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RESEARCH PAPER · Journal of the American Chemical Society · 2024

Homoatomic Polychalcogenide Nonlinear Optical Anionic Groups with Ultra-Large Optical Anisotropy

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Homoatomic Polychalcogenide Nonlinear Optical Anionic Groups with Ultra-Large Optical AnisotropyOriginalLaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups5Achieving Phase‐Matching in Nonlinear Optical Materials CsM 2 In 2 S 6 (M = Cd/In, Hg/In) by the Incorporation of Unprecedented Trigonal Planar MS 3 Motifs6BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect9Computer‐Aided Development of New Nonlinear Optical Materials38Computer‐Aided Development of New Nonlinear Optical Materials14Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units14BaFS: Birefringence Enhanced by the Transformation from Optical Isotropy to Anisotropy via Interlayer Anion Substitution8Can Low Structural Anisotropy Produce High Optical Anisotropy? Anomalous Giant Optical Birefringent Effect in PI4AlI4 in Focus11Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence54From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect14NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence20NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence6[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence18[TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence4Cd 7 I 12 Q·As 4 Q n (Q = S, Se; n = 3, 4): In Situ Alteration of Functional Molecules in Polar Metal Inorganic Framework Tailoring High‐Performance Infrared Nonlinear Optical Crystals9Research progress and future prospect of chalcogenides with large optical anisotropy46Synergistic Enhancement of Band Gap and Optical Anisotropy via Functional-Site Cosubstitution in Antiperovskite-Type Chalcohalides [Ba2K][X][MS4] (M = Ge, Si; X = Cl, Br)2CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction0Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation6Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation3A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)3KGdSiSe 4 and KGdGeSe 4 : two rare earth-based selenides with wide bandgaps and large nonlinear optical responses0KGdSiSe4 and KGdGeSe4: Two Rare Earth Metal-Based Selenides with Wide Bandgaps and Large Nonlinear Optical Responses0Optimized seeded-Bridgman growth and characterization of LiGaS 2 crystals0Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion6Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion11[Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency16[Ba2K][Br][SiS4]: An antiperovskite-type chalcohalide with simultaneously enhanced birefringence and band gap via cation-anion co-substitution0Bridging Motifs Induced Ordered Arrangement Contributing Large Birefringence for Hg 4 BiQ 2 Cl 5 (Q═S, Se)1Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates0

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  1. LaAgSiS4: Increasing Optical Birefringence in Rare Earth Chalcogenide by Addition of Planar [AgS3] Groups

    Inorganic Chemistry · 2024-10-25

    Linfeng Dong, Bohui Xu, Deshuai Xiao, Fan Liu, Xinyuan Zhang, Xuanlin Pan, Pifu Gong, Zheshuai Lin

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  2. Achieving Phase‐Matching in Nonlinear Optical Materials CsM 2 In 2 S 6 (M = Cd/In, Hg/In) by the Incorporation of Unprecedented Trigonal Planar MS 3 Motifs

    Small · 2024-11-19

    Lin‐Tao Jiang, Yi‐Bing Huang, Shao‐Min Pei, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  3. BaPb2(CO3)2F2: Enhancing Birefringence by a Multiunit Synergy Effect

    Inorganic Chemistry · 2024-12-02

    Yuan Hua Lin, Rongfang Zhang, Yucheng Hao, Ming-Yang Cao, Xuanlin Pan, Jiang‐Gao Mao

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  4. Computer‐Aided Development of New Nonlinear Optical Materials

    Angewandte Chemie International Edition · 2024-12-05

    Hongshan Wang, Miriding Mutailipu, Zhihua Yang, Shilie Pan, Junjie Li

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  5. Computer‐Aided Development of New Nonlinear Optical Materials

    Angewandte Chemie · 2024-12-05

    Hongshan Wang, Miriding Mutailipu, Zhihua Yang, Shilie Pan, Junjie Li

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  6. Hg4InS2Cl5: Achieving Giant Optical Anisotropy by Introducing Well‐Aligned Linear [Hg2S2] Units

    Advanced Optical Materials · 2024-12-13

    Qixian Ren, Yu Chu, Wenqi Jin, Mengmeng Chen, Cui Chen, Yabo Wu, Shilie Pan

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  7. BaFS: Birefringence Enhanced by the Transformation from Optical Isotropy to Anisotropy via Interlayer Anion Substitution

    Small · 2025-01-14

    Chao‐Hong Xie, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  8. Can Low Structural Anisotropy Produce High Optical Anisotropy? Anomalous Giant Optical Birefringent Effect in PI4AlI4 in Focus

    Journal of the American Chemical Society · 2025-01-14

    Huige Chen, Pifu Gong, Zheshuai Lin, Lei Kang

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  9. Na[B3IO7(OH)] and Na2[B4IO9](IO3): Explorations of Boroiodates with Strong Second Harmonic Generation Response and Large Birefringence

    Journal of the American Chemical Society · 2025-04-07

    Ya-Lan Deng, Chun‐Li Hu, Xiang Xu, Mingzhi Zhang, Jiang‐Gao Mao

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  10. From AgHgI(SO4) to AgHg3I3.2Cl1.8(SO4): Symmetry Breaking of the Belousovite‐Type Topology by Mixed Halides to Achieve Strong Nonlinear Optical Effect

    Laser & Photonics Review · 2025-04-30

    Qian‐Qian Chen, Ming‐Zhi Zhang, Jin Chen, Bingxuan Li, Chun‐Li Hu, Jiang‐Gao Mao

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  11. NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence

