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RESEARCH PAPER · Nature Communications · 2023

Photothermal recycling of waste polyolefin plastics into liquid fuels with high selectivity under solvent-free conditions

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Photothermal recycling of waste polyolefin plastics into liquid fuels with high selectivity under solvent-free conditionsOriginalUpgrading polyethylene terephthalate plastic into commodity chemicals paired with hydrogen evolution over a partially oxidized CuIn 5 S 8 nanosheet photocatalyst65Solar-driven photocatalysis for recycling and upcycling plastics122Magnetic induction assisted pyrolysis of plastic waste to liquid hydrocarbons on carbon catalyst21Advances in solar-driven, electro/photoelectrochemical, and microwave-assisted upcycling of waste polyesters15Electrochemical recycling of polymeric materials56Mild aqueous metal catalyzed oxidative conversion of low-density polyethylene to low molecular weight aliphatic carboxylic acids15Photon and phonon powered photothermal catalysis131Recent advances in oxidative degradation of plastics227A comprehensive review on photo-thermal co-catalytic reduction of CO2 to value-added chemicals116Enhanced Photocatalytic Hydrogen Production from Poly(vinyl alcohol) Plastic-Dissolved Wastewater27Innovations in chemical degradation technologies for the removal of micro/nano-plastics in water: A comprehensive review20Direct Photoreforming of Real-World Polylactic Acid Plastics into Highly Selective Value-Added Pyruvic Acid under Visible Light191Photoelectrothermocatalytic reduction of CO2 to glycol via CdIn2S4-N/C hollow heterostructure mimicking plant cell20Recent Progresses and Challenges in Upcycling of Plastics through Selective Catalytic Oxidation15Stable Interfacial Ruthenium Species for Highly Efficient Polyolefin Upcycling104Temperature-Dependent NiFeAl catalysts for efficient microwave-assisted catalytic pyrolysis of polyethylene into value-added hydrogen and carbon nanotubes24Upcycling of Plastic Waste Using Photo-, Electro-, and Photoelectrocatalytic Approaches: A Way toward Circular Economy159Synergism of solar-driven interfacial evaporation and photo-Fenton Cr(VI) reduction by sustainable Bi-MOF-based evaporator from waste polyester78Layered Double Hydroxide Derivatives for Polyolefin Upcycling103Advances in Photothermal Catalysis: Mechanisms, Materials, and Environmental Applications72Solvent-free selective hydrogenation of nitroaromatics to azoxy compounds over Co single atoms decorated on Nb2O5 nanomeshes91Hydrogen Bubbles: Harmonizing Local Hydrogen Transfer for Efficient Plastic Hydro-Depolymerization19Fine Regeneration of ABS and PS Plastics from Waste Refrigerators through Mechanical Physical Recycling14Electrocatalysis‐driven sustainable plastic waste upcycling33Brønsted-acid sites induced photocatalytic cracking of low-polarity polyethylene plastics17A concise synthesis of Se/Fe materials for catalytic oxidation reactions of anthracene and polyene26Recent advances in polyolefinic plastic pyrolysis to produce fuels and chemicals60Solar‐Driven Biomass Reforming for Hydrogen Generation: Principles, Advances, and Challenges66Sustainability Science and Technology in 2024 and beyond: equitable publishing aligned with United Nations’ Sustainable Development Goals5Catalytic chemical recycling and upcycling of polyolefin plastics27Upcycling of polyethylene terephthalate (PET) plastic wastes into carbon-based nanomaterials: Current status and future perspectives51Amino acid-mediated chiral Ag@Au with circularly polarized light induced photothermal and photodynamic synergistic photocatalytic disinfection7Photothermal-mediated advanced oxidation processes for wastewater purification27Copolymerization of Olefins and Conjugated Dienes: A Promising Approach to Produce Recyclable Polyolefins14N2O deconstruction of polycyclooctene to generate carbonyl-functionalized macromonomers3Catalytic recycling of plastics into value-added products28Copper Sulfide based Photocatalysts, Electrocatalysts and Photoelectrocatalysts: Innovations in Structural Modulation and Application53Upconversion Phosphor-Driven Photodegradation of Plastics11Oxidative Upcycling of Polyolefin Wastes into the Dynamically Cross-Linked Elastomer25Plasmonic Copper‐Ruthenium Superstructure for Efficient Photothermal Conversion and Plastic Recycling39Reinforcing the Efficiency of Plastic Upgrading through Full‐Spectrum Photothermal Effect Integration of Heat Isolator15Selective Oxidation of Polyesters via PdCu–TiO 2 Photocatalysts in Flow60Current Advances in the Photoconversion of Plastics: the Catalysts and Reaction Pathways7Surface self-modification of TiO2 for enhanced photocatalytic toluene oxidation via photothermal effect18Enhancing the Conversion Efficiency of Polyethylene to Methane through Codoping of Mn Atoms into Ru Centers and CeO2 Supports37Advances in photothermal catalysts for solar-driven hydrogen production24In-and-out of inert sites on high-entropy layered double hydroxide to facilitate peroxymonosulfate-assisted photocatalytic removal of microplastics34Recycling of Post-Consumer Waste Polystyrene