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RESEARCH PAPER · The Journal of Physical Chemistry C · 2021

Method to Measure the Degree of Reduction of Eu3+ to Eu2+: How Anion and Cation Vacancies Influence the Degree of Reduction

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Method to Measure the Degree of Reduction of Eu3+ to Eu2+: How Anion and Cation Vacancies Influence the Degree of ReductionOriginalNUV-pumped red-emitting Ca 9 MnK(PO 4 ) 7 phosphor: energy transfer and charge compensation3Tunable Luminescence and Oxygen Defects of the Spinel MgAl 2O 4: Eu 3+/Eu 2+ for Photonic Application0Stable Tunable Luminescence of Hetero-valent Eu Ion Activated Ba2InTaO6 Phosphors Synthesized by Defect-Induced Self-Reduction in the Molten-Salt Method16Structural and Luminescence Behavior of Nanocrystalline Orthophosphate KMeY(PO4)2: Eu3+ (Me = Ca, Sr) Synthesized by Hydrothermal Method17Luminescent enhancement of cyan BaSi2O2N2:Eu2+ phosphor by addition of Ho3+10Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Blue-light-excited red emission in a CaO:Eu phosphor17Tunable luminescence and oxygen defects of the spinel MgAl2O4: Eu3+/Eu2+ for photonic application3Elucidating the Multisite and Multivalence Nature of Mn Ions in Solids and Predicting Their Optical Transition Properties: A Case Study on a Series of Garnet Hosts14Stabilization of Eu 2+ in Li 2 B 4 O 7 with the BO 3 network through U 6+ co-doping and defect engineering8Annealing-assisted optimization for persistency of afterglow of SrAl 2 O 4 :Eu 2+ /Dy 3+ microparticles for forensic detection6Anomalous oxidation state of europium in the Sr3(PO4)2-type phosphors doped with alkaline cations6Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate Phosphor39Structural and Luminescence Properties of Eu-Doped PMO Films with Ethylene Bridge and Methyl Terminal Groups3Experimental and theoretical studies of a novel europium decorated carbon nanotube material: investigation of cytotoxicity, electrocatalytic properties, and corrosion inhibition behaviour on Mg AZ31 alloy in 3.5% NaCl environment2Multifaceted insight into the cation-disordered self-activated luminescence of Zn 3 V 2 O 8 compositions for lighting and pigment applications15Enhanced piezoelectric properties in europium-doped lead lanthanum zirconate titanate thin films1Synthesis and photoluminescence properties of Ba3(PO4)2:Eu3+/2+ phosphors5Ionoluminescence from Europium-doped BaMgAl10O17 nanophosphors under different doping concentrations4Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method4Reduction process and energy transfer from Eu 3+ /Sm 3+ co-doped Sr 2 MgSi 2 O 7 phosphors by heat treatment in 100% H 2 gas environment7Does the blue luminescence of Eu-doped β-NaYF4 originate from Eu2+ ions?1Swift heavy ion beam-induced oxidation of Eu2+ to Eu3+ and charge transfer processes in Mn-Eu doped BaMgAl10O17 nanophosphors3Monazite LaPO4: Eu nanorods annealed in air atmosphere: Luminescence optimization and co-existence of Eu2+/Eu3+1Li+ induced enhancements in Eu3+→Eu2+ reduction and photoluminescence properties of Eu-doped KAlSi2O6 phosphors for WLED applications8Comprehensive H2-TPR Study of the Lanthanide Oxides Reducibility17Therapeutic efficacy of the polidocanol versus pingyangmycin in the treatment of maxillofacial vascular disorders0Structural, luminescent properties and Sm3+ → Sm2+ reduction in H2 gas atmosphere of Tb3+/Sm3+ co-activated lithium sodium borate glasses2Facile Reversible Eu2+/Eu3+ Redox in Y2SiO5 via Spark Plasma Sintering: Dwell Time-Dependent Luminescence Tuning1Energy-Efficient Europium-Based 2D Perovskite ReRAM for Photo-Tunable Neuromorphic Computing1Tunable Synaptic Plasticity in Europium 2-D Perovskite ReRAM With Sub-0.5 V Switchings0Incorporation of broadband-emitting Eu2+/3+ YAG microspheres into the glass matrix0Ground-State Thermally Coupled Levels in BaMoO₄:Eu³⁺: A Self-Calibrated Ratiometric Thermometer with Spectroscopically Validated Boltzmann Parameters0Molten salt synthesis of Eu 2+ -doped Sr 5 (PO 4 ) 3 Cl in air atmosphere: europium self-reduction and optical properties1Defect-band reconstruction regulated by Zn²⁺/Eu³⁺ co-doping for color-tunable persistent luminescence in inverse-spinel Mg2-xZnxSnO41Optical thermometry application based on intensive blue emission of Eu-doped Al2O3 nanoparticles embedded in silica-glass host matrix1Unexpected Reduction of Eu3+ Ions to Eu2+ on a Nanodiamond Surface: An XPS, NMR, EPR, and Photoluminescence Study0

