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RESEARCH PAPER · Chemical Engineering Journal · 2022

Highly Efficient and Stable Deep-Blue Room Temperature Phosphorescence Via Through-Space Conjugation

Zhen Zhang, Yue Shi, Yibo Liu, Yifei Xing, Ding Yi, Zhenguang Wang, Dongpeng Yan

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Highly Efficient and Stable Deep-Blue Room Temperature Phosphorescence Via Through-Space ConjugationOriginalEfficient blue TADF-type organic afterglow material via boric acid-assisted confinement13In-Situ Grafting N-Arylcarbazoles Enables More Ultra-Long Room Temperature Phosphorescence Polymers30KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency33Defects and Structural Limitation-Induced Carbon Dots–Silica Hybrid Materials with Ultralong Room Temperature Phosphorescence46Solid‐State Luminescent Materials with Multiple Emission Colors and Near‐Unity Quantum Yield1Full‐color Persistent Room‐temperature Phosphorescence from Carbon Dot Composites Based on a Single Nonaromatic Carbon Source30Modulating Emission of Organic Emitters from Fluorescence to Red Afterglow through Boric Acid-Assisted Energy Transfer14Multiple Stimuli‐Response Polychromatic Carbon Dots for Advanced Information Encryption and Safety118Modulating Emission of Boric Acid into Highly Efficient and Color‐Tunable Afterglow via Dehydration‐Induced Through‐Space Conjugation67Achieving purple light excitable high-efficiency temperature-responsive dual- and single-mode afterglow in carbon dots91Excitation‐Dependent Long Afterglow Room‐Temperature Phosphorescence Material Activated by Doping Boric Acid Matrix30Carbonaceous Material Modified MoO2 Nanospheres with Oxygen Vacancies for Enhanced Visible-Light Photocatalytic Oxidative Coupling of Benzylamine5Construction of room temperature phosphorescent materials with ultralong lifetime by in-situ derivation strategy56Full-color persistent room temperature phosphorescent elastomers with robust optical properties123Facile preparation strategy of novel B2O3-modified carbon dots with 1.99 s ultra-long Room-Temperature phosphorescence for multidimensional encryption10Enhancing blue phosphorescence in matrix-free carbon dots through covalent crosslinking57Colorful Ultralong Room Temperature Phosphorescent Afterglow with Excitation Wavelength Dependence Based on Boric Acid Matrix92Water stimulus-responsive room temperature afterglow materials with color tunability based on inorganic/organic H–G hybrid systems5Anti-Kasha triplet energy transfer and excitation wavelength dependent persistent luminescence from host-guest doping systems71Visible-light-excited high efficiency multicolor room temperature phosphorescence of carbon dots in boric acid matrix75Phase-transition-induced phosphorescence: A novel icing detection strategy for airplane6One‐Step Fabrication of New PCPNs with Unique Optical Responses for Ultra‐Stable Anti‐Counterfeiting Labels31Achieving Efficient Dark Blue Room‐Temperature Phosphorescence with Ultra‐Wide Range Tunable‐Lifetime131Achieving Efficient Dark Blue Room‐Temperature Phosphorescence with Ultra‐Wide Range Tunable‐Lifetime14Host–Guest Doping Modulated Afterglow Emission of Fluoroquinolones for Their Separation-Free Detection and Discrimination17Achieving Efficient Room-Temperature Phosphorescence in the Host–Guest System through Covalent-Bond-Strengthened Hydrogen Bonding6High pH Stability and Ultralong‐Lived Room Temperature Phosphorescence Carbon Dots in Aqueous Environment45Wide-Color-Tunable Afterglow Materials from Blue to Deep Red via Boric Acid Assisted Molecular Doping4Solution-processable organic–inorganic materials with colorful afterglow at room temperature11Stepwise Stiffening Chromophore Strategy Realizes a Series of Ultralong Blue Room‐Temperature Phosphorescent Materials28Exploring the Ultralong Lifetime of Self‐matrix 1,10 Phenanthroline and Boron‐Based Room Temperature Phosphorescence Carbon Dots for Multiple Applications13Ultralong Blue Organic Room‐Temperature Phosphorescence Promoted by Green Assembly23Boric Acid Matrix‐Activated nπ* Transition of Guest Chromophores: from Pure Fluorescence to Efficient Afterglow12Non‐Covalent Iron‐Armored Chain Horse: A Strategy Leading to Highly Efficient Deep‐Blue Room Temperature Phosphorescence6Producing sustainable flame-retardant room temperature phosphorescent materials from natural wood assisted by borax6Confinement and heating promoted RTP of