensor components2Design of benzoxazolium-based nonlinear optical crystals with large second-order harmonic generation responses0Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite1Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units0中红外非线性光学晶体AVO2SeO3（A=Rb+， Cs+）的结构和光学性能研究（特邀）01D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation7Multinary tellurates as energy storage materials0C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties2Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities1Dose-varied tungsten ion implantation for performance modulation of GA2PbI4 x-ray detectors0

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  1. (C 14 H 14 N 2 )MCl 4 (M = Zn, Cd): two hybrid metal halides exhibiting strong second harmonic generation responses, large birefringence, and broadband photoluminescence

    Inorganic Chemistry Frontiers · 2025-01-01

    Xinhui Li, Pifu Gong, Mingxing Chen, Shujuan Zhuang, Man Qi, Wenqiang Wang, Xinfang Wang, Zhen Jia, Mingjun Xia

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  2. Hg 2 (SeO 3 )(TeO 3 ): a novel tellurite–selenite birefringent crystal achieved by assembling multiple functional groups

    Journal of Materials Chemistry C · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  3. Design and Synthesis of Two Sn-Centered Mixed Halide Crystals with Enhanced Birefringence

    Inorganic Chemistry · 2025-01-21

    Hongkun Liu, Gangji Yi, Jiarong Lv, Xuehua Dong, Hongmei Zeng, Ling Huang, Zhien Lin, Guohong Zou

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  4. Pb 4 O 3 I 2 : A Lead Oxyhalide IR Optical Crystal with an Unprecedented 1 ∞ [O 3 Pb 4 ] Chain Featuring a Wide Transmittance Range and Large Birefringence

    Inorganic Chemistry · 2025-01-27

    Jiang Wu, Jiahao Jiao, Mayinuer Maimaiti, Ke Li, Jugong Zheng, Min Zhang

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  5. From (C6H5N2)2CdCl4 to (C6H5N2)2ZnCl4, Chirality Transformation to Realize a Nonlinear Optical Organic–Inorganic Hybrid Halide with Balanced Comprehensive Performance

    Inorganic Chemistry · 2025-02-13

    Die-Xue Yang, Yi‐Lei Lv, Jiandong Guo, Wen-Ye Gao, Wenlong Liu, Ru‐Ling Tang

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  6. LiAgCe2F10(H2O)2: Focusing on the Cation Size Effect to Reasonably Design a Nonlinear Optical Hydrated Cerium(IV) Fluoride

    Inorganic Chemistry · 2025-03-24

    Wen-Ye Gao, Yi‐Lei Lv, Siyu Ma, Cheng Chen, Wenlong Liu, Ru‐Ling Tang

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  7. La2Zn3(SeO3)6: A UV Selenite Crystal with Second-Harmonic Generation and Large Birefringence

    Inorganic Chemistry · 2025-05-01

    Pengfei Li, Xiaoxue Wang, Chun‐Li Hu, Jiang‐Gao Mao, Fang Kong

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  8. Ca 7 (TeO 3 ) 6 (MoO 4 ): A Promising Mid-Infrared Nonlinear Optical Crystal Activated via a Module-Oriented Dimensionality Reduction Strategy

    Journal of the American Chemical Society · 2025-05-15

    Tinghui Zhang, Fei Liang, Conggang Li, Ning Ye, Zhanggui Hu

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  9. (CH5N3S)2Pb5Br10 and (CH5N3S)Pb2Br4: Two Nonlinear Optical Lead Thiosemicarbazide Bromides with Diverse Pb-Centered Building Units

    Inorganic Chemistry · 2025-05-20

    Ru‐Ling Tang, Yue‐Qi Wei, Yi‐Lei Lv, Bing-Wei Miao, Cheng Chen, Wenlong Liu

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  10. Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids

    Inorganic Chemistry · 2025-06-23

    Qian Wu, Tianyu Wang, Jingfang Zhou, Pifu Gong, Haochen Li, Haotian Tian, Mingjun Xia

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  11. Optimizing the Hydrogen-Bond Network Drives Cadmium Ce(IV) Fluoride Hydrate with Significantly Enhanced Optical Anisotropy

    Inorganic Chemistry · 2025-07-25

    Wen-Ye Gao, Siyu Ma, Bing-Wei Miao, Wenfeng Zhou, Wenlong Liu, Ru‐Ling Tang

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  12. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

    Angewandte Chemie International Edition · 2025-08-10

    Lingli Wu, Chensheng Lin, Huixin Fan, Shunda Yang, Tao Yan, Yunxia Song, Min Luo

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  13. Hydrogen‐Bond‐Directed Modular Assembly of Polar Chains for Rational Construction of UV Nonlinear Optical Crystals

    Angewandte Chemie · 2025-08-10

    Lingli Wu, Chensheng Lin, Huixin Fan, Shunda Yang, Tao Yan, Yunxia Song, Min Luo

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  14. Transition‐Metal Azo Schiff Base Complexes: Nonlinear Optics Across Solutions, Thin Films and Nanocomposites

    Advanced Optical Materials · 2025-09-04

    K. Waszkowska, Mark Busch, Siham Slassi, Amina Amine, Abdelkrim El‐Ghayoury, Janusz Strzelecki, Anna M. Zawadzka, Andriy V. Kityk, Patrick Huber, B. Sahraoui

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  15. Enabling Efficient Oxygen Reduction Reaction with Pt Single Atoms on Carbide: A Phosphorus-Doped Mo 2 C Interface Strategy

    Nano Letters · 2025-10-29

    Changwei Shi, Xingmao Jiang, Xueqiang Qi, Congcong Xing, Xiaolei Fan, Zhuo Chen, Xiang Wang, Andreu Cabot

