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RESEARCH PAPER · Advanced Functional Materials · 2023

Limitations of the Tauc Plot Method

Julian Klein, Laura Kampermann, Benjamin Mockenhaupt, Malte Behrens, Jennifer Strunk, Gerd Bacher

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Limitations of the Tauc Plot MethodOriginalFacile aqueous synthesis and comparative evaluation of TiO 2 -semiconductor and TiO 2 -metal nanohybrid photocatalysts in antibiotics degradation under visible light18Facile Preparation of the ZnSe/Ag2Se Binary Heterojunction for Photocatalytic Antibacterial Efficiency30Luminescence in Anion-Deficient Hafnia Nanotubes72D/1D PbI 2 /Sb 2 S 3 van der Waals heterojunction for highly sensitive and broadband photodetectors11A bifunctional primitive strategy induces enhancements of large second harmonic generation and wide UV transmittance in rare-earth borates containing [B 5 O 10 ] groups22Anion exchange membrane water electrolysis over superparamagnetic ferrites8Fabrication and characterisation of a flexible thermoelectric generator using PANI/graphite/bismuth telluride composites15Metal–support interactions in metal oxide-supported atomic, cluster, and nanoparticle catalysis414Nanostructured CeO 2 photocatalysts: optimizing surface chemistry, morphology, and visible-light absorption52Novel A-π-D-A organic dyes for better photovoltaic performance18Strong electron–phonon coupling in vacancy-ordered Cs 2 SnBr 6 double perovskite18Creation of molecular-level surface active centers on polymeric carbon nitride for boosting selectively photocatalytic CO2 reduction to CO13Harnessing light energy: Electrodeposited ZnO:ZnMn2O4 nano-heterojunction as promising electrode for photo-rechargeable supercapacitors29NIR‐Excitable POM‐Encapsulated Yb‐Bi 2 S 3 Decorated Graphene for Wearable Photoelectrochemical Sensing49Localized surface plasmon resonance sensing of Trenbolone acetate dopant using silver nanoparticles37Efficient photocatalytic hydrogen generation by CeCO3OH/TiO2 composites18BiOCl/BiOBr composites for efficient photocatalytic carbon dioxide reduction21A Photoelectrochemical Sensor for Real-Time Monitoring of Neurochemical Signals in the Brain of Awake Animals22Exploring secondary optical transitions: a study utilizing the DITM method, and enhanced photocatalytic properties in Ni-doped CuSe14Wavelength-dependent activity screening of reduced titania for photocatalytic degradation of imidacloprid in batch and flow-mode9Isolating the optical response of a MoS 2 monolayer under extreme screening of a metal substrate9Copper nanoclusters-doped novel carrier with synergistic adsorption-catalytic active sites to enable high-performance dye removal10High performance near ultraviolet ray detector by cluster-wrapped surface structure in ferroelectrics19BiVO4/CuIn5S8 heterojunction with rich sulphur vacancies for boosting visible light-driven photocatalytic water oxidation9Zirconium Oxynitride Thin Films for Photoelectrochemical Water Splitting16Preparation of wide bandgap CuGaSe2 absorbers and solar cells by sputtering a selenium-rich ceramic target and annealing in a selenium-free atmosphere47Construction of Bi2WO6/g-C3N4/Cu foam as 3D Z-scheme photocatalyst for photocatalytic CO2 reduction32Advancing SeNP synthesis: Innovative confined environments for enhanced stability and size control12Electronic and optical properties of the fully and partially inverse CoFe 2 O 4 spinel from first principles calculations including many-body effects12Enhanced CO2 photoreduction to CH4 via *COOH and *CHO intermediates stabilization by synergistic effect of implanted P and S vacancy in thin-film SnS238Reactive DC Sputtered TiO 2 Electron Transport Layers for Cadmium‐Free Sb 2 Se 3 Solar Cells24High Thermoelectric Performance in Rhombohedral GeSe-LiBiTe 232Determining bandgap from simulated absorbance: