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RESEARCH PAPER · Inorganic Chemistry · 2023

Atomic Substitution to Tune ScO6 Distortion in Ba2MSc2(BO3)4 (M = Na, K, Ba) to Acquire a Large Birefringence

Jingfang Zhou, Pifu Gong, Mingjun Xia, Aimin Ji, Li‐Fang Zhang, Huiqiang Wu, Qian Wu

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Atomic Substitution to Tune ScO6 Distortion in Ba2MSc2(BO3)4 (M = Na, K, Ba) to Acquire a Large BirefringenceOriginalPbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence12From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups13New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution15Tunable Optical Anisotropy in Rare‐Earth Borates with Flexible [BO3] Clusters7A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence4From NaSc 3 Ga 2 Q 8 (Q = S, Se) to KGa 2 In 3 S 8 : substitution of Sc 3+ with In 3+ to achieve doubled birefringence17Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal6P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions6Recent progress in structural design strategies of high-birefringence optical crystals54Assignment of the Luminescent Center in the Ba 3 Sc 2 (BO 3 ) 4 :Eu 2+ Phosphor: A Combined Study from Topological Crystallography and First-Principles Calculation1Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission0REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups2[Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units1Exploring the luminescence behaviour of RE³ + (Gd, Tb, Eu) activated borate host K₅Mg₂La₃(BO₃)₆0Review on recent trends in NIR-emitting trivalent chromium (Cr 3+ ) ion-doped phosphors for applications in pc-LEDs0

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  1. PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence

    Chemical Communications · 2023-11-28

    Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan

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  2. From BaAlBO 3 F 2 to BaAlB 3 O 6 F 2 and BaAl 2 (B 3 O 6 ) 2 F 2 : the enhancement of birefringence and band gap by extending the π-conjugated system combined with [Al–O/F] functional groups

    Inorganic Chemistry Frontiers · 2024-01-01

    Cheng Chen, Danyang Dou, Yunjie Bai, Bingbing Zhang, Ying Wang

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  3. New ultraviolet transparent rare-earth borates with enhanced birefringence induced by cation chemical substitution

    Inorganic Chemistry Frontiers · 2024-01-01

    Guanglian Sun, Xiaofang Qi, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  4. Tunable Optical Anisotropy in Rare‐Earth Borates with Flexible [BO3] Clusters

    Chemistry - A European Journal · 2024-05-02

    Xiangyu Long, Ran An, Yan An Lv, Xueyan Wu, Miriding Mutailipu

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  5. A 3 Sc(PO 4 ) 2 (A = Li, Na): rare earth cations effectively regulate phosphate structures for enhanced birefringence

    Dalton Transactions · 2025-01-01

    Hongheng Chen, Xudong Leng, Mei Hu, Yibo Han, Haiming Duan, Qun Jing, Zhaohui Chen, Ming‐Hsien Lee

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  6. From NaSc 3 Ga 2 Q 8 (Q = S, Se) to KGa 2 In 3 S 8 : substitution of Sc 3+ with In 3+ to achieve doubled birefringence

    Chemical Science · 2025-01-01

    Yun Xie, Wen‐Dong Yao, Qiu-Yang Du, Wenfeng Zhou, Nian‐Tzu Suen, Wenlong Liu, Sheng‐Ping Guo

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  7. Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal

    Chinese Chemical Letters · 2025-01-07

    Ning Yang, Huijian Zhao, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Conggang Li

    Read original paper ↗ ·

  8. P4Sn (n = 3, 5, 7): Large Birefringence Enhanced by 3D Aromaticity and Packing Effect Induced Directional π–π Noncovalent Interactions

    Advanced Optical Materials · 2025-04-11

    Wei Wu, Yi‐Bing Huang, Si‐Fan Lu, Jia Gao, Yan Guo, Wei‐Qi Huang, Meng‐Na Jing, Xiao‐Ming Jiang, Guo‐Cong Guo

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  9. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  10. Assignment of the Luminescent Center in the Ba 3 Sc 2 (BO 3 ) 4 :Eu 2+ Phosphor: A Combined Study from Topological Crystallography and First-Principles Calculation

    ACS Applied Optical Materials · 2025-11-06

    Piaopiao Jin, Xipeng Deng, Chunhui Zang, Chuan Lei, Wenhui Zhai, Zhaopeng Xu, Keju Sun, Xianfeng Hao, Rong‐Jun Xie, Faming Gao, Yongchao Jia

    Read original paper ↗ ·

  11. Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission

    Advanced Optical Materials · 2025-12-10

    Zhenkai Cen, Z.-Y. Li, Guang Peng, Junbo Gong, Junbo Gong

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  12. REV 3 (BO 3 ) 4 (RE = La–Nd): a series of rare earth vanadoborates exhibit large birefringence induced by distorted V III O 6 groups

    Chemical Communications · 2026-01-01

    Yu-Long Wei, Wen-Dong Yao, Yi‐Lei Lv, Liang Ma, Ru‐Ling Tang

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  13. [Sr(H 2 O)]{Sr[B(OH) 3 ]}[B 5 O 8 (OH)] 2 : A Deep-Ultraviolet Second-Order Nonlinear Optical Strontium Borate Constructed by Mixing π-Conjugated and Non-π-Conjugated Units

    Inorganic Chemistry · 2026-01-07

    Yuquan Feng, Dongqin Bi, K. C. Liu, Shuyang Chen, Limin Gao, Zhaohui Meng

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  14. Exploring the luminescence behaviour of RE³ + (Gd, Tb, Eu) activated borate host K₅Mg₂La₃(BO₃)₆

    Canadian Metallurgical Quarterly · 2026-05-15

    P.K. Tawalare, Renuka Nafdey, S. V. Moharil

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  15. Review on recent trends in NIR-emitting trivalent chromium (Cr 3+ ) ion-doped phosphors for applications in pc-LEDs

    Canadian Metallurgical Quarterly · 2026-07-03

    Shruti Prabhakar Dhale, P.K. Tawalare, Nilesh Sureshrao Ugemuge, S. V. Moharil

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