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RESEARCH PAPER · Angewandte Chemie · 2025

Dual‐Sided Multidentate Coordination Strategy Enables Record Birefringence in UV‐Transparent Antimony‐Based Hybrid Crystals

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Dual‐Sided Multidentate Coordination Strategy Enables Record Birefringence in UV‐Transparent Antimony‐Based Hybrid CrystalsOriginalRealizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion6Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal5(C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts1Persistent Second‐Harmonic Generation Enhancement Across an Unprecedented Pressure Range in a Hybrid Antimony Halide0Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps1The Power of Pnictogen Bond: As─As Linkages Drive Wide Bandgap, Strong NLO Response and Large Birefringence in SrGa 3 Si 4 As 110Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides1Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide0Lateral‐Site Unblocking Enables Bilateral π ‐Chromophore Organization for Giant Birefringence in One‐Dimensional Lead Hybrids0Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration0[La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window0

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  1. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

    Angewandte Chemie · 2026-01-05

    Meng‐Na Jing, Si‐Fan Lu, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  2. Overcoming the Bandgap‐Birefringence Trade‐Off: Proton‐Transfer Engineering of High‐Performance Ultraviolet‐Transparent Organic Crystal

    Angewandte Chemie · 2026-03-05

    Lin Qiu, Xing‐Yu Li, Bing-Wei Miao, Hongjian Yu, Wenlong Liu, Yifan Sun, Ru‐Ling Tang

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  3. (C 5 H 7 N 2 ) (C 8 H 4 O 4 ) PbBr: Jahn–Teller Distortion‐Induced Tilting of π‐Conjugated Planes Resolving the Second‐Order Polarizability–Structural Anisotropy Conflicts

    Angewandte Chemie · 2026-03-28

    Ming‐Yan Yu, Can Yang, Yun‐Jie Wang, Xin Yan Su, Jian Cui, Yao‐Long Zhu, Qing‐Wen Zhu, Qi Wu, Li‐Ming Wu, Ling Chen

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  4. Persistent Second‐Harmonic Generation Enhancement Across an Unprecedented Pressure Range in a Hybrid Antimony Halide

    Angewandte Chemie · 2026-04-01

    Wenbo Qiu, Weilong He, Xingxing Jiang, Yu Liu, Boyang Fu, Weizhao Cai

    Read original paper ↗ ·
  5. Electronegativity Adaption Approach for Solar‐Blind UV Birefringent Crystals With Ultrawide Bandgaps

    Angewandte Chemie · 2026-04-23

    Xinwei Zhou, Zhiyong Bai, Ji Qi, Yuexin Zhang, Weiqi Huang, Yipeng Song, Yong Wang, Chang Liu, Sangen Zhao, Junhua Luo

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  6. The Power of Pnictogen Bond: As─As Linkages Drive Wide Bandgap, Strong NLO Response and Large Birefringence in SrGa 3 Si 4 As 11

    Angewandte Chemie · 2026-04-26

    Hongshan Wang, Miriding Mutailipu, Shilie Pan, Junjie Li

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  7. Engineering Multiple Hydrogen‐Bond Sites With D‐π‐A Motifs for Strong Optical Nonlinearity and Giant Birefringence in Organic‐Inorganic Halides

    Angewandte Chemie · 2026-05-22

    Y Z Zhang, Yuchao Li, Y N Wu, Bing Teng, Hongting Lu, Xingxing Jiang, Shijia Sun, C Hu, Dongwei Zhai, Lifeng Cao, Jinkang Ma, R K Li, Degang Xu, Zheshuai Lin, Degao Zhong

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  8. Lock‐and‐Key Assembly Enables Record Birefringence in Monocyclic π‐Conjugated Crystals via Spatial Confinement of Linear Polyhalide

    Angewandte Chemie · 2026-05-26

    Yun‐Xia Hu, Huai Yu Wu, Jia‐jia Li, Ming‐Chang Wang, Jia‐Min Lian, Jin Yu Luo, Yiru Fu, Zi‐Yan Chen, Yang‐Hang Guo, Jin Chen, Ke‐Zhao Du

    Read original paper ↗ ·
  9. Lateral‐Site Unblocking Enables Bilateral π ‐Chromophore Organization for Giant Birefringence in One‐Dimensional Lead Hybrids

    Angewandte Chemie · 2026-08-07

    Yu Yan, Yingzi Zhang, Liyi Zhang, Ling Huang, Yuqiao Zhou, Xuehua Dong, Guohong Zou

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  10. Rational Construction of Fluoride Crystals With Record Birefringence via Water‐Regulated Hydrogen‐Bond Network Reconfiguration

    Angewandte Chemie · 2026-09-11

    Ru‐Ling Tang, Bing-Wei Miao, Ling Wang, Zheng-Yu Yang, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo

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  11. [La3Br][GeS4]2: Cationic-Moiety-Guided Strategy Enables Record Birefringence and Broad Optical Window

    Crystal Growth & Design · 2026-10-10

    Cuier Deng, Yuhan Hu, Ruixi Wang, Jingyu Guo

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