The Tauc approach13Electronic states near surfaces and interfaces of β-Ga2O3 and κ-Ga2O3 epilayers investigated by surface photovoltage spectroscopy, photoconductivity and optical absorption7Unveiling the role of ZrO2 doping in SrSmTiNbO ceramics: From structural study to dielectric enhancement9Electronic phase transitions and superconductivity in ferroelectric S n 2 P 2 S e 6 under pressure7Enhanced photocatalytic activity of Cr-doped CaTiO3 particles synthesized by solid state reaction route10An ultraviolet photodetector based on In2O3/β-Ga2O3 heterojunction20Interplay between the heat treatment and structural and optical properties of Nb2O5 thin films10Construction of Dual Active Sites in Perovskite Oxide for Targeted Photocatalytic CO 2 Reduction to CH 443When the fate of electrons matters — strategies for correct heterojunction classification in photocatalysis15Structural and optical properties of green-synthesised tricobalt tetroxide nanoparticles11Novel boehmite and η-alumina nanostructures synthesized using a green ultrasonic-assisted hydrothermal method by clove extract for water treatment17A new look at an explanation of band gap of PECVD grown a-Si:H thin films using absorption spectra, spectroscopic ellipsometry, Raman, and FTIR spectrosopy9Tunability of Sb2Se3 phase change material for multi-domain optoelectronics16The physico-chemical and antimicrobial properties of nano ZnO functionalised tannic acid13MOF-derived high-entropy oxides (YTbDyErYb)2O3 for boosted non-contact physiological humidity monitoring induced by oxygen vacancy modulation11RETRACTED: The effect of GO content on the improvement of efficient water splitting applications in ZnO/GO nanocomposites13Bimetallic MOF@CdS nanorod composite for highly efficient piezo-photocatalytic CO2 methanation under visible light20Unveiling the application potential of PbMo0.75W0.25O4 crystal: Linear and nonlinear optical properties through ellipsometry20Hydroflux Synthesis and Structural Phase Transition of Rare‐Earth Borate Hydroxides Na2[RE(BO3)(OH)2] (RE=Y, Gd−Er)7Effect of TiO2 content on the thermal control properties of Al2O3-xTiO2 composite coatings prepared by supersonic plasma spraying technology58Realizing Near‐Unity Photoluminescence Quantum Yield in Metal Halide RbCdCl3:Mn2+ Crystals via Phase Transformation Engineering16Optimizing antibacterial photodynamic theraphy of biocompatible ZnO/Ag2O p-n heterojunction: In vitro and in silico study7Construction of floating photothermal-assisted S-scheme heterojunction with enhanced photocatalytic degradation of tetracycline: Insights into mechanisms, degradation pathways and toxicity assessment20Nickel oxide nanoparticles embedded in polymer-matrix nanocomposite prepared by nanosecond laser ablation method for optoelectronic applications9Two‐Dimensional Silver–Isocyanide Frameworks13Cu3BiS3 film synthesis through rapid thermal processing sulfurization of electron beam evaporated precursors8Synthesis of Au/Co3O4/PVA hybrid nanocomposites via eco-friendly method based on pulsed laser ablation process for water treatment16Precursor Development and Aerosol‐Assisted Chemical Vapour Deposition for BiVO 4 and W‐Doped BiVO 4 Photoanodes: A Universal Ligand Approach9Nanoparticles of Cs3Bi2Br9 Decorated on H2Ti3O7 Nanotubes for the Photocatalytic Oxidation of Hydroxymethylfurfural to 2,5-Furandicarboxaldehyde11Mid-gap levels induced near-infrared response and photothermal catalytic degradation of chlortetracycline hydrochloride by (SnFe2)Ox under solar light9Tannic Acid Selective Modulation Defects to Enhance the Photocatalytic CO2 Reduction Activity of Layered Double Hydroxides13Flexible conductive adhesives with high conductivity and infrared stealth performance8Inkjet-Printed FASn1–xPbxI3-Based Perovskite Solar Cells11Enhancing photocatalytic hydrogen production: A systematic approach to improving