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RESEARCH PAPER · Inorganic Chemistry · 2024

Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large Birefringence

Liqin Liu, Hai‐Lan Huang, Mingliang Ding, Yaoguo Shen

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Noncentrosymmetric Crystal [C10H8NO2]2SiF6·H2O with Large BirefringenceOriginalGreatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units13Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification6Recent progress in structural design strategies of high-birefringence optical crystals54Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization88Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization13[C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy13From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization6Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response4Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission0Structural Anion Geometry-Regulated Molecular Alignment in [C 10 H 8 NO 2 ]-Based Crystals for Enhancing Ultraviolet Birefringence0Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals0Anion-Stabilized Incommensurate Modulation Enables Nonlinear Optical Response in Eu2SiO3.89N0.110

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  1. Greatly enhancing birefringence of fluorosilicates through the synergetic effect of functional units

    Inorganic Chemistry Frontiers · 2025-01-01

    Liang Ma, Yi‐Lei Lv, Bing-Wei Miao, Guo-Ren Zhu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  2. Hg[CS(NH 2 ) 2 ] 4 (SiF 6 ): a fluorosilicate crystal with large birefringence achieved via multi-functional group modification

    Dalton Transactions · 2025-01-01

    Pengfei Li, Xinlei Liu, Si-Qi Zhou, Mingchang Wang, Jingjing Wu, Yu‐Wu Zhong, Jiannian Yao

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  3. Recent progress in structural design strategies of high-birefringence optical crystals

    Coordination Chemistry Reviews · 2025-05-08

    A-Lan Xu, Mao‐Yin Ran, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  4. Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization

    Angewandte Chemie International Edition · 2025-05-22

    Yaolong Zhu, Jie Gou, Can Yang, Qingwen Zhu, Yi Xiong, Qi Wu

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  5. Decoupling the SHG‐Birefringence Trade‐off in UV NLO Materials via Triple‐Control Coordination Engineering: Achieving Synergistic Performance Optimization

    Angewandte Chemie · 2025-05-22

    Yaolong Zhu, Jie Gou, Can Yang, Qingwen Zhu, Yi Xiong, Qi Wu

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  6. [C( NH2 )3] 2SiF6 : Design of Deep Ultraviolet Crystals with Large Birefringence Based on a Fluorination‐Oriented Strategy

    Chinese Journal of Chemistry · 2025-06-24

    Shaohua Liu, Xiaoqin Ma, Xifa Long, Yun Mo Yang

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  7. From (C12H9N2)2TeBr6·2H2O to (C12H9N2)2TeBr6: Dehydration-Driven Crystal Reorganization for Birefringence Optimization

    Inorganic Chemistry · 2025-09-25

    Shiyi Wang, Yingzi Zhang, Yu Yan, Xuehua Dong, Liling Cao, Ling Huang, Guohong Zou

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  8. Na6(SO4)2SiF6: A Stable Sulfate Fluosilicate with Wide Deep-Ultraviolet Transparency Window and Strong Second-Harmonic Generation Response

    Chemistry of Materials · 2025-10-02

    Zilong Geng, Zuju Ma, Ruibiao Fu, Xintao Wu

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  9. Hydrogen‐Bond‐Driven Metal‐Free Crystal (C 6 H 7 N 2 O)(NH 2 SO 3 ) with Giant Birefringence and Solar‐Blind Ultraviolet Transmission

    Advanced Optical Materials · 2025-12-10

    Zhenkai Cen, Z.-Y. Li, Guang Peng, Junbo Gong, Junbo Gong

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  10. Structural Anion Geometry-Regulated Molecular Alignment in [C 10 H 8 NO 2 ]-Based Crystals for Enhancing Ultraviolet Birefringence

    Crystal Growth & Design · 2026-04-07

    YaoGuo Shen, Yiman Yang, Jiajia Xiong, Xinyi Wang

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  11. Noncovalent Assembly Engineering Achieves Excellent Birefringence in Crystals

    Inorganic Chemistry · 2026-04-24

    Mengqing Wu, Yiman Yang, Xinyi Wang, Yaoguo Shen

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  12. Anion-Stabilized Incommensurate Modulation Enables Nonlinear Optical Response in Eu2SiO3.89N0.11

    Inorganic Chemistry · 2026-07-10

    Yue Wang, Xiaoming Wang, Shirui Zhang, Jiayao Zhang, Hu Zhang, Zupei Yang, Chun‐Hai Wang, Huan Jiao

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