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RESEARCH PAPER · Advanced Science · 2023

Modulating Emission of Boric Acid into Highly Efficient and Color‐Tunable Afterglow via Dehydration‐Induced Through‐Space Conjugation

Zhen Zhang, Zhenguang Wang, Xiao Liu, Yue Shi, Zhiqiang Li, Yanli Zhao

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Modulating Emission of Boric Acid into Highly Efficient and Color‐Tunable Afterglow via Dehydration‐Induced Through‐Space ConjugationOriginalLarge‐Scale Preparation for Multicolor Stimulus‐Responsive Room‐Temperature Phosphorescence Paper via Cellulose Heterogeneous Reaction102Room-temperature phosphorescent materials derived from natural resources154Colorful Ultralong Room Temperature Phosphorescent Afterglow with Excitation Wavelength Dependence Based on Boric Acid Matrix92Unusual phosphorescence of boric acid: From impurity or clusterization‐triggered emission?31Water stimulus-responsive room temperature afterglow materials with color tunability based on inorganic/organic H–G hybrid systems5Achieving tunable time-dependent delayed emission color via dynamic competition between the matrix and carbon dots for anti-counterfeiting and multidimensional encryption41Hour‐Level Persistent Multicolor Phosphorescence Enabled by Carbon Dot‐Based Nanocomposites Through a Multi‐Confinement‐Based Approach67Cluster-Triggered Excitation-Dependent Phosphorescence Emission in Polymorphic Arylborinic Acids0Visible-excitable long-afterglow material with dual-mode emission of delayed fluorescence and room temperature phosphorescence7A Universal Strategy for Tuning Afterglow Color In Situ Via Radiative Energy Transfer7Producing naturally degradable room-temperature phosphorescent materials by covalently attaching lignin to natural polymers18Direct Population of Triplet States for Efficient Organic Afterglow through the Intra/Intermolecular Heavy-Atom Effect3Photo- and Oxygen- Synergistically Controlled Selective Expression of Organic Phosphorescence Units21Achieving Efficient Room-Temperature Phosphorescence in the Host–Guest System through Covalent-Bond-Strengthened Hydrogen Bonding6Thermally Enhanced Phosphorescent Carbon Nanodots for Monitoring Cold‐Chain Logistics15Visualizing Motion Trail via Phosphorescence Carbon Nanodots-Based Delay Display Array8Fully Exploiting Clusterization‐Triggered Room Temperature Phosphorescence of Cellulose by Stepwise Rigidification for Long‐Lived and Excitation Wavelength‐Dependent Afterglows49Wide-Color-Tunable Afterglow Materials from Blue to Deep Red via Boric Acid Assisted Molecular Doping4Boric Acid Matrix‐Activated nπ* Transition of Guest Chromophores: from Pure Fluorescence to Efficient Afterglow12Regulation of molecular conjugation to realize mult-color room temperature phosphorescence of carbon dots in urea and ammonium pentaborate precursor matrices9Cluster-triggered excitation-dependent phosphorescence emission in polymorphic arylborinic acid6Dynamic Long‐Afterglow Materials with Ultralong Lifetime for Advanced Message Encryption16Ultrahigh-Temperature Long-Persistent Luminescence from B 2 O 3 -Confined Polycyclic Aromatic Compounds46Recent Advances in Thermally Activated Delayed Fluorescence‐Based Organic Afterglow Materials18Modulating room temperature phosphorescence of acrylamide by stepwise rigidification for its detection in potato crisps5Dual State Emissive AIE Active Carbon Dots with Matrix‐Free Room Temperature Phosphorescence9Aromatic ring compounds with different conjugation degrees in a boronic acid matrix to realize multicolor phosphorescence for time division colorful multiplexing11Color-tunable ultralong room temperature afterglow in a wide excitation range from ultraviolet to visible light via doping boric acid with polyaromatic hydrocarbons0Confining Monochromophore in Dynamic Polymer Network for Multi-Stimuli Responsive Fluorescence-Phosphorescence Dual-Emission0Room-temperature phosphorescence sensor array for the detection and discrimination of neonicotinoid insecticides based on a host–guest doping strategy0Ultra-wide