g-C3N4/TiO2 nano-composites16The impact of green chemistry to synthesize PVA/cobalt metal complexes (CoMCs) composites with enhanced optical behavior18Tailoring Optical Performance of Polyvinyl Alcohol/Crystal Violet Band-Pass Filters via Solvent Features7Releasing trapped excitons in 2D perovskites via pressure annealing: a cooperative interplay between lattice strain and the electronic structure8Charge transport channel and nonmetallic plasmon synergistically augment surface reaction kinetics and charge separation for efficient photoelectrochemical hydrogen evolution of CdS/TiN-sensitized Fe2V4O13 photoanode19Molecular engineering of perylene diimide polymers to enhance photocatalytic performance for efficient photodegradation of ofloxacin13Effect of ultraviolet irradiation on contact electrification at liquid-solid interface9Enhancing the optical properties of chitosan-based biopolymer for optoelectronic applications using natural dye extracted from hollyhock waste flowers21Vapor-Assisted In Situ Synthesis of the Nb2CTxNS/NbO2F MXene Heterostructure for Enhanced Solar-Driven Photoelectrochemical Performance7High thermoelectric coefficients of β-Zn4Sb3 thin films at room temperature via chemical etching15In situ formed Se–TiO2 as a highly reusable photocatalyst for selenium reduction and removal from industrial wastewater7Surface Oxygen Vacancies on Copper-Doped Titanium Dioxide for Photocatalytic Nitrate-to-Ammonia Reduction116Visible light-driven copper vanadate/biochar nanocomposite for heterogeneous photocatalysis degradation of tetracycline: Performance, mechanism, and application of machine learning31Green beginnings: creating an affordable advanced enquiry-based experimental nanochemistry learning module with catalytically active ‘green’ iron oxide nanoparticles (IONPs)7Insights into photoelectrocatalytic lignin oxidation to value-added products using a niobium-doped titanium dioxide photoanode14Microwave shock-driven thermal engineering of unconventional cubic 2D LaMnO 3 for efficient oxygen evolution17Negative thermal quenching and optically stable Tb 3+ -doped tungstate phosphor for high temperature lighting and advanced thermometry applications15Optoelectronic characteristics and stability evaluation of Ba 2 TiMxO 6 (Mx = Ge, Sn, Se, Te) p-type semiconductors as candidates for functional layers in optoelectronic devices7Performance improvement of resistive switching memory achieved by reducing the size of MoS 2 embedded in poly(vinyl alcohol) films7Perovskite-inspired low-dimensional hybrid azetidinium bismuth halides: [(CH 2 ) 3 NH 2 ] 3 Bi 2 X 9 (X = I, Br, Cl)9Photoelectrochemical and optical fenton properties of Cu-doped ZnFe2O4 composites synthesized by hydrothermal method23Subgrid cage confinement engineering enabled ultra-efficient near-infrared Cr 3+ –Ln 3+ co-doped phosphors8Synthesis of TiO 2 –CuO@graphene oxide hybrid bionanocomposite with enhanced antibacterial and organic dye degradation activities18Carbon dots self-assembly enables near-infrared emission19Carbon Nanotubes as Emerging Field Emitters: Influencing Factors and Remedies12Annealing Strategy Toward Achieving High-Performance Indium Tungsten Oxide Thin-Film Transistors by Equilibrating Oxygen Vacancy and Chemisorbed Oxygen21Concentration-Dependent Control of the Band Gap Energy of a Low-Dimensional Lepidocrocite Titanate20Modulating e g Occupancy by A‐Site Vacancy to Boost Photocatalytic CO 2 Reduction on Perovskite Oxides14Intrinsic optical absorption of g-C3N4 thin films in ultraviolet range8Defect‐Engineered Biomimetic Piezoelectric Nanocomposites With Enhanced ROS Production, Macrophage Re‐polarization, and Ca 2+ Channel Activation for Therapy of MRSA‐Infected Wounds and Osteomyelitis38Harnessing Z-scheme charge transfer in SnS/ZnWO4 hybrid for efficient methylene blue photodegradation11Determination of the Urbach