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RESEARCH PAPER · Materials Today Physics · 2024

Breaking through the ‘‘200 nm deep-ultraviolet wall’’ of phase matching region by cation structural modulation

Yi Zheng, Zhijun Wei, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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Breaking through the ‘‘200 nm deep-ultraviolet wall’’ of phase matching region by cation structural modulationOriginalEquivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Exploiting Deep‐Ultraviolet Nonlinear Optical Material Rb 2 ScB 3 O 6 F 2 Originated from Congruously Oriented [B 3 O 6 ] Groups61Exploiting Deep‐Ultraviolet Nonlinear Optical Material Rb 2 ScB 3 O 6 F 2 Originated from Congruously Oriented [B 3 O 6 ] Groups4Constructing Ultraviolet Nonlinear Optical Crystals with Superior Thermal Stability Based on Organic π-Conjugated [HCOO] Groups6K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response10Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates6Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+2层状结构深紫外非线性光学晶体研究进展（特邀）2混合阴离子无水无机硼酸盐深紫外非线性光学晶体的研究进展（特邀）4Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate14Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates4Assembly of Highly Polarizable “Linkers” with Heteroleptic Groups for Inducing Large Optical Anisotropy in Ba2SnIIGe3O8S and Ba3SnIIGe3O2S82K 2 GdB 3 O 6 F 2 : A Promising Short-Wave UV Birefringent Crystal via Optimized Assembly of π-Conjugated [B 3 O 6 ] Groups8Unlocking Advanced UV NLO Crystals in Rare‐Earth Metal Borate Fluorides via [B 3 O 6 ]‐Mediated Structural Modulation18Asymmetry-driven organic–inorganic hybrid strategy for constructing structures with exceptional organofunctionalized B–O units2K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit2REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 Units15Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances3Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances32Regulating B‐O Arrangement Boosts Anisotropy in a Simple Rubidium Borate, Leading to a High‐Performance UV NLO Crystal0Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates2A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials0

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27 direct citing papers saved.

  1. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  2. Exploiting Deep‐Ultraviolet Nonlinear Optical Material Rb 2 ScB 3 O 6 F 2 Originated from Congruously Oriented [B 3 O 6 ] Groups

    Angewandte Chemie International Edition · 2024-09-20

    Qianzhen Zhang, Ran An, Xifa Long, Zhihua Yang, Shilie Pan, Yun Mo Yang

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  3. Exploiting Deep‐Ultraviolet Nonlinear Optical Material Rb 2 ScB 3 O 6 F 2 Originated from Congruously Oriented [B 3 O 6 ] Groups

    Angewandte Chemie · 2024-09-20

    Qianzhen Zhang, Ran An, Xifa Long, Zhihua Yang, Shilie Pan, Yun Mo Yang

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  4. Constructing Ultraviolet Nonlinear Optical Crystals with Superior Thermal Stability Based on Organic π-Conjugated [HCOO] Groups

    Inorganic Chemistry · 2024-09-25

    Zhiyuan Lei, Fangrong Liu, Xuan Pang, Yuanxue Yi, Chunmei Huang, Tao Yang

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  5. K 15 La 7 (BO 3 ) 12 : A KBBF-Like Nonlinear-Optical Material with a Short Cutoff Edge and a Strong Second-Harmonic-Generation Response

    Inorganic Chemistry · 2024-12-07

    Fanlu Bu, Xiaorong Liu, Hongwei Yu, Runqing Liu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongping Wu

    Read original paper ↗ ·

  6. Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

    Inorganic Chemistry · 2024-12-17

    Yucheng Hao, Changlin Chen, Cheng Hou, S. Liu, Peng Zheng, Yuan Ching Lin, Haijian Li, Xi Zhao, Kisan Koirala, Hongdian Lu, Chonghai Deng, Kunhong Hu

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  7. Pb 2 B 10 O 16 (OH) 2 ·B(OH) 3 ·H 2 O: significantly enhanced second harmonic generation via substituting metal cations in isostructural compounds with Pb 2+

    Journal of Materials Chemistry C · 2025-01-01

    Xintong Cai, Kaitong Liu, Yanhui Zhang

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  8. 层状结构深紫外非线性光学晶体研究进展（特邀）

    Chinese Journal of Lasers · 2025-01-01

    彭广 Peng Guang, 韩言鸣 Han Yanming, 叶宁 Ye Ning

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  9. 混合阴离子无水无机硼酸盐深紫外非线性光学晶体的研究进展（特邀）