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  2. Tunable Luminescence and Oxygen Defects of the Spinel MgAl 2O 4: Eu 3+/Eu 2+ for Photonic Application

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  3. Stable Tunable Luminescence of Hetero-valent Eu Ion Activated Ba2InTaO6 Phosphors Synthesized by Defect-Induced Self-Reduction in the Molten-Salt Method

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  4. Structural and Luminescence Behavior of Nanocrystalline Orthophosphate KMeY(PO4)2: Eu3+ (Me = Ca, Sr) Synthesized by Hydrothermal Method

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  9. Elucidating the Multisite and Multivalence Nature of Mn Ions in Solids and Predicting Their Optical Transition Properties: A Case Study on a Series of Garnet Hosts

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  11. Annealing-assisted optimization for persistency of afterglow of SrAl 2 O 4 :Eu 2+ /Dy 3+ microparticles for forensic detection

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  13. Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate Phosphor

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  14. Structural and Luminescence Properties of Eu-Doped PMO Films with Ethylene Bridge and Methyl Terminal Groups

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    Md Rasadujjaman, Jinming Zhang, Jinming Zhang, Alexey S. Vishnevskiy, Jing Zhang, Jing Zhang, Mikhaı̈l R. Baklanov

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  15. Experimental and theoretical studies of a novel europium decorated carbon nanotube material: investigation of cytotoxicity, electrocatalytic properties, and corrosion inhibition behaviour on Mg AZ31 alloy in 3.5% NaCl environment

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  16. Multifaceted insight into the cation-disordered self-activated luminescence of Zn 3 V 2 O 8 compositions for lighting and pigment applications

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  17. Enhanced piezoelectric properties in europium-doped lead lanthanum zirconate titanate thin films

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  18. Synthesis and photoluminescence properties of Ba3(PO4)2:Eu3+/2+ phosphors

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  19. Ionoluminescence from Europium-doped BaMgAl10O17 nanophosphors under different doping concentrations

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  20. Synthesis, Optical, and Magnetic Properties of the Mixed Chalcogenide Semiconductor Series Eu(II)2SiSexS4-x, Prepared via the Flux-Assisted Boron Chalcogen Mixture Method

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  21. Reduction process and energy transfer from Eu 3+ /Sm 3+ co-doped Sr 2 MgSi 2 O 7 phosphors by heat treatment in 100% H 2 gas environment

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  22. Does the blue luminescence of Eu-doped β-NaYF4 originate from Eu2+ ions?

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  23. Swift heavy ion beam-induced oxidation of Eu2+ to Eu3+ and charge transfer processes in Mn-Eu doped BaMgAl10O17 nanophosphors

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  29. Facile Reversible Eu2+/Eu3+ Redox in Y2SiO5 via Spark Plasma Sintering: Dwell Time-Dependent Luminescence Tuning

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  32. Incorporation of broadband-emitting Eu2+/3+ YAG microspheres into the glass matrix

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