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RESEARCH PAPER · Chemistry of Materials · 2022

Ba2MAsQ5 (Q = S and Se) Family of Polar Structures with Large Second Harmonic Generation and Phase Matchability

Abishek K. Iyer, Jeong Bin Cho, Michael J. Waters, Jun Sang Cho, Benjamin M. Oxley, James M. Rondinelli, Joon Ik Jang, Mercouri G. Kanatzidis

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Ba2MAsQ5 (Q = S and Se) Family of Polar Structures with Large Second Harmonic Generation and Phase MatchabilityOriginalHeteroanionic Control of Exemplary Second-Harmonic Generation and Phase Matchability in 1D LiAsS2–xSex43Honeycomb layered topology construction for exceptional long-wave infrared nonlinear optical crystals29Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response22Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure10Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization133Design Principles for Noncentrosymmetric Materials23AgMAsS3 (M = Cd, Hg): Double d10 Cation-Containing Thioarsenites(III) Exhibiting High Photocurrent Response and Moderate Second Harmonic Generation11Syntheses, Crystal Structures, and Electronic Structures of Quaternary Group IV-Selenide Semiconductors10Vacancy‐Induced Extraordinary Second Harmonic Generation Response for Diamond‐Like Cu3PS49Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides19Li3Sb7Se12: A Pavonite Homologue with Ultralow Thermal Conductivity10Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity6Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity0Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method4From non-innocent ionic liquids to reactive agents in the synthesis of chalcogenido metalate compounds1Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials10Research progress and future prospect of chalcogenides with large optical anisotropy46Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs29Antibonding States Drive Anharmonicity and Low Thermal Conductivity in Edge-Sharing Metal Chalcogenides4Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties6Discovery of Noncentrosymmetric Sr 3 As 2 S 7 and Sr 3 As 2 Se 2.5 S 4.5 Featuring As 3+ /As 5+ Coordination and Their Strong Nonlinear Optical Response2Mg Substitution in BaGa 4 Se 7 : Synthesis, Structure, and Property Modulation2Structural origins of the thermal properties of Ba2BiInSe50

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23 direct citing papers saved.

  1. Heteroanionic Control of Exemplary Second-Harmonic Generation and Phase Matchability in 1D LiAsS2–xSex

    Journal of the American Chemical Society · 2022-07-22

    Benjamin M. Oxley, Jeong Bin Cho, Abishek K. Iyer, Michael J. Waters, Jingyang He, Nathan Smith, Chris M. Wolverton, Venkatraman Gopalan, James M. Rondinelli, Joon Ik Jang, Mercouri G. Kanatzidis

    Read original paper ↗ ·

  2. Honeycomb layered topology construction for exceptional long-wave infrared nonlinear optical crystals

    Materials Horizons · 2023-01-01

    Jindong Chen, Chensheng Lin, Xiaotian Jiang, Guangsai Yang, Min Luo, Xin Zhao, Bingxuan Li, Guang Peng, Ning Ye, Zhanggui Hu, Jiyang Wang, Yicheng Wu

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  3. Na 6 Sn 3 P 4 S 16 : Sn( ii )-chelated PS 4 groups inspired an ultra-strong SHG response

    Inorganic Chemistry Frontiers · 2023-01-01

    Chenyao Zhao, Bingbing Zhang, Xinyu Tian, Guoqiang Zhou, Jingjing Xu, Kui Wu

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  4. Visualizing the alignment of lone pair electrons in La 3 AsS 5 Br 2 and La 5 As 2 S 9 Cl 3 to form an acentric or centrosymmetric structure

    CrystEngComm · 2023-01-01

    Gary Cicirello, Andrew Swindle, Jian Wang

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  5. Recent progress in the design of IR nonlinear optical materials by partial chemical substitution: Structural evolution and performance optimization

    Coordination Chemistry Reviews · 2023-02-08

    Mao‐Yin Ran, A-Yang Wang, Wenbo Wei, Xintao Wu, Hua Lin, Qi‐Long Zhu

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  6. Design Principles for Noncentrosymmetric Materials

    Annual Review of Materials Research · 2023-07-03

    Xudong Huai, T. Thao Tran

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  7. AgMAsS3 (M = Cd, Hg): Double d10 Cation-Containing Thioarsenites(III) Exhibiting High Photocurrent Response and Moderate Second Harmonic Generation

    Inorganic Chemistry · 2023-08-30

    Jian Tang, Fei Liang, Wenhao Xing, Chunlan Tang, Wenlong Yin, Bin Kang, Jianguo Deng

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  8. Syntheses, Crystal Structures, and Electronic Structures of Quaternary Group IV-Selenide Semiconductors