flumequine, oxolinic acid and levofloxacin on papers for their detection and discrimination6Dynamic Long‐Afterglow Materials with Ultralong Lifetime for Advanced Message Encryption16Intrinsic Narrowband Blue Phosphorescent Materials and Their Applications in 3D Printed Self‐monitoring Microfluidic Chips64Full‐Color Tunability Room Temperature Phosphorescence from Inorganic Crystal Frameworks3Modulating room temperature phosphorescence of acrylamide by stepwise rigidification for its detection in potato crisps5AIE-inspired segregation and immobilization strategies for achieving organic room temperature phosphorescence10Cascade energy transfer endows phosphorescent carbon dots-based films with tunable and broadband afterglow for fingerprint recognition and anticounterfeiting24Color-tunable ultralong room temperature afterglow in a wide excitation range from ultraviolet to visible light via doping boric acid with polyaromatic hydrocarbons0Efficient Time‐dependent Dual‐Model Room Temperature Phosphorescent Carbon Quantum Dots/ Boron Nitride Carbide Oxide Matrices26Achieving Efficient Blue Room‐Temperature Phosphorescence Through Self‐Doping of Similar Structures and Polymer Assistance11Construction of Cross‐Linked Polymer Phosphorescence by Functionalization of Cyclotriphosphazene14Dual-Ring-Locking Strategy Enables Persistent Blue Room Temperature Phosphorescence in Benzo[ b ]phospholiums12High-Temperature Phosphorescence of Carbon Dots by a Synergistic Locking Strategy28Achieving Persistent and Efficient Blue Phosphorescence by Doping Electron‐Deficient Benzenes Into Poly(Acrylic Acid)2Regulation of Conjugation Degree and Nitrogen Doping in Dual‐Confined Carbon Dots Enables Full‐Color‐Tunable Long‐Persistence Room Temperature Phosphorescence7Ultralong room-temperature phosphorescence of crystalline organic luminogens: excitation-dependence, chirality, and host-guest doping4Stimuli‐Responsive Recyclable Polymers with Room‐Temperature Ultralong Phosphorescence for Anti‐Counterfeiting31Intrinsic Bright and Robust Phosphorescence in Sulfur Quantum Dots Enabled by π‐Conjugation Engineering and Covalent Matrix Anchoring6From leaf to light: Amaranth derived red CDs as eco-friendly nanofillers in functional nanocomposites for indoor phyto illumination, active food packaging and forensic applications0Hydrogen‐Bond Engineering in Polymer Networks Enables Multi‐Mode Long‐Lived Blue Room‐Temperature Phosphorescence with High Efficiency0Carbon nitride quantum dots with full-color room-temperature phosphorescence via in situ precursor engineering and rigid matrix confinement9Boosting room-temperature phosphorescence via polarity-induced through-space conjugation in a host–guest doping system2Through-space interactions of optoelectronic materials21A Pyrolysis‐Assisted Strategy for High‐Temperature Resistant Afterglow Materials Through Defect‐Mediated Emission Mechanisms1Highly Efficient Deep‐Blue Room‐Temperature Phosphorescence With Tunable Long‐Lived Afterglow and Reversible Photoactivation Behavior15Highly Efficient Deep‐Blue Room‐Temperature Phosphorescence With Tunable Long‐Lived Afterglow and Reversible Photoactivation Behavior1One‐Step In Situ Synthesis of Carbon Dot‐Based Nanospheres With Underwater Color‐Tunable, Dual‐Mode Long‐Afterglow Emission2High-performance room-temperature phosphorescence achieved by promoting intersystem crossing and suppressing reverse intersystem crossing3Deep-blue long-lived delayed fluorescence enabled by triplet-triplet annihilation strategy for precision afterglow projection2Simultaneous High‐Contrast Time‐Dependent Afterglow Color and High‐Temperature Resistant Materials via Defect‐Mediated Emission Dynamics0Visible-Light-Excited Room-Temperature Afterglow from Carbonized Polymer Dots–Boron Oxide Nanohybrid for Data Encryption0Configuration-dependent host–guest h-bonding enables high-efficiency ultra-long afterglow in boric acid RTP0Achieving photo-activated deep-blue afterglow in single-component copolymers through covalent confinement strategy0

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  1. Efficient blue TADF-type organic afterglow material via boric acid-assisted confinement

    Chemical Communications · 2022-01-01

    Song Shen, Yuena Sun, Donghui Wang, Zhen Zhang, Yue Shi, Zhenguang Wang

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  2. In-Situ Grafting N-Arylcarbazoles Enables More Ultra-Long Room Temperature Phosphorescence Polymers