time-dependent phosphorescence color of carbon dots via a synergistic strategy of dual confinement structures constructing multiple luminescent centers24Room temperature phosphorescence-based sensor array for fluorescent brighteners through dehydration-induced doping6Adjusting TADF and Phosphorescence for Tailored Dynamic Time‐Dependent Afterglow Colored Carbon Dots spanning Full Visible Region50Adjusting TADF and Phosphorescence for Tailored Dynamic Time‐Dependent Afterglow Colored Carbon Dots spanning Full Visible Region7Achieving High‐Temperature Resistant Afterglow by Modulating Dual‐Mode Emission of Organic Emitters through Defects Engineering20Ultralong Room Temperature Phosphorescence through Both Space Confinement and Long-Range Charge Migration13Piezoelectric barium titanate/ PVDF-HFP nanocomposite-mediated soft ultrasound assisted organic dye degradation and antibacterial therapy against Bacillus subtilis and Vibrio cholerae5Time-Dependent Room-Temperature Afterglow of Carbon Dots Constructed by Trap-Induced Multiemission Centers28High contrast crystalline, dynamic, and excitation dependent room temperature phosphorescence by tuning acceptor structures11Atomic‐Scale Regulation of Covalent Bonding for Blue Phosphorescence4Thermal modulation for dual-mode high-temperature afterglow7Restricting planar chromophores to achieve long-lived, high color purity, colorful triplet excitons5Guiding the Triplet Excited State Landscape in Host‐Confined Carbon Dots by Orbital Mismatch7Confining monochromophore in polymer network for fluorescence-phosphorescence dual-emission sensing of thiram5Intrinsic Bright and Robust Phosphorescence in Sulfur Quantum Dots Enabled by π‐Conjugation Engineering and Covalent Matrix Anchoring6Dynamic Polymer-Based Room Temperature Phosphorescent Thin Films5Full-color tunable and stimuli-responsive ultralong room- temperature phosphorescence from sesbania galactomannan4Ultralong organic afterglow from small molecular host-guest materials: state of the art21A molecular-based aggregation engineering strategy for high-efficiency deep-blue phosphors3Photoexcitation‐Induced Chiral Self‐Assembly for Phosphorescence‐to‐Thermally Activated Delayed Fluorescence Transformation1Photoexcitation‐Induced Chiral Self‐Assembly for Phosphorescence‐to‐Thermally Activated Delayed Fluorescence Transformation2Full-color programmable high temperature afterglow polymers based on single-molecule emitters15Unlocking the Role of Lignin in Designing the Carbon Dot‐Based Afterglow Composites: Co‐Precursor and Co‐Ligand0A Pyrolysis‐Assisted Strategy for High‐Temperature Resistant Afterglow Materials Through Defect‐Mediated Emission Mechanisms1Organic Phosphorescence from Functional Polymer Matrices25Covalent Bonding Enhanced Structural Rigidity for Boosted Heavy Atom-Free Room-Temperature Phosphorescence1Effect of freeze-thaw cycles on thermal stability and fire retardancy of P/N/B wood composites1In situ Derivation Strategy for Constructing Hour‐level Long‐Persistence Luminescence of Carbon Dots by Matrix Synergy and Internal Charge Transfer6Deep Learning-Assisted Room-Temperature Phosphorescence Sensor Array Based on Host–Guest Doping for Visual Discrimination of Triazole Fungicides1Simultaneous High‐Contrast Time‐Dependent Afterglow Color and High‐Temperature Resistant Materials via Defect‐Mediated Emission Dynamics0A Fiber-Structured Electrochemical Sensor for In Situ Monitoring of Metal Oxide Colloids in Riparian Zones0Scalable Aqueous Polymerization Via Nanoconfinement Effect Generating Two‐Dimensional Polymers With Excitation‐Dependent Clusteroluminescence0Investigation on the crystal growth, spectroscopic, third harmonic generation studies and photocatalytic studies of organic–inorganic hybrid material complex single crystal0Organic room-temperature phosphorescence materials6Visible-Light-Excited Room-Temperature Afterglow from Carbonized Polymer Dots–Boron Oxide Nanohybrid for Data Encryption0Precisely Regulating 2.45 s Pure Blue Room‐Temperature Phosphorescence via Supramolecular Coordination0

