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RESEARCH PAPER · Advanced Functional Materials · 2025

Unlocking Advanced UV NLO Crystals in Rare‐Earth Metal Borate Fluorides via [B 3 O 6 ]‐Mediated Structural Modulation

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Unlocking Advanced UV NLO Crystals in Rare‐Earth Metal Borate Fluorides via [B 3 O 6 ]‐Mediated Structural ModulationOriginalTransition metal (Co, Ni, Cu) 1-vinylimidazole templated borates as high-efficiency oxygen reduction catalysts for zinc–air battery0Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency1K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response1Dual‐Functional Ultraviolet Nonlinear Optics and Bright Luminescence Achieved in the First Fluorine‐Containing Hybrid Lone‐Pair Metal Mixed Halides8Crystal Growth, Structure and Optical Properties of (NH 4 ) 2 Mg(SO 4 ) 2 ·6H 2 O: A Crystal With a Wide Deep Ultraviolet Window0Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal0Entropy‐Driven Structural Modulation Enables High‐Efficiency Nonlinear Optical Performance in Defective Wurtzite Selenides2Breakthrough in High Quality LaBGeO 5 Crystal for Deep Ultraviolet Quasi-Phase Matching Application0K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals1Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates2Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Research advances in rare-earth nonlinear optical crystalline materials in 20250Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs0A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials0MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence0

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  1. Transition metal (Co, Ni, Cu) 1-vinylimidazole templated borates as high-efficiency oxygen reduction catalysts for zinc–air battery

    Dalton Transactions · 2026-01-01

    Jiayue Yuan, Zhen-Ping Liao, Bo-Wei Liao, Chun‐Yang Pan

    Read original paper ↗ ·
  2. Li 6 Lu(BO 3 ) 3 : A Rare-Earth Borate Crystal Exhibiting Large Birefringence and Broad UV Transparency

    Inorganic Chemistry · 2026-02-05

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

    Read original paper ↗ ·
  3. K 3 YGe 3 O 9 : A Rare-Earth Germanate Nonlinear Optical Crystal with a Short Ultraviolet Cutoff Edge and Moderate Second-Harmonic Generation Response

    Inorganic Chemistry · 2026-03-12

    Mingyue Gu, Xianchao Zhu, Zhanggui Hu, Yicheng Wu, Yongmin Guo

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  4. Dual‐Functional Ultraviolet Nonlinear Optics and Bright Luminescence Achieved in the First Fluorine‐Containing Hybrid Lone‐Pair Metal Mixed Halides

    Advanced Functional Materials · 2026-03-25

    Jiajing Wu, Yu‐Qi Xu, Wen‐Dong Yao, Zhen‐Cheng Wu, Yi-Fan Fu, Ruo‐Nan Li, Yu‐Mei Zhang, Qiao‐Feng Huang, Sheng‐Ping Guo

    Read original paper ↗ ·
  5. Crystal Growth, Structure and Optical Properties of (NH 4 ) 2 Mg(SO 4 ) 2 ·6H 2 O: A Crystal With a Wide Deep Ultraviolet Window

    ChemistrySelect · 2026-04-01

    Ling Chen, Qianzhen Zhang, Xifa Long, Yun Mo Yang

    Read original paper ↗ ·
  6. Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-05-01

    Wenbin Zhang, Wenqi Jin, X. Ma, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

    Read original paper ↗ ·
  7. Entropy‐Driven Structural Modulation Enables High‐Efficiency Nonlinear Optical Performance in Defective Wurtzite Selenides

    Laser & Photonics Review · 2026-05-07

    Jian Cheng, Mao‐Yin Ran, Zi-Nan Chen, Sheng‐Ping Guo

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  8. Breakthrough in High Quality LaBGeO 5 Crystal for Deep Ultraviolet Quasi-Phase Matching Application

    ACS Applied Materials & Interfaces · 2026-06-29

    Jiahao Wang, Lingfei Lv, Rongbing Su, Z G Zhu, Hongjiang Wu, Hongyuan Sha, Zujian Wang, Bin Su, Chao He

    Read original paper ↗ ·
  9. K 3 Yb 2 (BO 3 ) 3 and Rb 3 Yb 2 (BO 3 ) 3 : Two Rare-Earth Borate Ultraviolet Nonlinear Optical Crystals

    Inorganic Chemistry · 2026-07-02

    Jingjing Xu, Huili Zhang, Xuemei Shi, Xin Wen, Jingyao Lu, Jindong Chen, Chensheng Lin, Ning Ye, Guang Peng

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  10. Covalent Interlayer Engineering Enables Ideal Birefringence and Strong SHG in Beryllium‐Free Deep‐UV NLO Borates

    Advanced Functional Materials · 2026-07-10

    Huijian Zhao, Kangyan Fan, Conggang Li, Zelong Liu, Pifu Gong, Ning Ye, Zhanggui Hu

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  11. Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects

    Advanced Optical Materials · 2026-07-21

    Xiangran Kong, Jingdong Yan, Zi Wang, Hongwei Leng, Shichao Cheng, Sue Hao, Xiaoran Niu, Zuotao Lei, Chunhui Yang

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  12. Research advances in rare-earth nonlinear optical crystalline materials in 2025

    Journal of Rare Earths · 2026-07-21

    Tiantian He, Dandan Zhou, Fang Kong, Jianggao Mao

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  13. Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs

    Chinese Journal of Chemistry · 2026-08-03

    Linsen Wang, Qianzhen Zhang, Ran An, Zhihua Yang, Yun Yang, Xueyan Wu

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  14. A Rare-Earth Borophosphate Ultraviolet Nonlinear Optical Crystal Featuring P–O–P Linkages

    Inorganic Chemistry · 2026-08-08

    Hanjing Huang, Huijian Zhao, Wenli Zhao, Xianchao Zhu, Ning Ye, Zhanggui Hu, Conggang Li

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  15. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie International Edition · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  16. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  17. Three Rare‐Earth Metal Borates Synthesized via a Cation Substitution Strategy as Potential Zero‐Order Waveplate Materials

    Advanced Optical Materials · 2026-09-30

    Bailin Chen, Yaqi Jin, Hucai Yang, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  18. MAlB3O6F2 (M = Ca and Pb): Two New Fluoroaluminoborates Featuring π-Conjugated [BO3] and [AlO4F2] Units with Large Birefringence

    Crystal Growth & Design · 2026-10-02

    Yaozu Li, Chao Wei, Wenjing Zhang, Huiyi Zhang, Bo Zhao, Bingbing Zhang, Ying Wang

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