energy Eu and the optical band gap Eg of submicron C60 and C70 fullerene films7Self-grown photocatalytic metal-organic frameworks on electrocatalytic NiFe layered double hydroxides as bifunctional photoelectrocatalyst for efficient overall water splitting13Determination of the Band Gap Energy of SnO2 and ZnO Thin Films with Different Crystalline Qualities and Doping Levels34Tunable Hierarchically Porous Gadolinium‐Based Metal‐Organic Frameworks for Bacteria‐Targeting Magnetic Resonance Imaging and In Situ Anti‐Bacterial Therapy17Fabrication of Novel ZnO@Mn3C photocatalyst for organic pollutants degradation via peroxymonosulfate activation37Lighting the Path to Practical Applications of Single‐Atom Catalysts in Photocatalysis: The Role of Platinum Group Single Atoms in Enhancing Catalytic Activity9Iodide Ion‐Assisted Silver‐Telluride‐Based Nanowires: Morphology Optimization and Efficient Doping for Improved Thermoelectric Application7Evolution of structural and photoluminescent properties of sputter-deposited Ga2O3 thin films during post-deposition heat treatment10Recyclable ternary composite photocatalyst Fe3O4@mTiO2/carbon deficient g-C3N4 for efficient degrading sodium ethyl xanthate in mining wastewater8Visible active novel 3D/2D SrTiO3/Bi2MoO6 heterojunction catalysts for photocatalytic HER/OER and overall water splitting30Polyphenol‐Regulated Bimetallic Artificial Metalloproteinases with Broad‐Spectrum RONS Scavenging Activities for Diabetic Wound Repair26The Achievement of Pulse Laser Deposited Amorphous P-Type N-Doped Ga₂O₃ for Applying in Thin Film Transistor and Homojunction Diode8Low-temperature growth and characterization of β-Ga2O3 thin films by ECR-PEMOCVD7Tailoring annealing duration of gallium oxide film deposited by electron beam evaporation13Bipolar simultaneously quenching in polarity-switchable photoelectrochemical biosensor for sensing lead ion12Improved ammonia sensing performance of Nd-modified nano-BaTiO3 at room temperature7The effects of reduced graphene oxide amount on the photocatalytic performance of TiO2 nanoparticles for hydrogen evolution15The effect of simultaneous 3d transition bimetal doping (Ni/Mn, Co/Mn, Ni/Co) on the structural, optical and photocatalytic properties of ZnO based materials12Ultrasound-responsive MoS@Cu-MOF heterojunction scaffold: Enhancing bacterial membrane permeability, exhibiting efficient antibacterial activity and facilitating bone regeneration10Novel Z-scheme Cu2O@Ag/g-C3N4 heterojunctions: integrating ultrasensitive SERS detection with superior visible-light photocatalysis for tetracycline elimination15Thickness dependence of optoelectronic properties of gallium oxide film deposited by electron beam evaporation technique12Unraveling metastable perovskite oxides insights from structural engineering to synthesis paradigms17Agent free pillaring engineering of interlayer spacing of Ti3C2 MXene layers for energy conversion and photothermal desalination9A comparative analysis of numerical and experimental optimization of CuSbS₂ absorber layer thickness for improved solar cell performance7Shedding Light on Common Misinterpretations in Photocatalyst Characterization8Robust Imidazole‐Linked 2D Covalent Organic Frameworks for Efficient Electrochemical Sodium‐Ion Storage10Robust Imidazole‐Linked 2D Covalent Organic Frameworks for Efficient Electrochemical Sodium‐Ion Storage20Pb2CoMoO6 as a Promising Energy Material: A First-Principles Perspective14Au‐Modified SrTiO 3 Nanoarray Featuring Enhanced Ultrasound‐Responsive Mott–Schottky Heterojunction Speeds Bone Regeneration Through Sonodynamic Antibacterial and Inflammatory Management13Antimicrobial, photodegradation and BioReRAM applications of multifaceted green zinc oxide nanoparticles synthesized using coffee leaves extract8Sulfur Vacancy-Driven Polarization Electric Field in CdIn 2 S 4 Enhances CO 2 