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  1. Large‐Scale Preparation for Multicolor Stimulus‐Responsive Room‐Temperature Phosphorescence Paper via Cellulose Heterogeneous Reaction

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  2. Room-temperature phosphorescent materials derived from natural resources

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    Xiongfei Luo, Bing Tian, Yingxiang Zhai, Hongda Guo, Shouxin Liu, Jian Li, Shujun Li, Tony D. James, Zhijun Chen

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  3. Colorful Ultralong Room Temperature Phosphorescent Afterglow with Excitation Wavelength Dependence Based on Boric Acid Matrix

    Advanced Functional Materials · 2023-10-11

    Zhizheng Li, Shuai Cao, Yangyang Zheng, Leqian Song, Huacheng Zhang, Yanli Zhao

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  4. Unusual phosphorescence of boric acid: From impurity or clusterization‐triggered emission?

    Aggregate · 2023-11-22

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  5. Water stimulus-responsive room temperature afterglow materials with color tunability based on inorganic/organic H–G hybrid systems

    Journal of Materials Chemistry C · 2023-11-29

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  6. Achieving tunable time-dependent delayed emission color via dynamic competition between the matrix and carbon dots for anti-counterfeiting and multidimensional encryption

    Chemical Engineering Journal · 2023-12-03

    Yufeng Chang, Nian Fu, Ming‐Jun Chen, You Zhang, Fuxing Li, Zhenyang Liu, Zhenyang Liu, Fenghe Wang, Gang Yue, Li Guan, Li Guan

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  7. Hour‐Level Persistent Multicolor Phosphorescence Enabled by Carbon Dot‐Based Nanocomposites Through a Multi‐Confinement‐Based Approach

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  8. Cluster-Triggered Excitation-Dependent Phosphorescence Emission in Polymorphic Arylborinic Acids

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  9. Visible-excitable long-afterglow material with dual-mode emission of delayed fluorescence and room temperature phosphorescence

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  10. A Universal Strategy for Tuning Afterglow Color In Situ Via Radiative Energy Transfer

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  11. Producing naturally degradable room-temperature phosphorescent materials by covalently attaching lignin to natural polymers

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  12. Direct Population of Triplet States for Efficient Organic Afterglow through the Intra/Intermolecular Heavy-Atom Effect

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  13. Photo- and Oxygen- Synergistically Controlled Selective Expression of Organic Phosphorescence Units

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  14. Achieving Efficient Room-Temperature Phosphorescence in the Host–Guest System through Covalent-Bond-Strengthened Hydrogen Bonding

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  15. Thermally Enhanced Phosphorescent Carbon Nanodots for Monitoring Cold‐Chain Logistics

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  16. Visualizing Motion Trail via Phosphorescence Carbon Nanodots-Based Delay Display Array

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  17. Fully Exploiting Clusterization‐Triggered Room Temperature Phosphorescence of Cellulose by Stepwise Rigidification for Long‐Lived and Excitation Wavelength‐Dependent Afterglows

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  18. Wide-Color-Tunable Afterglow Materials from Blue to Deep Red via Boric Acid Assisted Molecular Doping

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  19. Boric Acid Matrix‐Activated nπ* Transition of Guest Chromophores: from Pure Fluorescence to Efficient Afterglow

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  20. Regulation of molecular conjugation to realize mult-color room temperature phosphorescence of carbon dots in urea and ammonium pentaborate precursor matrices

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  21. Cluster-triggered excitation-dependent phosphorescence emission in polymorphic arylborinic acid

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  22. Dynamic Long‐Afterglow Materials with Ultralong Lifetime for Advanced Message Encryption

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  23. Ultrahigh-Temperature Long-Persistent Luminescence from B 2 O 3 -Confined Polycyclic Aromatic Compounds

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  24. Recent Advances in Thermally Activated Delayed Fluorescence‐Based Organic Afterglow Materials

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  27. Aromatic ring compounds with different conjugation degrees in a boronic acid matrix to realize multicolor phosphorescence for time division colorful multiplexing

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