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RESEARCH PAPER · Sustainable Energy & Fuels · 2022

Assessment of acidity and the zeolite porous structure on hydrocracking of HDPE

Cátia S. Costa, Hang Dao Thi, Kevin M. Van Geem, M. Rosário Ribeiro, João Miguel Silva

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Assessment of acidity and the zeolite porous structure on hydrocracking of HDPEOriginalUnderstanding the Structure–Activity Relationships in Catalytic Conversion of Polyolefin Plastics by Zeolite-Based Catalysts: A Critical Review269Evaluation of two approaches for the synthesis of hierarchical micro-/mesoporous catalysts for HDPE hydrocracking15Precise activation of C–C bonds for recycling and upcycling of plastics81Identification of coke species on Fe/USY catalysts used for recycling polyethylene into fuels18Sustainable high-density polyethylene via chemical recycling: From modification to polymerization methods45Acidity regulation of Fe-based catalysts and its effect on the selectivity of HDS reaction pathways2The catalytic pyrolysis of waste polyolefins by zeolite-based catalysts: A critical review on the structure-acidity synergies of catalysts47Hierarchical FAU Zeolites Boosting the Hydrocracking of Polyolefin Waste into Liquid Fuels38Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design25Insights into the development of greener mild zeolite dealumination routes applied to the hydrocracking of waste plastics29Analyzing HDPE Thermal and Catalytic Degradation in Hydrogen Atmosphere: A Model-Free Approach to the Activation Energy13Catalyst Accessibility and Acidity in the Hydrocracking of HDPE: A Comparative Study of H-USY, H-ZSM-5, and MCM-41 Modified with Ga and Al11Unlocking the structure-activity relationship of hierarchical MFI zeolites towards the hydrocracking of HDPE14Pore-Structure Engineering of Hierarchical β Zeolites for the Enhanced Hydrocracking of Waste Plastics to Liquid Fuels51Maximizing light olefin production in the cracking of polyethylene using hierarchical acidic–basic zeolites5Recent advancements in upcycling of polyolefins by hydrocracking: Effect of various heterogeneous catalysts and reaction parameters8Advances in catalytic transformations of waste plastic resources with zeolites0A Review on the Research Progress of Zeolite Catalysts for Heavy Oil Cracking63Synergistic Catalysis for Recycling and Upcycling of Plastics35On the use of a bulky base for evaluating the accessibility of Brønsted acid sites in USY zeolites3Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene3Synergistic pore-acidity engineering of hierarchical ZSM-5 for hydrogen-free upcycling of Polyethylene to C8–C12 Methylated Aromatics1Upgrading the Brønsted acidity of zeolite Hβ via phosphotungstates: engineering a high-performance catalytic platform for the production of energy-efficient biofuel additives2Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production3Compressed CO 2 -Assisted Catalytic Hydrocracking of Polyethylene over Ru-Loaded Zeolites0Hydrocracking of Waste Plastic Pyrolysis Oil and Light Cycle Oil (PPO/LCO) Blends in a Trickle-Bed Reactor: Catalyst Assessment and Operating-Condition Screening3Polymer and plastic waste recycling: Challenges and prospects towards a circular economy3Single-Atom Nickel Dispersed on Mo 2 TiC 2 T x MXene for Upcycling of Polyolefins via Catalytic Hydropyrolysis for Fuels and Lubricants0In situ growth of mordenite on modified montmorillonite: A hierarchically porous hybrid catalyst with enhanced porosity and activity in fluid catalytic cracking0Circular management of single-use polyolefins via hydrocracking over zeolite-based catalysts0

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  1. Understanding the Structure–Activity Relationships in Catalytic Conversion of Polyolefin Plastics by Zeolite-Based Catalysts: A Critical Review

    ACS Catalysis · 2022-11-23

    Zhongwen Dong, Wenjun Chen, Keqing Xu, Yue Liu, Jing Wu, Fan Zhang

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  2. Evaluation of two approaches for the synthesis of hierarchical micro-/mesoporous catalysts for HDPE hydrocracking

    Microporous and Mesoporous Materials · 2023-04-15

    Sabino Armenise, Cátia S. Costa, Syie Luing Wong, M. Rosário Ribeiro, João Miguel Silva, Thomas Onfroy, Laetitia Valentin, Sandra Casale, Marta Muñoz, Franck Launay

