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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Unusual Triple-State Switching of Thermally Induced Birefringence in a Two-Dimensional Perovskite Ferroelectric

Yu Ma, Beibei Wang, Wenjing Li, Yi Liu, Wuqian Guo, Haojie Xu, Liwei Tang, Qingshun Fan, Junhua Luo, Zhihua Sun

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Unusual Triple-State Switching of Thermally Induced Birefringence in a Two-Dimensional Perovskite FerroelectricOriginalA one-dimensional organic–inorganic hybrid ferroelectric exhibiting a dielectric-optical duple switch5A photoluminescent second-order nonlinear optical molecular crystal with cold crystallization1Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities39Ferroelectric polarization in 2D halide hybrid perovskites: influence on bulk crystals, thin films, and applications17Highly stable and reversible birefringence switching triggered by thermally stimulated phase transition1Large birefringence switching in a new zero-dimensional cyanide perovskite ferroelastic material3Precise Tailoring of Unprecedent Layered Perovskite‐Type Heterostructure Ferroelectric via Chemical Molecular Scissor3Precise Tailoring of Unprecedent Layered Perovskite‐Type Heterostructure Ferroelectric via Chemical Molecular Scissor11A Lithium Complex Ferroelectric with High Curie Temperature: [Li(1,10-Phenanthroline)2]I1The First Recyclable Molecular Ferroelectric Can Catalyze Difunctionalization of Olefin7Regulation of Refractive Index by Halogens in Two-Dimensional Layered Methylsulfonate Halides7A 3D Hybrid Perovskite Ferroelastic with Triclinic‐to‐Cubic Phase Transition Boosts Temperature/Pressure Dual On/Off Switchable Birefringence4A 3D Hybrid Perovskite Ferroelastic with Triclinic‐to‐Cubic Phase Transition Boosts Temperature/Pressure Dual On/Off Switchable Birefringence19Alkyl Substitution on the Phase Transition and Optical Properties of Lead-Based Molecular Ferroelastic Materials0Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties35Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties6Research progress and future prospect of chalcogenides with large optical anisotropy46Dual‐Sided Multidentate Coordination Strategy Enables Record Birefringence in UV‐Transparent Antimony‐Based Hybrid Crystals37Dual‐Sided Multidentate Coordination Strategy Enables Record Birefringence in UV‐Transparent Antimony‐Based Hybrid Crystals11Large vertical spontaneous polarization and strong second harmonic generation in a layered perovskite ferroelectric1Multiaxial Aromatic‐Based Photoferroelectric Induced by Synergistic Intermolecular Interactions for Multidirectional Self‐Powered X‐Ray Detection18Multiaxial Aromatic‐Based Photoferroelectric Induced by Synergistic Intermolecular Interactions for Multidirectional Self‐Powered X‐Ray Detection3Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations14Lone pair expression in fluorinated two-dimensional hybrid perovskite enables multiaxial ferroelectricity and nonlinear optical response23A 2D Van Der Waals Molecular Ferroelectric3Chiral Bismuth Halide Crystals: Polarizability-Driven Birefringence and Wave Plate Functionality4Sulfonated Module Aggregation for Ultrahigh Birefringence in Aqueous-Processable Crystals26Proton Alloying in an Organic‐Inorganic Hybrid Material Enables Unusual Dynamic Birefringence and Martensitic Actuation0Proton Alloying in an Organic‐Inorganic Hybrid Material Enables Unusual Dynamic Birefringence and Martensitic Actuation7Supramolecular Rotor Assemblies Exhibiting Thermally Driven Shear‐Dominated Transformation and Birefringence Switching1Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence3Halogen-mediated interaction engineering enables tailored order–disorder phase transitions in photoactive nitroprusside hybrids0Molecular pseudo-halogen engineering enables remarkable birefringence enhancement in hybrid perovskites0Distinct Tunable In‐Plane Birefringence via Domain Manipulation in a 2D Metal Halide Ferroelectric3Distinct Tunable In‐Plane Birefringence via Domain Manipulation in a 2D Metal Halide Ferroelectric1Significant Birefringence Enhancement via Cs + Alloying in Layered Perovskites: Synergistic Alignment of Organic Cations and Inorganic Framework1Organosilicon cluster goes ferroelectric0Cation-sulfur-driven dimensional reduction engineering for tailoring sulfonate birefringent crystals with enhanced anisotropy2Mixed Cation-Ordering-Driven Ferroelastic Phase Transition in Hybrid Lead Halide Enabling Large Switchable Birefringence0Reconfigurable and nonvolatile photo-pyroelectricity in a ceramic-like biaxial molecular ferroelectric via polarization engineering1Perspective on Ferroelectric and Nonferroelectric Low‐Dimensional Metal Halide Perovskites for Memristor Technology1Molecular Crystals With Reversible Chromic Three‐State Crystal‐to‐Crystal Transformation via the Dynamic Motion of Negatively Curved π‐Frameworks0Polarization-dependent refractive index sensing via ordinary and extraordinary quasi-BIC resonances in LiTaO₃ and LiNbO₃ nanobar gratings0A Dynamic Hydrogen‐Bonded Organic Framework With Giant OFF–ON Birefringence0A Dynamic Hydrogen‐Bonded Organic Framework With Giant OFF–ON Birefringence0

