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RESEARCH PAPER · Chemical Communications · 2022

KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparency

Yang Li, Xinglong Chen, Kang Min Ok

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KF·B(OH) 3 : a KBBF-type material with large birefringence and remarkable deep-ultraviolet transparencyOriginalNaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge5Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra36Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair9Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups14An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles32K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence18KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge6Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence21BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge4Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System15Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps6Clamping effect driven design and fabrication of new infrared birefringent materials with large optical anisotropy45[Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds36Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures27Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F211Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals12PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence12Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds9Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn 3 B 7 O 13 Cl2NaVSeO 5 : synergistic combinations to synthesize excellent birefringent materials8Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties18Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O3Li2B5O8Cl: A New Borate Chloride with Interpenetrating 3D B–O Frameworks Enriching Structural Chemistry of Borate0Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals66Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals8Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units19CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge3Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal6Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F34Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations2Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups0Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates0From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates0

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  1. NaB3O4F(OH): A Hydroxyfluorooxoborate with One-Dimensional Chain Featuring Large Birefringence and Short Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2022-08-18

    Yu Dang, Dongdong Chu, Zhihua Yang, Hongsheng Shi, Shilie Pan

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  2. Ba6Zn6(B3O6)6(B6O12): Barium Zinc Borate Contains π-Conjugated [B3O6]3– Anions and [B6O12]6– Anion with Edge-Sharing BO4 Tetrahedra

    Inorganic Chemistry · 2022-10-28

    Weijie Xie, Zhi Gang Fang, Jiang‐Gao Mao

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  3. Sn3B10O17Cl2 Achieving Birefringence Enhancement by Stereochemical Activity Lone Pair

    Inorganic Chemistry · 2022-11-01

    Lihan Deng, Mengfan Wu, Zhihua Yang, Shujuan Han, Shilie Pan

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  4. Li2PbB2O5: A Pyroborate with Large Birefringence Induced by the Synergistic Effect of Stereochemical Active Lone Pair Cations and π-Conjugated [B2O5] Groups

    Inorganic Chemistry · 2022-11-04

    Jingdong Yan, Dongdong Chu, Zilong Chen, Jian Wei Han

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  5. An effective pathway to design and synthesize UV birefringent crystals via rational assembly of π-conjugated [CO 3 ] 2− and [NO 3 ] − triangles

    Journal of Materials Chemistry C · 2023-01-01

    Zhaowei Hu, Lili Liu, Ruixin Zhang, Qun Jing, Huan Wang, Jindan Tian, Jiayue Xu, P. Shiv Halasyamani

    Read original paper ↗ ·

  6. K 5 [B 3 O 3 F 4 (OH)] 2 (NO 3 ): the first hydroxyfluorooxoborate-nitrate with a short ultraviolet cutoff edge and large birefringence

    Dalton Transactions · 2023-01-01

    Luyong Zhang, Shi‐Bin Wang, Fangfang Zhang, Zhihua Yang, Xueling Hou

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  7. KRb 2 (NO 3 ) 2 Cl: a new birefringent crystal exhibiting a perovskite-related framework and a short cutoff edge

    Dalton Transactions · 2023-01-01

    Zhiyuan Zhang, Die Xu, Zhencheng Wu, Mei Hu, Xin Su, Yineng Huang

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  8. Structure and optical property evolution in PbM(PO 4 )X (M = Zn, Sn; X = halogen): SHG effect and birefringence

    Inorganic Chemistry Frontiers · 2023-01-01

    Xiaobao Li, Chun‐Li Hu, Fang Kong, Jiang‐Gao Mao

    Read original paper ↗ ·

  9. BaB2P2O8F2: A Fluoroborophosphate with [B2P2O8F2]∞ Layers and Deep-Ultraviolet Cutoff Edge

    Inorganic Chemistry · 2023-01-04

    Jinbin Fan, Mengfan Wu, Bingliang Cheng, Jian Wei Han

    Read original paper ↗ ·

  10. Rational Design of the First Ammonium Magnesium Borate with Deep-Ultraviolet Cutoff Edge and Moderate Birefringence and Further Investigation into the Nature of Ammonium in the Borate System

    Inorganic Chemistry · 2023-01-18

    Feixiang Wang, Mengfan Wu, Zhihua Yang, Xifa Long, Yun Mo Yang, Shilie Pan

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  11. Two Carboxylate-Cyanurates with Strong Optical Anisotropy and Large Band Gaps

    Inorganic Chemistry · 2023-01-23

    Yan Chen, Chun‐Li Hu, Zhi Gang Fang, Jiang‐Gao Mao

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  12. Clamping effect driven design and fabrication of new infrared birefringent materials with large optical anisotropy

    Science China Chemistry · 2023-03-13

    Linan Wang, Chenchen Tu, Hongbo Gao, Jiazheng Zhou, Hongshan Wang, Zhihua Yang, Shilie Pan, Junjie Li

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  13. [Ba4(S2)][ZnGa4S10]: Design of an Unprecedented Infrared Nonlinear Salt‐Inclusion Chalcogenide with Disulfide‐Bonds

    Small · 2023-06-04

    Kaixuan Ding, Hongping Wu, Zhanggui Hu, Jiyang Wang, Yicheng Wu, Hongwei Yu

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  14. Fluorooxoborate Promoting the Exploration of Short-Wavelength Linear and Nonlinear Optical Crystals with Expected Properties and Versatile Structures

    Chemistry of Materials · 2023-07-07

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Zilong Chen, Xueling Hou, Zhihua Yang, Shilie Pan

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  15. Introduction of the [B–O/F] Units Enhances the Band Gap and Birefringence from Na6Mg3B10O18F6 to K3NaB10O16F2