    Chemical Engineering Journal · 2022-01-01

    Yuefa Zhang, Junwu Chen, Qikun Sun, Haichang Zhang, Shanfeng Xue, Wenjun Yang

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  3. KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency

    Chemical Communications · 2022-01-01

    Yang Li, Xinglong Chen, Kang Min Ok

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  4. Defects and Structural Limitation-Induced Carbon Dots–Silica Hybrid Materials with Ultralong Room Temperature Phosphorescence

    The Journal of Physical Chemistry Letters · 2022-10-06

    Tianyu Chao, Jingjing Wang, Xuezhe Dong, Junkai Ren, Hailong Zhang, Rui Song, Zheng Xie

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  5. Solid‐State Luminescent Materials with Multiple Emission Colors and Near‐Unity Quantum Yield

    Chemistry - A European Journal · 2022-10-27

    Guanjie Wang, Zhen Zhang, Donghui Wang, Yue Shi, Zhenguang Wang

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  6. Full‐color Persistent Room‐temperature Phosphorescence from Carbon Dot Composites Based on a Single Nonaromatic Carbon Source

    Chemistry - An Asian Journal · 2022-12-01

    Xiaolang Wang, Shuaiqi Wang, Yuanshan Huang, Limei Huang, Jianping Sun, Zhenghuan Lin

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  7. Modulating Emission of Organic Emitters from Fluorescence to Red Afterglow through Boric Acid-Assisted Energy Transfer

    The Journal of Physical Chemistry C · 2022-12-27

    Donghui Wang, Yue Shi, Zhen Zhang, Song Shen, Zhenguang Wang

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  8. Multiple Stimuli‐Response Polychromatic Carbon Dots for Advanced Information Encryption and Safety

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  9. Modulating Emission of Boric Acid into Highly Efficient and Color‐Tunable Afterglow via Dehydration‐Induced Through‐Space Conjugation

    Advanced Science · 2023-03-22

    Zhen Zhang, Zhenguang Wang, Xiao Liu, Yue Shi, Zhiqiang Li, Yanli Zhao

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  10. Achieving purple light excitable high-efficiency temperature-responsive dual- and single-mode afterglow in carbon dots

    Carbon · 2023-03-31

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  11. Excitation‐Dependent Long Afterglow Room‐Temperature Phosphorescence Material Activated by Doping Boric Acid Matrix

    Advanced Optical Materials · 2023-04-23

    Junjie Deng, Zhihao Guan, Donglei Fu, Yuewei Zheng, Zhengjie Chen, Houbin Li, Xinghai Liu

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  12. Carbonaceous Material Modified MoO2 Nanospheres with Oxygen Vacancies for Enhanced Visible-Light Photocatalytic Oxidative Coupling of Benzylamine

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  13. Construction of room temperature phosphorescent materials with ultralong lifetime by in-situ derivation strategy

    Nature Communications · 2023-07-13

    Qinglong Jia, Xilong Yan, Bowei Wang, Jiayi Li, Wen‐Sheng Xu, Zhuoyao Shen, Changchang Bo, Yang Li, Ligong Chen

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  14. Full-color persistent room temperature phosphorescent elastomers with robust optical properties

    Nature Communications · 2023-08-10

    Juan Wei, Mingye Zhu, Tingchen Du, Jangang Li, Peiling Dai, Chenyuan Liu, Jiayu Duan, Shujuan Liu, Xingcheng Zhou, Sudi Zhang, Luo Guo, Hao Wang, Yun Ma, Wei Huang, Qiang Zhao

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  15. Facile preparation strategy of novel B2O3-modified carbon dots with 1.99 s ultra-long Room-Temperature phosphorescence for multidimensional encryption

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2023-10-06

    Xilang Jin, Huaqi Zhao, Haiyan Bai, Liu Ding, Weixing Chen

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  16. Enhancing blue phosphorescence in matrix-free carbon dots through covalent crosslinking

    Chemical Engineering Journal · 2023-10-07

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  17. Colorful Ultralong Room Temperature Phosphorescent Afterglow with Excitation Wavelength Dependence Based on Boric Acid Matrix

    Advanced Functional Materials · 2023-10-11

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  18. Water stimulus-responsive room temperature afterglow materials with color tunability based on inorganic/organic H–G hybrid systems

    Journal of Materials Chemistry C · 2023-11-29

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  19. Anti-Kasha triplet energy transfer and excitation wavelength dependent persistent luminescence from host-guest doping systems

