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RESEARCH PAPER · Chemistry of Materials · 2024

KPO2(NHCONH2)2: A Promising Deep-Ultraviolet Nonlinear Optical Phosphate Containing Polar [PO2(NHCONH2)2]− Tetrahedra

Fuhai Chen, Fuxiang Mo, Hongming Chen, Mei‐Jin Lin, Yong Chen

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KPO2(NHCONH2)2: A Promising Deep-Ultraviolet Nonlinear Optical Phosphate Containing Polar [PO2(NHCONH2)2]− TetrahedraOriginalDesigning promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)4MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction1Functional assembly and modification of nonlinear optical fundamental motifs in phosphates27层状结构深紫外非线性光学晶体研究进展（特邀）2NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence1[CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy15All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials4(C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence0Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity0Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence1Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications5Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly1Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures2

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  1. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

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  2. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

    Advanced Optical Materials · 2024-08-29

    Haotian Qiu, Ran An, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  3. Structure and optical properties of alkali rare-earth double phosphates of M3RE(PO4)2 (M = K, Rb; RE = Y, La, and Lu)

    Optical Materials · 2024-10-13

    Qun Jing, Mei Hu, Menglin Zhu, Jialong Wang, Haiming Duan, Zhaohui Chen

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  4. MgPO2F3: An Ultraviolet Nonlinear Optical System with an Extremely Short Phase-Matching Wavelength Achieved by Introducing Dual-Type Fluorine via Structure Prediction

    The Journal of Physical Chemistry C · 2024-11-26

    Xue Bai, Xin Su, Wenqi Jin

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  5. Functional assembly and modification of nonlinear optical fundamental motifs in phosphates

    Coordination Chemistry Reviews · 2024-11-27

    Fan Liu, Pifu Gong, Zheshuai Lin, Lei Kang

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  6. 层状结构深紫外非线性光学晶体研究进展（特邀）

    Chinese Journal of Lasers · 2025-01-01

    彭广 Peng Guang, 韩言鸣 Han Yanming, 叶宁 Ye Ning

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  7. NH4PO3HCH3 and NH4PO3CH2NH3: Two Phosphate Derivatives with Deep-UV Cutoff Edges and Moderate Birefringence

    Inorganic Chemistry · 2025-05-01

    Chenhui Hu, Jiale Qu, Jinghui Hu, Junjie Liu, Wenchao Hu, Xiangzhan Jiang

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  8. [CON3H6BF4]: An Efficient Metal‐Free Borate with Optimized Birefringence Achieved by Structural Design Strategy

    Small · 2025-05-23

    Muhammad Arif, Xu Liu, Hangwei Jia, Zhihua Yang, Xueling Hou, Shilie Pan

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  9. All-three-in-one: Pb2(H2PO4)2(C2O4) significantly enhanced birefringence in phosphate materials

    Science China Chemistry · 2025-05-28

    Qingpeng Shao, Qingran Ding, Yanqiu Zhang, Weiqi Huang, Zihao Yu, Yipeng Song, Chengmin Ji, Ziyi Wang, Sangen Zhao, Junhua Luo

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  10. (C 4 H 8 N 5 )(PhPHO 2 )·H 2 O: a polar ionic cocrystal with strong second-harmonic generation and high birefringence

    Journal of Materials Chemistry C · 2026-01-01

    Peng Zhuang, Bing‐Ping Yang, Jiang‐Gao Mao

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  11. Two hydrated ionic cocrystals of phenylphosphonate exhibiting second-harmonic generation and proton conductivity

    Materials Chemistry Frontiers · 2026-01-01

    Peng Zhuang, Chun‐Li Hu, Bing‐Ping Yang, Jiang‐Gao Mao

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  12. Cd[C(NH 2 ) 2 O] 2 Cl 2 : A Urea-Based Open-Framework Crystal with Concurrent Short UV Cutoff Edge and Large Birefringence

    Inorganic Chemistry · 2026-03-03

    Chenyuan Ma, Xin-Mei Zeng, Jia-Tong Li, Xing-Yu Bi, Zhi Gang Fang, Meihong Duan

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  13. Recent Progress in Hg-Based Oxysalt Crystals for Nonlinear Optics and Birefringence Applications

    Inorganic Chemistry · 2026-04-15

    Peng-Fei Li, Y Wang, Naifeng Zhuang, Jiannian Yao, Yu‐Wu Zhong

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  14. Strong Optical Nonlinearity in Polar Hypophosphites via Chiral Cation Assembly

    Chemistry of Materials · 2026-04-21

    Yiran Zhang, Qiao Xia, Xiaotian Zhang, Zhipeng Huang, Mark Graeme Humphrey, Liming Cheng, Kasper Moth‐Poulsen, C L Zhang, Chao Wu

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  15. Toward the vacuum-ultraviolet frontier in nonlinear optical frequency conversion: phase-matching mechanisms across dimensions and architectures

    Progress in Materials Science · 2026-07-09

    Zhihua Yang, Shilie Pan

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