    Chinese Journal of Lasers · 2025-01-01

    贾行伟 Jia Hangwei, 陈柏霖 Chen Bailin, 安帅 An Shuai, 侯雪玲 Hou Xueling, 潘世烈 Pan Shilie

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  10. Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge

    Journal of Molecular Structure · 2025-04-08

    Xiaotian Ma, Shaohua Liu, Xifa Long, Yun Mo Yang

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  11. Achieving the birefringence-bandgap trade-off: Hydrogen-bond engineered biuret-cyanurate

    Chinese Journal of Structural Chemistry · 2025-07-29

    Ziqi Chen, Miriding Mutailipu

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  12. Research on Nonlinear Optical Materials Based on BO 3 and BO 4 Hydroxy Tetraborates

    Advanced Optical Materials · 2025-09-15

    Shuai An, Bailin Chen, Fangfang Zhang, Xueling Hou, Shilie Pan

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  13. Assembly of Highly Polarizable “Linkers” with Heteroleptic Groups for Inducing Large Optical Anisotropy in Ba2SnIIGe3O8S and Ba3SnIIGe3O2S8

    Inorganic Chemistry · 2025-09-30

    Jiaxue Wang, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  14. K 2 GdB 3 O 6 F 2 : A Promising Short-Wave UV Birefringent Crystal via Optimized Assembly of π-Conjugated [B 3 O 6 ] Groups

    Inorganic Chemistry · 2025-10-14

    Mengru Liu, Huijian Zhao, Xianghao Kong, Ning Ye, Zhanggui Hu, Conggang Li

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  15. Unlocking Advanced UV NLO Crystals in Rare‐Earth Metal Borate Fluorides via [B 3 O 6 ]‐Mediated Structural Modulation

    Advanced Functional Materials · 2025-10-17

    Qianzhen Zhang, Ran An, Abudukadi Tudi, Jiongquan Chen, Xiaoqin Ma, Xifa Long, Zhihua Yang, Shilie Pan, Yun Mo Yang

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  16. Asymmetry-driven organic–inorganic hybrid strategy for constructing structures with exceptional organofunctionalized B–O units

    Inorganic Chemistry Frontiers · 2025-12-20

    Haoran Wang, chenxu li, Xue Bai, Qingyu Liu, Xueling Hou, Min Zhang

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  17. K 7 MgY 2 (B 5 O 10 ) 3 : a novel ultraviolet nonlinear optical crystal based on the [B 5 O 10 ] functional unit

    New Journal of Chemistry · 2026-01-01

    Haozhen Liu, Shiyu Du, Paipai Zhang, Jiawei Zhao, Yanna Chen, Donghai An

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  18. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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  19. Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 Units

    Advanced Functional Materials · 2026-01-10

    Hongkang Su, chenxu li, Jiahao Jiao, Zhihua Yang, Shilie Pan, Min Zhang

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  20. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  21. Strategic Oxygen‐Substitution in Perfluorinated Ce(IV) Coordination Frameworks Triggers Dual‐Wavelength Nonlinear Optical Materials With Exceptional Performances

    Angewandte Chemie International Edition · 2026-01-16

    Ru‐Ling Tang, Wen‐Ye Gao, Guo-Ren Zhu, Yang Chi, Liang Ma, Wenlong Liu, Sheng‐Ping Guo

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  22. Regulating B‐O Arrangement Boosts Anisotropy in a Simple Rubidium Borate, Leading to a High‐Performance UV NLO Crystal

    Small · 2026-06-07

    Bingliang Cheng, Wenjuan Ma, Junhua Zhang, Meng Cheng, Wenqi Jin, Zhihua Yang, Xifa Long, Shilie Pan, Yi Yang

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  23. Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates

    Advanced Functional Materials · 2026-07-10

    Huijian Zhao, Kangyan Fan, Conggang Li, Zelong Liu, Pifu Gong, Ning Ye, Zhanggui Hu

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  24. A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages

    Inorganic Chemistry · 2026-08-08

    Hanjing Huang, Huijian Zhao, Wenli Zhao, Xianchao Zhu, Ning Ye, Zhanggui Hu, Conggang Li

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  25. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie International Edition · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  26. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  27. Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials

    Small · 2026-10-11

    Haoran Wang, Haotian Qiu, chenxu li, Xue Bai, Qingyu Liu, Zhihua Yang, Min Zhang

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