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  16. Maximizing the second-harmonic generation response via coordination-induced localization of nonbonding electrons

    Chemical Science · 2025-11-17

    Jia-Xiang Zhang, A-Lan Xu, Yang Chi, Xin-Tao Wu, Hua Lin, Qi‐Long Zhu

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  17. Heterocationic strategy to design a nonlinear optical crystal with a polar anti-perovskite structure

    Nature Communications · 2025-12-12

    Shuoxing Yang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  18. ZnGa(SeO 3 ) 2 F: a UV transparent birefringent crystal explored in M( ii )–IIIA–selenite–F systems

    Inorganic Chemistry Frontiers · 2025-12-20

    Tian-Tian He, C Hu, Ya-Ping Gong, Jiang‐Gao Mao, Fang Kong

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  19. Amino Acid Modification in One-Dimensional Cadmium Thiocyanates for Enhancing Second-Harmonic Generation Response

    Inorganic Chemistry · 2025-12-22

    Xuemei Wen, Yue Zhou, Caihong Guo, Guohong Zou, Zhien Lin

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  20. Mid Infrared Nonlinear Optical Series A 4 MV 5 O 15 X (A = K, Rb; M = Zn, Cd; X = Cl, Br) with Strong Second Harmonic Generation Responses

    Inorganic Chemistry · 2025-12-23

    Haochen Li, Jinhua Wang, Haotian Tian, Xiaodong Zhang, T. Wang, Hongrui Liu, Bing Li, Pengyun Chen, Pifu Gong, Qian Wu, Shu Hai Guo, Mingjun Xia

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  21. A mercury-based selenite with wide bandgap and moderate birefringence via cation substitution and partial fluorination

    Dalton Transactions · 2026-01-01

    Chen Zhu, Xiao-Min Wu, Xiao-Xue Wang, Si-Qi Zhou, Jing-Jing Wu, Xin-Lei Liu, You-Qian Wu, Jiannian Yao, Peng-Fei Li, Yu-Wu Zhong

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  22. Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation

    Inorganic Chemistry Frontiers · 2026-01-01

    S AN, Yaqi Jin, Wenhu Wang, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  23. Charge-order-induced directional enhancement of non-diagonal second-order nonlinear optical tensor components

    Chemical Communications · 2026-01-01

    马祖驹, Zehui Fang, Zhenlong Xie, Jia-Xiang Zhang, Hua Lin

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  24. Design of benzoxazolium-based nonlinear optical crystals with large second-order harmonic generation responses

    Chemical Communications · 2026-01-01

    Shaona Wang, Bin Li, Xinyuan Zhang, Zhanggui Hu, Ning Ye

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  25. Li 3 GaTe 4 O 11 : small ion-driven orientation of TeO n units in a tunnel-structured tellurite

    Dalton Transactions · 2026-01-01

    Jingfang Zhou, Pifu Gong, Chang Gao, Mingjun Xia, Jing Yu, Hongxia Zhang, Qian Wu

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  26. Optical anisotropy in Mo–Te–O frameworks constructed from distorted MoO 6 and TeO 3 units

    Dalton Transactions · 2026-01-01

    Cheng He, Kun Hu, Jing-Yang Zhou, Long Wu, Jian‐Han Zhang

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  27. 中红外非线性光学晶体AVO2SeO3（A=Rb+， Cs+）的结构和光学性能研究（特邀）

    Chinese Journal of Lasers · 2026-01-01

    钟丽 Zhong Li, 吴玲莉 Wu Lingli, Lin Chensheng, 李丙轩 Li Bingxuan, 颜涛 Yan Tao, 罗敏 Luo Min

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  28. 1D Cobalt‐Cytidine Monophosphate Coordination Polymer Exhibiting Efficient Ultraviolet Second‐Harmonic Generation

    Chemistry - A European Journal · 2026-02-09

    Mubashar Ilyas, Lin Xiong, Li Zhang, Maida, Maroof Ahmad Khan, Muhammad Abbas, Nagesh Manurkar, Mudassar Ilyas, Niu Zhang, Hui Li

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  29. Multinary tellurates as energy storage materials

    iScience · 2026-02-09

    Titus Masese, Godwill Mbiti Kanyolo

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  30. C 6 H 7 NCl·X (X = Cl, Br): Outstanding Multifunctional Nonlinear Optical and Birefringent Crystals Enabled by Incorporation of π‐Conjugated Moieties

    Advanced Optical Materials · 2026-02-28

    Chuanying Shen, Jiaxi Ding, Zhengao Xie, Kang Yang, Xunwang Yan, Bingbing Zhang, Kui Wu, Jiyang Wang, Duanliang Wang

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  31. Rational design of a quasi-0D tungsten tellurite nonlinear optical crystal with exceptionally balanced properties

    Science China Chemistry · 2026-03-19

    Shijie Zhao, Lili Li, Tinghui Zhang, Huijian Zhao, Ning Ye, Zhanggui Hu, Conggang Li

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  32. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  33. Metal tellurite oxides: Lone-pair-enabled coordination chemistry, polymerized architectures, and functional materials opportunities

    Coordination Chemistry Reviews · 2026-05-07

    Yiyun Wang, Hongbo Cui, Jiayi Guo, Guijian Guan, Ming‐Yong Han

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  34. Dose-varied tungsten ion implantation for performance modulation of GA2PbI4 x-ray detectors

    Journal of Applied Physics · 2026-09-15

    Lu-Di Zhang, Hong‐Jian Feng

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