Photocatalytic Reduction by Facilitating *COOH Formation8Unleashing the effect of engineered high-performance S-scheme n–n–n heterojunction g-C3N4/SnO2/Bi2S3 as a dual photo-electrocatalyst for water splitting7Semiconductor Bandgap Measurements: Overview of Optical, Electrical, and Device‐Level Techniques23Site‐Selective Occupation of Mn 2+ Activators for Tunable Luminescence in Well‐Designed CaZnGe 2 O 6 Phosphors7Improved optical characteristics of PEO polymer integrated with graphene oxide16Piezo-photocatalytic coupling field driven efficient C2H4 synthesis: Proton-coupled electron transfer path optimization9Artificial Interfacial Quasi‐Electric Field: A Pathway to Promote Ga 2 O 3 Photodetectors16Sulfonated Module Aggregation for Ultrahigh Birefringence in Aqueous-Processable Crystals26Understanding the structural intricacies in carbon nitride materials through multimodal characterization: a critical review8Sustainable Photocatalytic Treatment of Real Pharmaceutical Wastewater Using a Novel ZnO/MIP-202(Zr) Bio-MOF Hybrid Synthesized via a Green Approach11Liquid Metal Interstitial Enhanced Energy Filtering Effect in PEDOT:PSS Fibers Enables High Thermoelectric Figure of Merit18Accurate determination of the band gap energy of non-translucent semiconductor materials through the Tauc method: Theoretical framework, limitations, technical hints, and automated algorithms30Nickel-doped VS 4 nanostructures as a promising candidate for nonlinear optical limiter application8Construction of a synergistic Z-scheme heterojunction for efficient piezo-photocatalytic hydrogen production via water splitting using NH2-MIL-101(Fe/Cr)@ZnO nanocomposite7Plasma-assisted green synthesis of SrTiO3/MoS2/MWCNTs nanohybrids for photocatalytic degradation of phenazopyridine in aqueous and smart polymeric film systems9Photocatalytic prospects of phyto-fabricated CeO2-rGO nanocomposite as an eco-friendly catalyst for detoxification of contaminated water11Double Organic‐Ligand Enabled Narrow‐Band Manganese Halides Toward Wide Gamut Displays, Flexible X‐Ray Detection, and 3D Printing Applications10Multiscale electronic structure engineering of transition metal oxides: From atomic-scale, mesoscale, and external-field manipulation to multifunctional applications10Type‐II Heterojunction Regulated BIEF Toward Nitride/Chalcogenide Semiconductors for Multi‐Polarization Relaxation30Enhanced g-C3N5/In2O3 nanophotocatalysts for rapid degradation of dyes and efficient hydrogen evolution: A synergistic strategy of S-Scheme heterojunctions and oxygen vacancies9Dy3+/Eu3+ co-doped Ca2InTaO6 phosphor for latent fingerprint visualization and anti-counterfeiting7Extraction of band gap energies and composition of mixed-phase polycrystalline semiconductors; a possible alternative method10Two‐Dimensional La 2 CoO 4 Perovskite Oxide Enabled by Phonon‐Resonance‐Driven Exfoliation for High‐Performance Gas Sensing17A self-powered wearable uric acid sensor for prolonged monitoring and intervene of hyperuricemia28

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  46. Electronic and optical properties of the fully and partially inverse CoFe 2 O 4 spinel from first principles calculations including many-body effects

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  47. Photoelectrochemical and photo-Fenton properties of ZnFe2O4@g-C3N4 nanocomposites

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  48. Unraveling Halogen Role in Two-Step Solution Growth of Organic–Inorganic Hybrid Mixed-Halide Perovskites: Guidelines of Fabricating Single-Phase Perovskites with Predictable Stoichiometry

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  49. Enhanced CO2 photoreduction to CH4 via *COOH and *CHO intermediates stabilization by synergistic effect of implanted P and S vacancy in thin-film SnS2

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