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RESEARCH PAPER · Advanced Functional Materials · 2026

Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 Units

Hongkang Su, chenxu li, Jiahao Jiao, Zhihua Yang, Shilie Pan, Min Zhang

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Constructing Deep‐Ultraviolet Nonlinear Optical Crystals via Synergistic Combination of Fluorinated Polyhedra and Polymerized BO 3 UnitsOriginalAchieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation1Structural engineering of α-BaEuBO 3 F 2 borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor0Boosting Ultraviolet Phase‐Matching Performance of B 3 O 7 ‐Based Systems via Synergistic Fluorination and Organic Modification Strategy1Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal0Record‐High Birefringence with Ultralow Dichroic Loss Realized by Cation‐Templated Engineering Ordered Assembly of Linear Birefringent‐Active Unit6Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation2A 3 Zr 2 (PS 4 )(P 2 S 7 ) 2 (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS 4 Tetrahedron and P 2 S 7 Dimer0Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures2Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals0Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs0Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates0Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures0Fluorination‐Driven Molecular Polarization Engineering in Hydroxyfluorooxoborates for Generating Strong Short‐Wavelength Nonlinear Optical Responses0Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials0

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15 direct citing papers saved.

  1. Achieving an optimal performance balance in UV nonlinear optical crystals via hydrogen-bond regulation

    Inorganic Chemistry Frontiers · 2026-01-01

    S AN, Yaqi Jin, Wenhu Wang, Bailin Chen, Zhihua Yang, Xueling Hou, Shilie Pan

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  2. Structural engineering of α-BaEuBO 3 F 2 borate oxyfluoride: circumventing concentration quenching for a highly efficient and thermally stable red phosphor

    Inorganic Chemistry Frontiers · 2026-01-01

    Huiyi Zhang, Li Li, Bo Zhao, Yaozu Li, Bingbing Zhang, Cuimiao Zhang, Guang Jia, Ying Wang

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  3. Boosting Ultraviolet Phase‐Matching Performance of B 3 O 7 ‐Based Systems via Synergistic Fluorination and Organic Modification Strategy

    Advanced Optical Materials · 2026-04-01

    Xueli Du, Haoran Liu, Wenhu Wang, Haoran Wang, Xueyan Wu, Min Zhang

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  4. Charge Compensation via Heterovalent Cation Disorder for Birefringence Modulation to Design UV Nonlinear Optical Crystal

    Advanced Optical Materials · 2026-05-01

    Wenbin Zhang, Wenqi Jin, X. Ma, Zhihua Yang, Fangfang Zhang, Shujuan Han, Shilie Pan

    Read original paper ↗ ·

  5. Record‐High Birefringence with Ultralow Dichroic Loss Realized by Cation‐Templated Engineering Ordered Assembly of Linear Birefringent‐Active Unit

    Advanced Functional Materials · 2026-05-22

    Jing‐Jing Zhao, Q Zhang, Shu‐Fang Li, Honggang Gu, Shiyuan Liu, Hongbo Huang, Bingbing Zhang, Dong Yan

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  6. Deep-Ultraviolet Transparent Zr/Hf Fluorides with Second-Harmonic Generation Effects Induced by Alkali-Metal Modulation

    Inorganic Chemistry · 2026-06-26

    Ling Wang, Mei Yan, Min Li, Zheng-Yu Yang, X X Li, Wenfeng Zhou, Ru‐Ling Tang

    Read original paper ↗ ·

  7. A 3 Zr 2 (PS 4 )(P 2 S 7 ) 2 (A = K, Rb, Cs) Synthesized by the Metal Oxide-Boron-Chalcogen Routine: A Series of Zirconium-Based Thiophosphate Nonlinear Optical Crystals Featuring PS 4 Tetrahedron and P 2 S 7 Dimer

    Inorganic Chemistry · 2026-07-01

    Zi-Nan Chen, Zong-Ze Li, Ning Wang, Jian Cheng, Zhen‐Cheng Wu, Feng Qiu, Mao‐Yin Ran, Sheng‐Ping Guo

    Read original paper ↗ ·

  8. Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures

    Progress in Materials Science · 2026-07-09

    Zhihua Yang, Shilie Pan

    Read original paper ↗ ·

  9. Parallel arrangement of functional building blocks: toward performance synergy in oxalate borate ultraviolet nonlinear optical crystals

    Science China Chemistry · 2026-07-13

    Juhui Cui, Minqiang Gai, Ke Li, Z L Yang, Xueling Hou, Shilie Pan, Miriding Mutailipu

    Read original paper ↗ ·

  10. Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects

    Advanced Optical Materials · 2026-07-21

    Xiangran Kong, Jingdong Yan, Zi Wang, Hongwei Leng, Shichao Cheng, Sue Hao, Xiaoran Niu, Zuotao Lei, Chunhui Yang

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  11. Fluorine‐Driven Chemical Scissor Effect in Scandium Borates: Structural Evolution with Retained Optically Active Motifs

    Chinese Journal of Chemistry · 2026-08-03

    Linsen Wang, Qianzhen Zhang, Ran An, Zhihua Yang, Yun Yang, Xueyan Wu

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  12. Symmetry Breaking Induced by Hydration-Number Tuning Enables Second-Order Nonlinear Optical Responses in Lanthanum Sulfate Hydrates

    Inorganic Chemistry · 2026-08-04

    Xiuying Zhang, Yebiao Wu, Qiya Huang, Lehui Liu, Peican Chen, Hongming Liu

    Read original paper ↗ ·

  13. Rational Design of a Strong Nonlinear Optical Crystal With Ultrawide Bandgap via Fine‐Tuning of Channel Structures

    Laser & Photonics Review · 2026-08-15

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xin-Tao Wu

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  14. Fluorination‐Driven Molecular Polarization Engineering in Hydroxyfluorooxoborates for Generating Strong Short‐Wavelength Nonlinear Optical Responses

    Advanced Functional Materials · 2026-10-09

    Hongkang Su, Juhui Cui, chenxu li, Xiaona Li, Minqiang Gai, Zhihua Yang, Shilie Pan, Min Zhang

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  15. Cation‐Regulated [CH 3 BO 2 F]‐Derived Borates: Synergistic Fluorination and Organic Functionalization for High‐Birefringence UV NLO Materials

    Small · 2026-10-11

    Haoran Wang, Haotian Qiu, chenxu li, Xue Bai, Qingyu Liu, Zhihua Yang, Min Zhang

    Read original paper ↗ ·
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