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RESEARCH PAPER · Inorganic Chemistry Frontiers · 2023

A UV solar-blind nonlinear optical crystal with confined π-conjugated groups

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A UV solar-blind nonlinear optical crystal with confined π-conjugated groupsOriginal[(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect60Achieving strong second harmonic generation effects induced via dimensional increase of PbX 6 octahedra and halogen substitutes in (C 10 H 11 N 3 )PbX 4 (X = Cl or Br)26Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks18Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material32Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units66Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement13Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective109Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates6A HTO‐Type Nonlinear Optical Fluorophosphate with Ultrawide Bandgap16Exploiting Rigid Inorganic π‐Conjugated Units and Deprotonatable Organic π‐Conjugated Dimers for Enhanced Linear and Nonlinear Optical Properties9Non-centrosymmetric ZnSO4·Zn(OH)2: synthesis, crystal structure, and its applications towards photocatalytic methylene blue degradation and solvent-free Knoevenagel condensation reaction1Computational design of new DUV NLO fluorooxoborates with [BO 3 ] : [BO 3 F] = 2 : 1 via an anionic framework dimensionality-fixed strategy0Strong SHG, piezoelectricity, and fluorescence coexisting in a single-component organic polar crystal enabled by σ-hole interactions0

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  1. [(C 5 H 6 N 2 ) 2 H](Sb 4 F 13 ): a polyfluoroantimonite with a strong second harmonic generation effect

    Chemical Science · 2024-01-01

    Jia-Hang Wu, Chun‐Li Hu, Yafeng Li, Jiang‐Gao Mao, Fang Kong

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  2. Achieving strong second harmonic generation effects induced via dimensional increase of PbX 6 octahedra and halogen substitutes in (C 10 H 11 N 3 )PbX 4 (X = Cl or Br)

    Inorganic Chemistry Frontiers · 2024-01-01

    Liling Zhang, Qingran Ding, Peihan Wang, Yanqiu Zhang, Qing‐Yan Liu, Yu‐Ling Wang, Junhua Luo

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  3. Designing promising ultraviolet (UV) birefringent crystals with different hydrogen-bonded phosphate frameworks

    Inorganic Chemistry Frontiers · 2024-01-01

    Miao‐Bin Xu, Jin Chen, Huai‐Yu Wu, Jiajia Li, Ning Yu, Mo-Fan Zhuo, Fei‐Fei Mao, Ke‐Zhao Du

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  4. Hydrogen bonding bolstered head-to-tail ligation of functional chromophores in a 0D SbF 3 ·glycine adduct for a short-wave ultraviolet nonlinear optical material

    Chemical Science · 2024-01-01

    Zhiyong Bai, Jihyun Lee, Chun‐Li Hu, Guohong Zou, Kang Min Ok

    Read original paper ↗ ·
  5. Recent advances and future perspectives on rare-earth-based nonlinear optical materials with π-conjugated [XO3] (X = B, C, N) units

    Coordination Chemistry Reviews · 2024-07-03

    Bo Zhang, Mao‐Yin Ran, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  6. Tetrahedra Modification of Phosphates for Optical Anisotropy Enhancement

    Advanced Optical Materials · 2024-08-29

    Haotian Qiu, Ran An, Junjie Li, Zhihua Yang, Shilie Pan, Miriding Mutailipu

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  7. Looking Back the Nonlinear Optical Crystals in a Functionalized Unit's Perspective

    Advanced Functional Materials · 2024-12-15

    Miriding Mutailipu, Junjie Li, Shilie Pan

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  8. Li3[AlP2O7F(OH)](H2O)0.5 and A[Al2(PO4)2F(H2O)](A = K, Rb): Counter Cation Templates Derived Three Polar Alkaline Metal Fluoroaluminophosphates

    Inorganic Chemistry · 2024-12-17

    Yucheng Hao, Changlin Chen, Cheng Hou, S. Liu, Peng Zheng, Yuan Ching Lin, Haijian Li, Xi Zhao, Kisan Koirala, Hongdian Lu, Chonghai Deng, Kunhong Hu

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  9. A HTO‐Type Nonlinear Optical Fluorophosphate with Ultrawide Bandgap

    Small · 2025-01-09

    Shanshan Chen, Zhiyong Bai, Xianyu Song, Tao Ouyang, Yanqiang Li, Qingran Ding, Han Wang, Wen‐Tong Chen, Junhua Luo, Sangen Zhao

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  10. Exploiting Rigid Inorganic π‐Conjugated Units and Deprotonatable Organic π‐Conjugated Dimers for Enhanced Linear and Nonlinear Optical Properties

    Laser & Photonics Review · 2025-05-12

    Yanqiu Zhang, Qingran Ding, Yanqiang Li, Xianyu Song, Weiqi Huang, Yang Zhou, Qingpeng Shao, Zhiyong Bai, Sangen Zhao, Junhua Luo

    Read original paper ↗ ·
  11. Non-centrosymmetric ZnSO4·Zn(OH)2: synthesis, crystal structure, and its applications towards photocatalytic methylene blue degradation and solvent-free Knoevenagel condensation reaction

    Inorganic Chemistry Communications · 2025-08-08

    Sangita Das, S. Ali

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  12. Computational design of new DUV NLO fluorooxoborates with [BO 3 ] : [BO 3 F] = 2 : 1 via an anionic framework dimensionality-fixed strategy

    Dalton Transactions · 2026-01-01

    Yajie Qi, Kewang Zhang, Xin Su, Abudukadi Tudi, Wenqi Jin, Congwei Xie

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  13. Strong SHG, piezoelectricity, and fluorescence coexisting in a single-component organic polar crystal enabled by σ-hole interactions

    Inorganic Chemistry Frontiers · 2026-01-01

    Jun‐Chao Liu, Xinyi Yang, Shuqi Han, Lei Ren, Ruru Wang, Wan-ying Zhang, Pingping Shi

    Read original paper ↗ ·