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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2024

[Sn 3 OF]PO 4 vs. [Sn 3 F 3 ]PO 4 : enhancing birefringence by breaking the R 3 symmetry and realigning lone pairs

Yuhan Hu, Xi Xu, Ruixi Wang, Jingyun Han, Shunsong Zhang, Shuhui Zhan, Jingyu Guo, Li‐Ming Wu, Ling Chen

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[Sn 3 OF]PO 4 vs. [Sn 3 F 3 ]PO 4 : enhancing birefringence by breaking the R 3 symmetry and realigning lone pairsOriginalStrategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence12Tin chalcohalide Sn 11 (PS 4 ) 4 I 10 obtained from structural-template-oriented synthesis: exhibiting balanced infrared nonlinear optical performance6A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups12Phase transition engineering to break the symmetry of diamond-like chalcogenide for second-order nonlinear optics2Selenoborates: a latent structure resource for infrared functional crystal materials1Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency10Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy16NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1(NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance1Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides0Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy0

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12 direct citing papers saved.

  1. Strategically designed anisotropic organic–inorganic metal halides (OIMHs) with superior balance between bandgap and birefringence

    Inorganic Chemistry Frontiers · 2024-12-16

    Mingchang Wang, Huaiyu Wu, Miao‐Bin Xu, Jiajia Li, Ke‐Zhao Du, Jin Chen

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  2. Tin chalcohalide Sn 11 (PS 4 ) 4 I 10 obtained from structural-template-oriented synthesis: exhibiting balanced infrared nonlinear optical performance

    Inorganic Chemistry Frontiers · 2024-12-19

    Cuier Deng, Xi Qing Xu, Yuhan Hu, Jingyu Guo, Li‐Ming Wu, Ling Chen

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  3. A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence

    Dalton Transactions · 2025-01-01

    Hongheng Chen, Xudong Leng, Mei Hu, Yibo Han, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  4. Hg 2 (HTe 2 O 5 )(PO 4 ): a novel phosphate crystal with enhanced birefringence enabled by the synergistic modification of multiple functional groups

    Inorganic Chemistry Frontiers · 2025-01-01

    Pengfei Li, Chun‐Li Hu, Bo Zhang, Jiang‐Gao Mao, Fang Kong

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  5. Phase transition engineering to break the symmetry of diamond-like chalcogenide for second-order nonlinear optics

    Inorganic Chemistry Frontiers · 2025-01-01

    Chunlan Tang, Aoge Yao, Wenhao Xing, Wenwen Jiang, Jian Tang, Lei Kang, Jieyun Wu, Wenlong Yin, Bin Kang

    Read original paper ↗ ·

  6. Selenoborates: a latent structure resource for infrared functional crystal materials

    Inorganic Chemistry Frontiers · 2025-01-01

    Yihan Yun, Abudukadi Tudi, Zhihua Yang, Guangmao Li, Shilie Pan

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  7. Dual Lone Pair Strategy for High Birefringence in Antimony(III)-Based Tellurite Sulfates with Short-Wave UV Transparency

    Inorganic Chemistry · 2025-01-24

    Jiale Xue, Shuyao Wang, Xiande Peng, Zhengyan Lin, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  8. Hg3(TeO3)2(NO3)2 and Hg3(Te2O5)2(NO3)2: The First Two Hg‐Based Tellurite Nitrate Unit‐Mixed Crystals with Large Optical Anisotropy

    Laser & Photonics Review · 2025-04-10

    Piao Tang, Xin Wen, Yuchen Yan, Cao Xue, Jindong Chen, Chensheng Lin, Min Luo, Ning Ye, Guang Peng

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  9. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  10. (NH4)Na3Zn4(PO4)4:An open-framework zincophosphate exhibiting well-balanced optical and thermal performance

    Journal of Molecular Structure · 2025-06-07

    Chen-Yuan Ma, Qiang Tu, Yu-Ming Pan, Pei De Han, Meihong Duan, Zhi Gang Fang

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  11. Reversal Enhancement of Birefringence by Stereochemically Active Lone Pairs in Sn(II)-Based Mixed Halides

    Crystal Growth & Design · 2025-07-11

    Xu Liu, Abudukadi Tudi, Junben Huang, Juanjuan Lu, Zhaofeng Wu

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  12. Pyrazinamide–IBr: an organic–inorganic hybrid crystal exhibiting giant optical anisotropy

    Dalton Transactions · 2026-01-01

    Meng-Fan Duan, Jiang‐Gao Mao, Bing‐Ping Yang

    Read original paper ↗ ·
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