    Inorganic Chemistry · 2023-07-26

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Changyou Liu, Xifa Long, Yun Mo Yang

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  16. Three Borates Belonging to the A(I)7Ae(II)Re(III)2B15O30 Family as Promising Nonlinear Optical Crystals

    Crystal Growth & Design · 2023-08-21

    Chengfa Wu, Yu Dang, Jianbang Chen, Xueling Hou, Hongsheng Shi

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  17. PbTeB 4 O 9 : a lead tellurium borate with unprecedented fundamental building block [B 4 O 10 ] and large birefringence

    Chemical Communications · 2023-11-28

    Ruonan Zhang, Abudukadi Tudi, Xia Yang, Xuping Wang, Zhihua Yang, Shujuan Han, Shilie Pan

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  18. Achieving great optical anisotropy with the well-directed alignment of π-conjugated groups due to hydrogen bonds

    Journal of Saudi Chemical Society · 2023-12-16

    Chenhui Hu, Junjie Liu, Jiale Qu, Jinghui Hu, Xiangzhan Jiang

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  19. Crystal growth and spontaneous polarization mechanism of polar metal borate halides: Mn 3 B 7 O 13 Cl

    CrystEngComm · 2024-01-01

    Haodong Li, Duo Zhang, Jiesen Guo, Qiangqiang Wang, Yuxin Ma, Munan Hao, Yuetong Wu, Fanshu Meng, Tianming Liu, Yibo Xu, Chen Xu, Changchun Zhao, Dezhong Meng, Zhiyuan Zheng, Ruijin Sun

    Read original paper ↗ ·

  20. NaVSeO 5 : synergistic combinations to synthesize excellent birefringent materials

    Inorganic Chemistry Frontiers · 2024-01-01

    Qiuyuan Feng, Jialong Wang, Changyou Liu, Qun Jing, Xiaoyu Dong

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  21. Strategically designed metal-free deep-ultraviolet birefringent crystals with superior optical properties

    Chemical Science · 2024-01-01

    Yang Li, Xinglong Chen, Kang Min Ok

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  22. Syntheses, structures and properties of two new members of the pentaborate family: NaKB 5 O 8 (OH)·H 2 O and KB 5 O 8 ·2H 2 O

    Dalton Transactions · 2024-01-01

    Xiaojing Li, Luyong Zhang, Fuming Li, Zhihua Yang, Xueling Hou, Fangfang Zhang

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  23. Li2B5O8Cl: A New Borate Chloride with Interpenetrating 3D B–O Frameworks Enriching Structural Chemistry of Borate

    ECS Journal of Solid State Science and Technology · 2024-03-04

    Lihan Deng, Chunyan Bai, Jin Li, N. T. Zhang

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  24. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie International Edition · 2024-06-26

    Yang Li, Kang Min Ok

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  25. Breaking Boundaries: Giant Ultraviolet Birefringence in Dimension‐Reduced Zn‐Based Crystals

    Angewandte Chemie · 2024-06-26

    Yang Li, Kang Min Ok

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  26. Na2B6SO13 with unprecedented [B6SO13]∞ double chains and largest birefringence among borosulfates induced by the uniform arrangement of [B3O7] units

    Science China Chemistry · 2024-08-19

    Jinbin Fan, Ziting Yan, Zilong Chen, Huimin Li, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  27. CsBO(OH) 2 : a new hydroxyborate with the rare [BO(OH) 2 ] group and a deep ultraviolet cutoff edge

    Chemical Communications · 2025-01-01

    Jinbin Fan, Luyong Zhang, Zilong Chen, Huimin Li, Zhihua Yang, Yun Mo Yang, Fangfang Zhang, Shilie Pan

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  28. Assembly of π-conjugated [B3O7] groups by unprecedented antiparallel triangles [ZnO3] to tailor a deep-UV zinc borate birefringent crystal

    Chinese Chemical Letters · 2025-01-07

    Ning Yang, Huijian Zhao, Wenli Zhao, Yuheng She, Ning Ye, Zhanggui Hu, Conggang Li

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  29. Size effect of cations in the A2B3O4F3 family: Based on the new member Cs2B3O4F3

    Materials Today Chemistry · 2025-03-06

    Bingliang Cheng, Wenjuan Ma, Abudukadi Tudi, Fangfang Zhang, Xifa Long, Shilie Pan, Yun Mo Yang

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  30. Enhancement of Birefringence in Alkali Metal Sulfates Induced by Rare Earth Metal-Centered Polyhedra and Structure Regulation via Cations

    Chemistry of Materials · 2025-10-23

    Luyong Zhang, Zhencheng Wu, Jingdong Yan, Shibin Wang, Zilong Chen, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  31. Design of borate-squarate hybrid crystals with large birefringence by synergistic assembly of planar π-conjugated groups

    Dalton Transactions · 2026-01-01

    Haowen Li, X Y Wang, Hui Chai, Fangfang Zhang

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  32. Significant Enhancement of Birefringence Resulting from the Introduction of [BO 2 (OH)] Groups into Borosulfates

    Chemistry of Materials · 2026-03-04

    Luyong Zhang, Jianyi Zuo, Guangsheng Xu, Jinbin Fan, Xue Bai, Zhihua Yang, Fangfang Zhang, Shilie Pan

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  33. From High Symmetry to High Symmetry: A Self‐Assembly Strategy for Synthesizing Large Birefringent Borates

    Small · 2026-08-03

    Chunjie Shen, Junwei Feng, Zhihua Yang, Shilie Pan, Feng Zhang

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