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  3. Dynamic control of halide perovskite structures for tailored ferroelectric and second-order nonlinear optical functionalities

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  4. Ferroelectric polarization in 2D halide hybrid perovskites: influence on bulk crystals, thin films, and applications

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  5. Highly stable and reversible birefringence switching triggered by thermally stimulated phase transition

    Inorganic Chemistry Frontiers · 2025-01-01

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  6. Large birefringence switching in a new zero-dimensional cyanide perovskite ferroelastic material

    Inorganic Chemistry Frontiers · 2025-01-01

    Jun-Si Zhou, Luan-Ying Ji, Shuyi Liu, Xiao‐Gang Chen

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  7. Precise Tailoring of Unprecedent Layered Perovskite‐Type Heterostructure Ferroelectric via Chemical Molecular Scissor

    Angewandte Chemie · 2025-01-20

    Yu Ma, Wenjing Li, Yi Liu, Wuqian Guo, Haojie Xu, Liwei Tang, Qingshun Fan, Hao Rong, Junhua Luo, Zhihua Sun

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  8. Precise Tailoring of Unprecedent Layered Perovskite‐Type Heterostructure Ferroelectric via Chemical Molecular Scissor

    Angewandte Chemie International Edition · 2025-01-20

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  9. A Lithium Complex Ferroelectric with High Curie Temperature: [Li(1,10-Phenanthroline)2]I

    Inorganic Chemistry · 2025-01-31

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  10. The First Recyclable Molecular Ferroelectric Can Catalyze Difunctionalization of Olefin

    Advanced Functional Materials · 2025-03-05

    Jun‐Chao Qi, Xian‐Jiang Song, Hang Peng, Xiao‐Gang Chen, Ren‐Gen Xiong, Wei‐Qiang Liao

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  11. Regulation of Refractive Index by Halogens in Two-Dimensional Layered Methylsulfonate Halides

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    Cao Xue, Xuemei Shi, Piao Tang, Xin Wen, Jindong Chen, Guang Peng, Ning Ye

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  12. A 3D Hybrid Perovskite Ferroelastic with Triclinic‐to‐Cubic Phase Transition Boosts Temperature/Pressure Dual On/Off Switchable Birefringence

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  13. A 3D Hybrid Perovskite Ferroelastic with Triclinic‐to‐Cubic Phase Transition Boosts Temperature/Pressure Dual On/Off Switchable Birefringence

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  14. Alkyl Substitution on the Phase Transition and Optical Properties of Lead-Based Molecular Ferroelastic Materials