Using Commercial Plastic Additives54Photothermal Upcycling of Waste Polyvinyl Chloride Plastics27Recent Progress for Designing of Catalysts for Photothermal Conversion of Plastic Wastes48Photoreforming of Plastic Waste to Sustainable Fuels and Chemicals: Waste to Energy593D printing technology for photocatalysis: review and prospect14A Novel Upcycling Process of Polystyrene Wastes into Benzaldehyde by Catalyst-Free Laser Flash Depolymerization and In-Line Oxidation0Circular plastic economy for sustainable development: current advances and future perspectives49Integrated photothermal and photocatalytic degradation of micro-/nanoplastics: a mini-review with mechanistic insights and future perspectives39Lignin refinement based on efficient thermo-photo-catalysis of Ru–RuO 2 /TiO 2 -deep eutectic solvents6Plasmonic degradation of plastics on gold nanoparticles: electronic-scale insights from computation1Prospects of high-value recycling methods for polyurethane based on the selective cleavage of C–O/C–N bonds22Sustainable thermochemical plastic valorization towards a circular economy: a critical review27Upgrading of waste polyolefins with non-noble metal catalysts21Advanced Catalysts for the Chemical Recycling of Plastic Waste90Trimetallic mesoporous PdCuRu for efficient formate electrosynthesis from polyethylene terephthalate recycling13Selective Liquid Chemical Production in Waste Polyolefin Photorefinery by Controlling Reactive Species26Ultrasensitive and light erasable surface-enhanced Raman scattering substrates based on Au–MoO2 heterostructures4Emerging Plastic Recycling Strategies Based on Photothermal Conversion15Recycling homocarbon backbone polymers toward a circular materials economy12Photothermal catalytic dry reforming of methane over Ce ‐promoted Ni / NiO heterostructure13Catalytic conversion of polymer waste into high-value products for advancing circular economy and eco-sustainability11Photoreforming polylactic acid plastics into pyruvate over CdS/Bi4Ti3O12 S-scheme heterojunction: Successive removal of hydrogen from α-C11Agricultural Plastic Mulch: A Brief Review of Development, Composition and Catalytic Upcycling Strategies12Polyolefin Recycling with Binary Cobalt–Nickel Nanosheets6Green One-Step Synthesis and Characterization of Fluorescent Carbon Quantum Dots from PET Waste as a Dual-Mode Sensing Probe for Pd(II), Ciprofloxacin, and Fluoxetine via Fluorescence Quenching and Enhancement Mechanisms25Photothermal recycling of polylactic acid into H2 and gaseous C1 products via cooperative depolymerization and reforming11Photocatalytic Upcycling of Plastic Waste Into Value‐Added Chemicals21Microwave-Assisted Catalytic Upcycling of Plastic Wastes over Heterojunction-Structured Layered Triple Oxides8Consecutive coproduction of H2 and syngas from waste polyolefins derived pyrolysis gas via chemical looping cracking–gasification3Recent Advances in the Thermo-Catalytic Upcycling of Polyethylene Waste13From Waste Plastics to Carbon/Graphene Quantum Dots: A Journey Towards Value-Added Carbon Nanostructures for Various Applications5Ambient solar thermal catalysis for polyolefin upcycling using copper encapsulated in silicon nanosheets and chloroaluminate ionic liquid32Enhancing polypropylene/high-density polyethylene blend performance through the incorporation of microcrystalline cellulose-based core-shell particles at the interface9Morphology‐Controlled Rheological and Non‐Isothermal Crystallization Behaviors in Immiscible Polypropylene/High Density Polyethylene Blends1Cross-scale construction of photothermal synergistic catalytic systems: Mechanistic insights from single atoms, clusters to nanoparticles and energy conversion applications35Photothermal catalysis of waste plastics into propionic acid and hydrogen via Ni single-atom site isolation effect28An UV and Near‐Infrared Dual‐Photothermal Responsive Polymer Capable of Red‐Light Emission3Sustainable Treatment of Plastic Wastes with Photocatalytic Technologies: A Review7Low-Temperature Thermal Pyrolysis of Polypropylene: Tailoring Molecular Weight and Terminal Vinylidene Functionality for Upcycling11Study on co-pyrolysis of enzymolytic lignin and high-density polyethylene: Effects of pyrolysis parameters and synergistic interactions on the product distribution and characteristics7Fabricated double Z-scheme heterojunction photocatalyst for highly selective photocatalytic conversion of polylactic acid plastics6Trash‐to‐Energy: Shedding Light on Plastic and Biomass Valorization Through Artificial Photosynthesis Towards Sustainability14Solar‐Driven Plastic Upcycling Coupled with Valuable Reduction Reactions3The silent partner in catalysis: How support architectures dictate efficiency in polyolefin hydrogenolysis1Repurposing spent LiFePO4 batteries for sustainable photothermal-upcycling of polyesters10Upgrading Natural Ores for Efficient Photothermal Polyester Recycling21Stable single-site organonickel catalyst preferentially hydrogenolyses branched polyolefin C–C bonds12Highly Efficient Photothermal‐Catalytic Depolymerization of Polyester Fiber Enabled by a Phosphotungstate‐Based Palladium Single‐Atom Catalyst4Upcycling Spent Graphite