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  3. Precise activation of C–C bonds for recycling and upcycling of plastics

    Chemical Science · 2023-12-07

    Hongshun Ran, Shuo Zhang, Wenyi Ni, Yaxuan Jing

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  4. Identification of coke species on Fe/USY catalysts used for recycling polyethylene into fuels

    RSC Advances · 2024-01-01

    Yongli Wang, Na Yan, Zezhou Chen

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  5. Sustainable high-density polyethylene via chemical recycling: From modification to polymerization methods

    Polymer · 2024-01-16

    Xiaomeng Li, Nagarjuna A. Mahadas, Mengxue Zhang, Jacquelyn DePodesta, Morgan Stefik, Chuanbing Tang

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  6. Acidity regulation of Fe-based catalysts and its effect on the selectivity of HDS reaction pathways

    Journal of Fuel Chemistry and Technology · 2024-02-01

    Guosheng Li, Kunhong Li, Xiaohan Li, Xinrui Yin, Jiaxin SHAO, Rong Guo, Shenyong Ren, Qiaoxia Guo, Baojian Shen

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  7. The catalytic pyrolysis of waste polyolefins by zeolite-based catalysts: A critical review on the structure-acidity synergies of catalysts

    Polymer Degradation and Stability · 2024-02-21

    Yang Ge, Peng Peng, Hailing Guo, Hongwei Song, Zhibo Li

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  8. Hierarchical FAU Zeolites Boosting the Hydrocracking of Polyolefin Waste into Liquid Fuels

    ACS Sustainable Chemistry & Engineering · 2024-04-03

    Xinru Zhou, Xinlei Han, Zhengyan Qu, Jiuxuan Zhang, Feng Zeng, Zhenchen Tang, Rizhi Chen

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  9. Recent advances in polyolefin plastic waste upcycling via mild heterogeneous catalysis route from catalyst development to process design

    Cell Reports Physical Science · 2024-07-01

    Haokun Wang, Shik Chi Edman Tsang

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  10. Insights into the development of greener mild zeolite dealumination routes applied to the hydrocracking of waste plastics

    Applied Catalysis A General · 2024-07-08

    Muhammad Usman Azam, Waheed Afzal, Auguste Fernandes, Inês Graça

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  11. Analyzing HDPE Thermal and Catalytic Degradation in Hydrogen Atmosphere: A Model-Free Approach to the Activation Energy

    Catalysts · 2024-08-09

    Cátia S. Costa, Auguste Fernandes, Marta Muñoz, M. Rosário Ribeiro, João Miguel Silva

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  12. Catalyst Accessibility and Acidity in the Hydrocracking of HDPE: A Comparative Study of H-USY, H-ZSM-5, and MCM-41 Modified with Ga and Al

    Molecules · 2024-09-07

    Cátia S. Costa, M. Rosário Ribeiro, João Miguel Silva

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  13. Unlocking the structure-activity relationship of hierarchical MFI zeolites towards the hydrocracking of HDPE

    Fuel · 2024-09-08

    Muhammad Usman Azam, Auguste Fernandes, Maria João Ferreira, Alan J. McCue, Inês Graça, Waheed Afzal

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  14. Pore-Structure Engineering of Hierarchical β Zeolites for the Enhanced Hydrocracking of Waste Plastics to Liquid Fuels

    ACS Catalysis · 2024-10-17

    Muhammad Usman Azam, Auguste Fernandes, Maria João Ferreira, Waheed Afzal, Inês Graça

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  15. Maximizing light olefin production in the cracking of polyethylene using hierarchical acidic–basic zeolites

    Catalysis Science & Technology · 2025-01-01

    Samira Motamednejad, Reza Panahi, Kourosh Tabar Heydar, Li Gao, Bingsen Zhang, Mozaffar Shakeri

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  16. Recent advancements in upcycling of polyolefins by hydrocracking: Effect of various heterogeneous catalysts and reaction parameters

    Polymer Degradation and Stability · 2025-01-27

    Thangaraj Baskaran, Yong-Kul Lee

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  17. Advances in catalytic transformations of waste plastic resources with zeolites

    Scientia Sinica Chimica · 2025-04-08

    Haiwei Lai, Dongsheng Xiang, Tian Tan, Weiping Deng, Qinghong Zhang, Ye Wang

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  18. A Review on the Research Progress of Zeolite Catalysts for Heavy Oil Cracking

