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RESEARCH PAPER · Inorganic Chemistry · 2022

Realization of Enlarged Birefringence from BaCdBe2(BO3)2F2 to NaMgBe2(BO3)2F via the Cation Size Effect as a Potential Deep-Ultraviolet Birefringent Material

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Realization of Enlarged Birefringence from BaCdBe2(BO3)2F2 to NaMgBe2(BO3)2F via the Cation Size Effect as a Potential Deep-Ultraviolet Birefringent MaterialOriginalCsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group8Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal17An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32Synthesis and characterization of a new isoxazolone-based nonlinear optical crystal: MPMOI7Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers7Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence130Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence6The synthesis of novel lanthanum hydroxyborate at extreme conditions3Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence12Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates5Review on birefringence in borates based on birefringence-active functional groups and arrangements57Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)12Anion ratio-directed design of CaB 4 O 5 F 4 and CaB 6 O 8 F 4 : [BO 3 ]/[BO 2 F 2 ] hybridization tailoring deep-ultraviolet nonlinear optical performance2RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence1Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F34Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge1SrMBe 2 (BO 3 ) 2 F 2 (M = Zn, Mg): two SBBO-like compounds obtained by cation regulation1Towards equilateral triangular lattice frustrated quantum magnets through crystal symmetry–protected molecular-brick chemical strategy4

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  1. CsB 3 O 4 (OH) 2 : a new deep-ultraviolet birefringent crystal with [B 3 O 4 (OH) 2 ] anionic group

    Dalton Transactions · 2022-01-01

    Xinyue Wang, Bingbing Zhang, Daqing Yang, Ying Wang

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  2. Hexameric poly-fluoroberyllophosphate Na 4 Be 2 PO 4 F 5 with moderate birefringence and deep-ultraviolet transmission as a potential zero-order-waveplate crystal

    Inorganic Chemistry Frontiers · 2022-01-01

    Yuanyu Yang, Yao Guo, Yi-Gang Chen, Xiwei Hu, Xia Zhang, Xian‐Ming Zhang, Xian-Ming Zhang, Xian-Ming Zhang

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  3. An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles

    Journal of Materials Chemistry C · 2023-01-01

    Zhaowei Hu, Lili Liu, Ruixin Zhang, Qun Jing, Huan Wang, Jindan Tian, Jiayue Xu, P. Shiv Halasyamani

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  4. Synthesis and characterization of a new isoxazolone-based nonlinear optical crystal: MPMOI

    CrystEngComm · 2023-01-01

    Ying Yang, Jianjuan Zhao, Xinyuan Zhang, Zhanggui Hu, Yicheng Wu

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  5. Ba1.09Pb0.91Be2(BO3)2F2: The First Pb-Containing Beryllium Borate Fluoride with Trigonal Prismatic PbO6 and 2D [Be3B3O6F3]∞ Layers

    Inorganic Chemistry · 2023-02-20

    Ruixin Guo, Shu Hai Guo, Mingjun Xia, Lijuan Liu, Minjuan Li, Sangen Zhao, Xiaoyang Wang

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  6. Recent Development of Sn II , Sb III ‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie International Edition · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  7. Recent Development of SnII, SbIII‐based Birefringent Material: Crystal Chemistry and Investigation of Birefringence

    Angewandte Chemie · 2023-03-13

    Shujuan Han, Abudukadi Tudi, Wenbin Zhang, Xueling Hou, Zhihua Yang, Shilie Pan

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  8. The synthesis of novel lanthanum hydroxyborate at extreme conditions

    Frontiers in Chemistry · 2023-09-28

    Olga A. Ibragimova, Lia Vaquero, Zain Hussein, Vadym Drozd, Stella Chariton, Vitali B. Prakapenka, Irina Chuvashova

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  9. Hg16O12(NO3)6F2(H2O): A Mercury-Rich Nitrate Oxyfluoride with Diverse Triple-Coordinated Mercury-Based Units That Exhibits an Unparalleled [(Hg16O12F2(H2O))6+]∞ Cationic Framework and a Large Birefringence

    Inorganic Chemistry · 2024-03-28

    Yi‐Lei Lv, Wei Xu, Wen‐Dong Yao, Miao‐Bin Xu, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  10. Influence of Cation-Size Effects of Alkaline Earth (Ae) Metals on Dimensionality and Optical Anisotropy Regulation in K4AeP2S8 Thiophosphates

    Inorganic Chemistry · 2024-04-23

    Xinyu Tian, Ning Zhao, Kui Wu, Jingjing Xu, Dazhi Lu, Haohai Yu, Huaijin Zhang

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  11. Review on birefringence in borates based on birefringence-active functional groups and arrangements

    Science China Chemistry · 2024-06-14

    Qianzhen Zhang, Ran An, Zhihua Yang, Xifa Long, Shilie Pan, Yun Mo Yang

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  12. Structural Evolution and Optical Properties of Hydroxyfluorooxoborates MM′2n-1[B3O3F4(OH)]n (M = K, Cs, and Rb; M′ = K, NH4, and Cs; n = 1, 2, and 3)

    Chemistry of Materials · 2024-11-25

    Huan Pei, Luyong Zhang, Huanhuan Cheng, Shi‐Bin Wang, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  13. Anion ratio-directed design of CaB 4 O 5 F 4 and CaB 6 O 8 F 4 : [BO 3 ]/[BO 2 F 2 ] hybridization tailoring deep-ultraviolet nonlinear optical performance

    Journal of Materials Chemistry C · 2025-01-01

    Ke Li, Abudukadi Tudi, Congwei Xie, Wenqi Jin, Linlin Liu, Miriding Mutailipu, Kenneth Reinhard Poeppelmeier, Fangfang Zhang, Zhihua Yang, Shilie Pan

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  14. RbB 7 O 10 (OH) 2 and NaB 11 O 16 (OH) 2 : alkali metal hydroxyborates with two-dimensional layered structures and large birefringence

    Dalton Transactions · 2025-01-01

    Yujing Zheng, Ke Li, Ling Huang, Fangfang Zhang

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  15. Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F3

    Materials Today Chemistry · 2025-03-06

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Xifa Long, Shilie Pan, Yun Mo Yang

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  16. Synthesis, characterization and theoretical calculations of a new rare-earth fluoride with a DUV cutoff edge

    Journal of Molecular Structure · 2025-04-08

    Xiaotian Ma, Shaohua Liu, Xifa Long, Yun Mo Yang

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  17. SrMBe 2 (BO 3 ) 2 F 2 (M = Zn, Mg): two SBBO-like compounds obtained by cation regulation

    Dalton Transactions · 2025-12-16

    Tong Wu, Lei Kang, Fan Liu, Ruixin Guo, Shu Guo, Tianhong Huang, Shuangyue Shang, Lijuan Liu, Xiaoyang Wang

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  18. Towards equilateral triangular lattice frustrated quantum magnets through crystal symmetry–protected molecular-brick chemical strategy

    Chinese Chemical Letters · 2026-03-15

    Ruixin Guo, Jieming Sheng, Bowen Li, Kaizhen Guo, Wenjiao Yao, Nan Zhao, Jianqiao Wang, Zhibin Qiu, Bo Wen, Shuang Jia, Xiaoyang Wang, Ping Wu, Feng Yang, Liusuo Wu, Qiushi Yao, Shu Guo

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