    Crystal Growth & Design · 2025-05-15

    Leqi Chen, Yawen Yang, Zining Zhou, Zongwei Hu, Qiong Ye

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  15. Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties

    Angewandte Chemie International Edition · 2025-06-20

    Xuehua Dong, Ling Huang, Hongmei Zeng, Zhien Lin, Kang Min Ok, Guohong Zou

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  16. Dual Chemical Scissors Strategy Enables 1D Antimony Selenates with Ultraviolet Nonlinear Optical Properties

    Angewandte Chemie · 2025-06-20

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  17. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

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  18. Dual‐Sided Multidentate Coordination Strategy Enables Record Birefringence in UV‐Transparent Antimony‐Based Hybrid Crystals

    Angewandte Chemie International Edition · 2025-07-10

    Pu Zhang, Xuehua Dong, Ling Huang, Zhien Lin, Yuqiao Zhou, Guohong Zou

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  19. Dual‐Sided Multidentate Coordination Strategy Enables Record Birefringence in UV‐Transparent Antimony‐Based Hybrid Crystals

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  20. Large vertical spontaneous polarization and strong second harmonic generation in a layered perovskite ferroelectric

    Chinese Chemical Letters · 2025-07-15

    Qian Jun Gu, Run-Zhi Zhang, R. Q. Ma, Yajuan Li, Peng-Peng Gong, Yi Ping Guo, Bo Huang, Ai‐Xin Zhu

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  21. Multiaxial Aromatic‐Based Photoferroelectric Induced by Synergistic Intermolecular Interactions for Multidirectional Self‐Powered X‐Ray Detection

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  22. Multiaxial Aromatic‐Based Photoferroelectric Induced by Synergistic Intermolecular Interactions for Multidirectional Self‐Powered X‐Ray Detection

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  23. Local Symmetry Breaking and Hidden Spin Polarization in 2D Hybrid Perovskites with Nonprimary Ammonium Cations

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  24. Lone pair expression in fluorinated two-dimensional hybrid perovskite enables multiaxial ferroelectricity and nonlinear optical response

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  25. A 2D Van Der Waals Molecular Ferroelectric

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  26. Chiral Bismuth Halide Crystals: Polarizability-Driven Birefringence and Wave Plate Functionality

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  27. Sulfonated Module Aggregation for Ultrahigh Birefringence in Aqueous-Processable Crystals

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  28. Proton Alloying in an Organic‐Inorganic Hybrid Material Enables Unusual Dynamic Birefringence and Martensitic Actuation

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  29. Proton Alloying in an Organic‐Inorganic Hybrid Material Enables Unusual Dynamic Birefringence and Martensitic Actuation

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  31. Sb 2 (SeO 3 ) 2 SeO 4 : A Selenite–Selenate Crystal with Balanced Band Gap and Birefringence

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  33. Molecular pseudo-halogen engineering enables remarkable birefringence enhancement in hybrid perovskites

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  34. Distinct Tunable In‐Plane Birefringence via Domain Manipulation in a 2D Metal Halide Ferroelectric

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  35. Distinct Tunable In‐Plane Birefringence via Domain Manipulation in a 2D Metal Halide Ferroelectric

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  36. Significant Birefringence Enhancement via Cs + Alloying in Layered Perovskites: Synergistic Alignment of Organic Cations and Inorganic Framework

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  39. Mixed Cation-Ordering-Driven Ferroelastic Phase Transition in Hybrid Lead Halide Enabling Large Switchable Birefringence

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  41. Perspective on Ferroelectric and Nonferroelectric Low‐Dimensional Metal Halide Perovskites for Memristor Technology

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  43. Polarization-dependent refractive index sensing via ordinary and extraordinary quasi-BIC resonances in LiTaO₃ and LiNbO₃ nanobar gratings

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  44. A Dynamic Hydrogen‐Bonded Organic Framework With Giant OFF–ON Birefringence

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  45. A Dynamic Hydrogen‐Bonded Organic Framework With Giant OFF–ON Birefringence

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