    Catalysts · 2025-04-19

    Lisha Wei, Hui Wang, Qi Dong, Yongwang Li, Hongwei Xiang

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  19. Synergistic Catalysis for Recycling and Upcycling of Plastics

    ACS Catalysis · 2025-05-07

    Hongshun Ran, Xinyang Sun, Mengying Zheng, Yaxuan Jing

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  20. On the use of a bulky base for evaluating the accessibility of Brønsted acid sites in USY zeolites

    Microporous and Mesoporous Materials · 2025-07-03

    Yuna Han, Mickaël Rivallan, Kim Larmier, Gerhard D. Pirngruber

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  21. Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low‐H 2 ‐Pressure Hydrogenolysis of Low‐Density Polyethylene

    Chemistry - A European Journal · 2025-11-02

    Yukari Yamazaki, Xiongjie Jin, Weihan Sun, Satoshi Yamamoto, Katsutoshi Nomoto, Kohei Takahashi, Hiroki Miura, Tetsuya Shishido, Akira Nakayama, Kyoko Nozaki

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  22. Synergistic pore-acidity engineering of hierarchical ZSM-5 for hydrogen-free upcycling of Polyethylene to C8–C12 Methylated Aromatics

    The Innovation Energy · 2026-01-01

    Bingyan Sun, Bo Li, Marc Mate, Linjia Yin, Qihui Song, Xiaopeng Shi, Dingran Wang, Fawei Lin, Kaige Wang

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  23. Upgrading the Brønsted acidity of zeolite Hβ via phosphotungstates: engineering a high-performance catalytic platform for the production of energy-efficient biofuel additives

    Sustainable Energy & Fuels · 2026-01-01

    Margi Joshi, Anjali Uday Patel

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  24. Recent advancements in catalytic processes for plastic upcycling into fuels: a major step in sustainable waste management and energy production

    Fuel · 2026-02-26

    Sudipta Nayak, Rajat Singhal, S. M. A. Hakim Siddiki, Ken Motokura, Navya Subray Bhat, Navneet Kumar Gupta

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  25. Compressed CO 2 -Assisted Catalytic Hydrocracking of Polyethylene over Ru-Loaded Zeolites

    ACS Sustainable Chemistry & Engineering · 2026-03-27

    Nicholas Gorschak, Lakshmiprasad Gurrala, Allison Tran, Samir Fernando Castilla-Acevedo, Diego Trevisan Melfi, Hashim A. Alzahrani, Van Son Nguyen, Aaron M. Scurto, Alan M. Allgeier, Juan J. Bravo-Suárez, Ana Rita C. Morais

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  26. Hydrocracking of Waste Plastic Pyrolysis Oil and Light Cycle Oil (PPO/LCO) Blends in a Trickle-Bed Reactor: Catalyst Assessment and Operating-Condition Screening

    Energy & Fuels · 2026-03-30

    Iratxe Crespo, Tomás Cordero‐Lanzac, Ana Fernandez Cimiano, Roberto Palos, Alazne Gutiérrez

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  27. Polymer and plastic waste recycling: Challenges and prospects towards a circular economy

    Chemical Engineering Journal Advances · 2026-04-06

    Olajumoke Alabi‐Babalola

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  28. Single-Atom Nickel Dispersed on Mo 2 TiC 2 T x MXene for Upcycling of Polyolefins via Catalytic Hydropyrolysis for Fuels and Lubricants

    Precision Chemistry · 2026-05-01

    Jonathan Tjioe, Wei-Ling Huang, Harish Radhakrishnan, Ruoyu Cui, Yuting Li, Alex Gatiba, Tao Ma, Dapeng Jing, Long Hao Qi, Jeffrey T. Miller, Xianglan Bai, Yue Wu

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  29. In situ growth of mordenite on modified montmorillonite: A hierarchically porous hybrid catalyst with enhanced porosity and activity in fluid catalytic cracking

    Journal of materials research/Pratt's guide to venture capital sources · 2026-08-14

    Mahta Badienezhad, Sh. Sohrabnezhad

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  30. Circular management of single-use polyolefins via hydrocracking over zeolite-based catalysts

    Elsevier eBooks · 2026-09-25

    Muhammad Usman Azam, Muhammad Umer, Inês Graça, Waheed Afzal

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