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RESEARCH PAPER · Chemical Communications · 2025

[C(NH 2 ) 3 ] 2 [C 2 H 5 (C 2 O 4 )]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifs

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[C(NH 2 ) 3 ] 2 [C 2 H 5 (C 2 O 4 )]Cl: rational design of a metal-free UV birefringent crystal through the synergistic assembly of three distinct motifsOriginal[Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence0Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution0Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups0From [C(NH2)3]2[Sn2(C2O4)3]·2H2O to [C(NH2)3]4[Sn(C2O4)2]2·H2O: Uneven-substitution-activated polar stannous oxalate with balanced bandgap and birefringence0Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects3

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  1. [Cd 4 P 2 ][I 3 ] and [Cd 2 P][CdCl 3 ]: two Millon's phase phosphides exhibiting wide band gaps and large birefringence

    Dalton Transactions · 2026-01-01

    Fupeng Wang, Guang Peng, Ning Ye, Jindong Chen

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  2. Counterion engineering in open-framework crystals: dual enhancement of birefringence and UV transparency in Cd–oxalate framework via cation substitution

    CrystEngComm · 2026-01-01

    Chenyuan Ma, Jingyi Xie, Zhi Fang, Meihong Duan

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  3. Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups

    Dalton Transactions · 2026-01-01

    Haowen Li, X Y Wang, Hui Chai, Fangfang Zhang

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  4. From [C(NH2)3]2[Sn2(C2O4)3]·2H2O to [C(NH2)3]4[Sn(C2O4)2]2·H2O: Uneven-substitution-activated polar stannous oxalate with balanced bandgap and birefringence

    Journal of Molecular Structure · 2026-01-25

    Yin-Jie Peng, Xin-Ting Zhu, P. L. Li, Zhi Fang, Meihong Duan

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  5. Halogen Anion-Mediated Substitution of Nitrate: Toward Polar Materials with Intense Second-Harmonic Generation Effects

    Inorganic Chemistry · 2026-03-09

    Zheng-Yu Yang, Ming-Yang Cao, Liang Ma, Bing-Wei Miao, Xing-Yu Li, Wenfeng Zhou, Ru‐Ling Tang

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