    Nature Communications · 2023-12-07

    Weiwei Xie, Wenbin Huang, Jietai Li, Zikai He, Guangxi Huang, Bing Shi Li, Ben Zhong Tang

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  20. Visible-light-excited high efficiency multicolor room temperature phosphorescence of carbon dots in boric acid matrix

    Chemical Engineering Journal · 2023-12-18

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  21. Phase-transition-induced phosphorescence: A novel icing detection strategy for airplane

    Dyes and Pigments · 2024-01-17

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  22. One‐Step Fabrication of New PCPNs with Unique Optical Responses for Ultra‐Stable Anti‐Counterfeiting Labels

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  23. Achieving Efficient Dark Blue Room‐Temperature Phosphorescence with Ultra‐Wide Range Tunable‐Lifetime

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  24. Achieving Efficient Dark Blue Room‐Temperature Phosphorescence with Ultra‐Wide Range Tunable‐Lifetime

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  25. Host–Guest Doping Modulated Afterglow Emission of Fluoroquinolones for Their Separation-Free Detection and Discrimination

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  26. Achieving Efficient Room-Temperature Phosphorescence in the Host–Guest System through Covalent-Bond-Strengthened Hydrogen Bonding

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  27. High pH Stability and Ultralong‐Lived Room Temperature Phosphorescence Carbon Dots in Aqueous Environment

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  28. Wide-Color-Tunable Afterglow Materials from Blue to Deep Red via Boric Acid Assisted Molecular Doping

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  29. Solution-processable organic–inorganic materials with colorful afterglow at room temperature

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  30. Stepwise Stiffening Chromophore Strategy Realizes a Series of Ultralong Blue Room‐Temperature Phosphorescent Materials

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  31. Exploring the Ultralong Lifetime of Self‐matrix 1,10 Phenanthroline and Boron‐Based Room Temperature Phosphorescence Carbon Dots for Multiple Applications

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  32. Ultralong Blue Organic Room‐Temperature Phosphorescence Promoted by Green Assembly

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  33. Boric Acid Matrix‐Activated nπ* Transition of Guest Chromophores: from Pure Fluorescence to Efficient Afterglow

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  34. Non‐Covalent Iron‐Armored Chain Horse: A Strategy Leading to Highly Efficient Deep‐Blue Room Temperature Phosphorescence

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  35. Producing sustainable flame-retardant room temperature phosphorescent materials from natural wood assisted by borax

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  36. Confinement and heating promoted RTP of flumequine, oxolinic acid and levofloxacin on papers for their detection and discrimination

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  37. Dynamic Long‐Afterglow Materials with Ultralong Lifetime for Advanced Message Encryption

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  38. Intrinsic Narrowband Blue Phosphorescent Materials and Their Applications in 3D Printed Self‐monitoring Microfluidic Chips

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  39. Full‐Color Tunability Room Temperature Phosphorescence from Inorganic Crystal Frameworks

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  40. Modulating room temperature phosphorescence of acrylamide by stepwise rigidification for its detection in potato crisps

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  41. AIE-inspired segregation and immobilization strategies for achieving organic room temperature phosphorescence

    Chemical Communications · 2025-01-01

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  42. Cascade energy transfer endows phosphorescent carbon dots-based films with tunable and broadband afterglow for fingerprint recognition and anticounterfeiting

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  43. Color-tunable ultralong room temperature afterglow in a wide excitation range from ultraviolet to visible light via doping boric acid with polyaromatic hydrocarbons

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  44. Efficient Time‐dependent Dual‐Model Room Temperature Phosphorescent Carbon Quantum Dots/ Boron Nitride Carbide Oxide Matrices

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  45. Achieving Efficient Blue Room‐Temperature Phosphorescence Through Self‐Doping of Similar Structures and Polymer Assistance

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  46. Construction of Cross‐Linked Polymer Phosphorescence by Functionalization of Cyclotriphosphazene

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  47. Dual-Ring-Locking Strategy Enables Persistent Blue Room Temperature Phosphorescence in Benzo[ b ]phospholiums

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  48. High-Temperature Phosphorescence of Carbon Dots by a Synergistic Locking Strategy

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  49. Achieving Persistent and Efficient Blue Phosphorescence by Doping Electron‐Deficient Benzenes Into Poly(Acrylic Acid)

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  50. Regulation of Conjugation Degree and Nitrogen Doping in Dual‐Confined Carbon Dots Enables Full‐Color‐Tunable Long‐Persistence Room Temperature Phosphorescence

    Advanced Optical Materials · 2025-05-16

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