    Angewandte Chemie International Edition · 2025-05-29

    Wenli Zhao, Rui‐Xi Wang, Shuang Zhao, Li‐Ming Wu, Ling Chen

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  12. NbGa 2 S 4 (S 2 ): A Rare Linear [S 2 ] 2− Coordination to Niobium Resulting in Simultaneously Large SHG Effect and Giant Birefringence

    Angewandte Chemie · 2025-05-29

    Wenli Zhao, Rui‐Xi Wang, Shuang Zhao, Li‐Ming Wu, Ling Chen

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  13. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie International Edition · 2025-06-17

    Bo Zhang, Wei‐Qi Huang, Jiaxiang Zhang, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  14. [TeSeS 2 ] 2− : The First Heterotriple‐Chalcogenide Motifs Decode Giant Mid‐Far Infrared Birefringence

    Angewandte Chemie · 2025-06-17

    Bo Zhang, Wei‐Qi Huang, Jiaxiang Zhang, Xintao Wu, Hua Lin, Qi‐Long Zhu

    Read original paper ↗ ·
  15. Cd 7 I 12 Q·As 4 Q n (Q = S, Se; n = 3, 4): In Situ Alteration of Functional Molecules in Polar Metal Inorganic Framework Tailoring High‐Performance Infrared Nonlinear Optical Crystals

    Laser & Photonics Review · 2025-06-20

    Huikang Jiang, Xuemei Shi, Lihua Gao, Guangsai Yang, Guang Peng, Ning Ye, Jindong Chen

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  16. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  17. Synergistic Enhancement of Band Gap and Optical Anisotropy via Functional-Site Cosubstitution in Antiperovskite-Type Chalcohalides [Ba2K][X][MS4] (M = Ge, Si; X = Cl, Br)

    Inorganic Chemistry · 2025-08-26

    Yong‐Fang Shi, Shenghua Zhou, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  18. CsGaGe₃Se₈: Enhanced optical anisotropy and bandgap via cation-substitution-driven dimensionality reduction

    Inorganic Chemistry Communications · 2025-10-01

    Yue Wang, Rongfang Jiang, Zihao Lou, Yong‐Fang Shi

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  19. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie International Edition · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

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  20. Structural Symmetry and Mixed‐anion Engineering in Halopnictides for Extraordinary Second‐Harmonic Generation

    Angewandte Chemie · 2025-12-18

    Yi‐Bing Huang, Bin‐Wen Liu, Wei Wu, Xiao‐Ming Jiang, Xiyue Cheng, Guo‐Qiang Wang, Guo‐Cong Guo

    Read original paper ↗ ·
  21. A Homoatomic Heteroleptic Coordination Strategy for Exceptional Infrared Linear and Nonlinear Optical Properties in ANb 2 PS 4 (S 2 ) 3 (A = K,Rb,Cs)

    Inorganic Chemistry · 2025-12-31

    Yumiao Niu, Yan Chun Xiao, Yidan Chen, Chu Chu, Daqing Yang, Ying Wang, Bingbing Zhang

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  22. KGdSiSe 4 and KGdGeSe 4 : two rare earth-based selenides with wide bandgaps and large nonlinear optical responses

    Dalton Transactions · 2026-01-01

    Zhenglong Li, Guansong Zheng, Chen Bai, Leyan Nian, Shilie Pan, Junjie Li

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  23. KGdSiSe4 and KGdGeSe4: Two Rare Earth Metal-Based Selenides with Wide Bandgaps and Large Nonlinear Optical Responses

    SSRN Electronic Journal · 2026-01-01

    Zhenlong Li, Guansong Zheng, Chen Bai, Leyan Nian, Shilie Pan, Junjie Li

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  24. Optimized seeded-Bridgman growth and characterization of LiGaS 2 crystals

    CrystEngComm · 2026-01-01

    Chao Ma, Xingguang Li, Shilei Wang, Shuai Liu, Xuan Wang, Zerui Li, Shanpeng Wang

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  25. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

    Angewandte Chemie · 2026-01-05

    Meng‐Na Jing, Si‐Fan Lu, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  26. Realizing Phase‐Matching of Nonlinear Optical [ABa 3 Br 2 ][Ga 5 Se 10 ] (A = Cs, Rb, K, Na) Through Large Anisotropic Lattice Distortion

    Angewandte Chemie International Edition · 2026-01-05

    Meng‐Na Jing, Si‐Fan Lu, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  27. [Hg3Se2]2- cluster drives giant optical anisotropy and broad infrared transparency

    Nature Communications · 2026-01-06

    Qixian Ren, Chen Cui, Xinchen Chen, Yabo Wu, Ran An, Zhihua Yang, Shilie Pan

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  28. [Ba2K][Br][SiS4]: An antiperovskite-type chalcohalide with simultaneously enhanced birefringence and band gap via cation-anion co-substitution

    Inorganic Chemistry Communications · 2026-03-10

    Yue Wang, Hua Wang, Rongfang Jiang, Yongfang Shi

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  29. Bridging Motifs Induced Ordered Arrangement Contributing Large Birefringence for Hg 4 BiQ 2 Cl 5 (Q═S, Se)

    Small · 2026-06-02

    Zhen‐Cheng Wu, Chang‐Hong Li, Yu‐Xuan Zhang, Mao‐Yin Ran, Sheng‐Ping Guo

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  30. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie International Edition · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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  31. Chiral Supramolecular Templating Enables Tunable Second‐Harmonic Generation in Hybrid Zinc Thiocyanates

    Angewandte Chemie · 2026-08-19

    Xuemei Wen, Qinglan Zhong, Gangji Yi, Guohong Zou, Jianli Wang, Zhien Lin, Kang Min Ok

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