    Inorganic Chemistry · 2024-03-27

    Subhendu Jana, Eric A. Gabilondo, Scott McGuigan, Paul A. Maggard

    Read original paper ↗ ·

  9. Vacancy‐Induced Extraordinary Second Harmonic Generation Response for Diamond‐Like Cu3PS4

    Advanced Optical Materials · 2024-04-10

    Weiping Guo, Yudi Fu, Hong‐Hua Cui, Lingyun Li, Yan Yu, Zhong‐Zhen Luo, Zhigang Zou

    Read original paper ↗ ·

  10. Large Mid-Infrared Second-Harmonic Generation in Eu(II)-Based Quaternary Chalcogenides

    Chemistry of Materials · 2024-09-19

    Subhendu Jana, Eric A. Gabilondo, Machima Mongkhonratanachai, Yujie Zhang, P. Shiv Halasyamani, Paul A. Maggard

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  11. Li3Sb7Se12: A Pavonite Homologue with Ultralow Thermal Conductivity

    Chemistry of Materials · 2024-10-03

    Abishek K. Iyer, Shima Shahabfar, Alann P. Au, Hongyao Xie, Anastasia D. Pournara, Christopher Wolverton, Mercouri G. Kanatzidis

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  12. Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity

    Angewandte Chemie International Edition · 2024-10-29

    Ermeng Han, Y.J. Li, Tun Wu, Qixia Bai, Zhe Zhang, Jie Yuan, Wei Liu, Die Liu, Yiming Li, Pingshan Wang

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  13. Chiral Metal Self‐Assemblies of Zirconium‐Tetrahedra and Their Second Harmonic Generation Activity

    Angewandte Chemie · 2024-10-29

    Ermeng Han, Y.J. Li, Tun Wu, Qixia Bai, Zhe Zhang, Jie Yuan, Wei Liu, Die Liu, Yiming Li, Pingshan Wang

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  14. Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method

    Inorganic Chemistry · 2024-12-04

    Gopabandhu Panigrahi, Gregory W. Morrison, Mark D. Smith, Hans‐Conrad zur Loye

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  15. From non-innocent ionic liquids to reactive agents in the synthesis of chalcogenido metalate compounds

    Chemical Communications · 2025-01-01

    Gina Stuhrmann, Bastian Weinert, Stefanie Dehnen

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  16. Synergistic Machine Learning Guided Discovery of ABa 3 (BSe 3 ) 2 X (A = Rb, Cs; X = Cl, Br, I): A Promising Family as Property‐Balanced IR Functional Materials

    Advanced Science · 2025-04-26

    Yihan Yun, Mengfan Wu, Zhihua Yang, Guangmao Li, Shilie Pan

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  17. Research progress and future prospect of chalcogenides with large optical anisotropy

    Coordination Chemistry Reviews · 2025-06-20

    Zhen-Cheng Wu, Sheng‐Ping Guo

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  18. Structure-property relationships in IR nonlinear optical chalcogenides with stereochemically active lone pairs

    Coordination Chemistry Reviews · 2025-09-03

    Hong Chen, Xin‐Tao Wu, Hua Lin

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  19. Antibonding States Drive Anharmonicity and Low Thermal Conductivity in Edge-Sharing Metal Chalcogenides

    ACS Applied Materials & Interfaces · 2025-10-25

    Harpriya Minhas, Rahul Kumar Sharma, Biswarup Pathak

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  20. Ba-based IR nonlinear optical materials: synthesis, growth, structures, and properties

    Coordination Chemistry Reviews · 2025-11-19

    Wei Huang, Chi Wang, Guohong Tang, Kexin Huang, Baojun Chen, Z. Y. He, Z. Y. He

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  21. Discovery of Noncentrosymmetric Sr 3 As 2 S 7 and Sr 3 As 2 Se 2.5 S 4.5 Featuring As 3+ /As 5+ Coordination and Their Strong Nonlinear Optical Response

    Chemistry of Materials · 2026-01-27

    Vidyanshu Mishra, Jinseong Kim, Joshua Lim, Manya Rishi, Joon Ik Jang, Abishek K. Iyer

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  22. Mg Substitution in BaGa 4 Se 7 : Synthesis, Structure, and Property Modulation

    Chemistry of Materials · 2026-03-24

    Chi Wang, Guohong Tang, Kexin Huang, Yuhang Du, Jinsong Wei, Baojun Chen, Zhiyu He, Wei Huang

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  23. Structural origins of the thermal properties of Ba2BiInSe5

    Materials Chemistry and Physics · 2026-05-25

    Wilarachchige D. C. B. Gunatilleke, George S. Nolas

    Read original paper ↗ ·
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