Anodes into Bifunctional Photothermal Catalysts for Efficient PET Chemical Recycling9Research progress on photothermal catalytic conversion of waste plastics4Degradation-catalysis of polypropylene into liquid fuel-range iso-olefins using Zn and Ni-incorporated microporous carbon3Multiphase morphology control as a robust route to recycling mixed plastic waste2Toward Sustainable Plastic Waste Valorization: Green Synergistic Catalytic Strategies for Plastic Upcycling12Spin-polarization-enhanced photoreforming of plastic waste6Advancing chemical recycling for waste plastic conversion1Solar-to-chemical conversion in catalytic plastic transformation8Photothermal conversion of polyoxymethylene into syngas over supported alloyed nanocrystals2Laser-driven reforming of wastewater to adjustable syngas0Dynamic Polymer Networks: Key to Recyclable Polyolefins3Green-chemistry-based nanomaterials as solutions for plastic remediation0Plasma Catalysis for Plastic Waste Conversion into Value‐Added Products: Advancements and Perspectives11Valorization of plastic waste into drop-in fuels: Economic and environmental perspectives16Synergistically photothermocatalytic hydrogenolysis of waste plastics over the robust ultrafine Ru cluster catalysts3Recent advances in photocatalytic plastic degradation and upcycling: Catalysts, experiments, and mechanisms9Metal encapsulated hollow zeolites for waste plastics upcycling6Chemical recycling of polyolefin wastes: recent advances and insights into recycling routes0Surface and Interface Properties of Metal Species for Waste Plastic Hydroconversion6Catalytic Oxidation of Commodity Plastics: Advances in Polyethylene and Polystyrene Valorization5Room‐Temperature Synthesis of High‐Entropy Oxides via NH 4 F Modulation for Dark •OH Radical‐Enhanced Photothermal Catalysis0Performance comparison and sustainability assessment of mesoporous FAU zeolites for the plastic upcycling4Solar-driven upcycling of plastic waste using plasmonic black gold4Photothermal Revolution in Plastic Upcycling24Beyond mechanical recycling: artificial photosynthesis enables polyester plastic upcycling into valuable chemicals5Atomically precise nanoclusters of coinage metals for photothermal energy conversion: recent progress and biomedical applications0Carbon–carbon bond cleavage for lignin and plastics deconstruction0Catalyst-free lignin photothermal valorization via light-promoted aromatic C–H cleavage1Chlorine-mediated low-temperature solar-thermally catalytic PMMA degradation into liquid fuels0Electrochemical depolymerization of polycarbonates under catalyst-free conditions0Electronegativity-driven d-band center shifts in Ru–Ni alloys for low methane hydrogenolysis of polyolefin plastics2From waste to resource: Upcycling strategies for plastic pollution reduction0Green electrochemical upcycling of PET waste via bimetallic catalyst-driven ethylene glycol selective oxidation to formate0Microwave-assisted recycling of plastic waste into value-added chemicals: challenges, recent advances, and perspectives0Nanomaterials for natural sunlight-driven photothermal catalysis: from laboratory innovations to outdoor demonstrations4TiO 2 –CDots composite with near-infrared light excitation enabling the ultra-efficient CO 2 reduction by the photothermo coupling effect0MoV-induced upcycling of polyethylene terephthalate waste to high-value chemicals under mild conditions2Impact of Network Architecture and Cross-Link Aggregation on the Crystallization Behavior of a Polypropylene-Based Thermoset Polyurethane2Photo-induced reactive oxygen species for selective oxidation of plastics and biomass4Acid sites in hydrogen-involved polyolefin upcycling: mechanistic insights and design principles0Recycling of polyolefins using recycled PVC under sunlight7Photo-driven upcycling of plastics: pathways to value-added products1Reframing Biodegradable Plastic as an Effective, Chemically Recyclable Resource for a Circular Economy6Synergistic bifunctional catalysis and plasma activation for valorizing polypropylene and CO2 to gasoline-range olefins1Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Hydrogenolysis Versus Hydrocracking for Polyolefin Upcycling0Oxidative Extrusion of Polypropylene Melts: Impact of Chain-End and In-Chain Functionalization on Thermal Properties, Crystal Structure, and Crystallization Kinetics1Photothermal catalysis for plastic upcycling: a review on material design and reaction mechanisms2Dimensionality- and Pathway-Engineered Charge Transport Dynamics Mediate Divergent Product Selectivity in Photocatalysis6Polymer and plastic waste recycling: Challenges and prospects towards a circular economy3Engineering Interfacial Compatibility and Dynamic Active Hydrogen Pools to Accelerate Polyolefin Hydrogenolysis0Advances in plastic waste valorization: Economic and green perspectives9Solar-Driven Dehalogenation and Upcycling of Brominated Plastic Waste1Well‐Defined Heterocatalysts for Plastic Upcycling: From Design to Applications3Ambient-pressure conversion of plastic waste to jet fuel cycloalkanes by tandem hydropyrolysis and vapour-phase hydrogenation2

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