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RESEARCH PAPER · Inorganic Chemistry · 2023

Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate Phosphor

Hongling Wang, Ke Su, Lefu Mei, Qingfeng Guo, Libing Liao

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Vacancy-Enhanced Self-Reduction of Eu in Pyrophosphate PhosphorOriginalEfficient trivalent chromium ions doped ZnLu2Al4SiO12 garnet phosphor: Crystal structure, optical properties and application15Charge compensators achieve controlled self-reduction of Europium in BaMgP2O730Utilizing diametrically opposite thermal quenching luminescence to achieve highly sensitive temperature measurement and anti-counterfeiting24Crystal structure and microwave dielectric properties of BaZnP2O7-based ceramics with Sr2+ substitution11Design opto-thermo-mechano-multi-responsive luminescence from Sr4Al14O25: Eu2+, Nd3+, Tm3+ for optical information storage8Defect regulation of a distinctive synthetic Eu2+-doped SiAlON S-phase towards controllable spectra and thermal quenching for white-light-emitting diode17Achieving multi-wavelength excitation and multi-color tunable emission in self-reducing phosphor of Ba2MgSi2O7: Eu2+/Eu3+16Europium Ions Self‐Reduction Benefiting from AlO4/Si(Al)O4 Network Structure for Multimode Optical Thermometry Manometry27Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review18Wide Range Near‐Zero Thermal Quenching of Orange–Yellow Phosphor via Impeding Self‐Oxidation of Eu 2+ for Versatile Optoelectronic Applications20Cation substitution strategy realizing controllable spectral shape and multiple applications in a novel blue-cyan emitting KBaScSi2O7:Bi3+ phosphor4Phase Transition of α-Mg2P2O7 at High-Pressure and High-Temperature Conditions: The Third Polymorph of Mg2P2O73Non‐volatile and Secure Optical Storage Medium with Multilevel Information Encryption18Defect-Enabled Superior Negative Thermal Quenching in Palmierite Ba9La(VO4)7:Eu3+ for WLED In Situ Temperature Measuring12Cl− skeleton modification and K+ charge compensation construct Eu2+ subcrystalline luminescent structure in NaAlSiO46Ce3+-doped CaSrSiO4 blue phosphor prepared via a novel self-reduction strategy for high-CRI solid-state lighting and visible light communication11Tunable broadband visible emission achieved by phase transformation-driven self-reduction of Eu 3+ to Eu 2+ in a calcium phosphate matrix6Reduction process and energy transfer from Eu 3+ /Sm 3+ co-doped Sr 2 MgSi 2 O 7 phosphors by heat treatment in 100% H 2 gas environment7Toward Recyclable, Luminescent Transparent Wood Film via Synergistic Light Responses of Lignocellulose and Phosphors for Plant Growth Lighting and Optical Thermometer15Charge-space dual effects inducing Eu2 +-Ce3 + ions occupancy luminescence in NaSiAlO4 constructed by waste glass coupled aluminum air batteries byproduct Al(OH)32Facilitated self-reduction of manganese through alkali metal ions co-doping and photoluminescence properties in CaSb2O6 host lattice3Self-reduction regulation in NaZr2(PO4)3: Eu2+/Eu3+ phosphor and their potential optical thermometric applications4Achieving defect resistance engineering through alkaline charge compensation: Synergistic enhancement of luminescence and thermal stability for Ca3Ga2Ge3O12:Dy3+0Thermal modulation of Cr3 + excited states population in BaLu2Al4SiO12 garnet for biological window temperature sensing and precision agricultural lighting7Oxygen vacancy‐induced cerium self‐reduction in cyan‐emitting phosphors for high‐quality white lighting and visible light communication applications7Novel Bi3+/Eu3+ co-doped Sr3Gd(BO3)3 phosphors with high thermal stability and near-white light emission via energy transfer4Facile Reversible Eu2+/Eu3+ Redox in Y2SiO5 via Spark Plasma Sintering: Dwell Time-Dependent Luminescence Tuning1Ce3+ → Pr3+ energy transfer and traps boosting thermal stability of KSrScSi2O7: Ce3+, Pr3+ phosphor for full-spectrum solid-state lighting2A multifunctional phosphor CaLaAl3O7: Eu2+, Eu3+ capable of achieving high sensitivity thermometry and wide color gamut ‘temperature mapping’6Smart tri-mode imaging material for on-demand visual encryption and dynamic displays0A dual-reduction strategy for Eu3 + via air-atmosphere calcination: Achieving efficient white-light emission and enhanced thermal stability in Ba3P4O13: Eu2+ phosphors1Constructing Framework Defects via B3+/B3+-P5+ Substitution for Si4+ to Regulate Mn2+ Site Occupancy Luminescence0Molten salt synthesis of Eu 2+ -doped Sr 5 (PO 4 ) 3 Cl in air atmosphere: europium self-reduction and optical properties1Preparation of Ba[B 8 O 11 (OH) 4 ]:Eu 2+ High Efficiency UVA Phosphor by Low-temperature Self-reduction Method1Suppressing concentration quenching in Eu3+/Tb3+-doped phosphates via site-self-limiting crystal structures2Photochromism and dynamic photoluminescence in CaAl12O19:Eu, Ce phosphor for dual-mode anti-counterfeiting and encryption applications0Multi-site regulation and luminescence enhancement of narrow-band green-emitting Sr2Li(Al,Ga)(O,N)4: Eu2+ phosphors1Defect-Engineered NaTb(MoO 4 ) 2 : Linking Structural Distortion to Enhanced Green Emission and Formaldehyde Sensing0Enhanced Photoluminescence Quantum Efficiency and Thermal Stability of Cyan‐Emitting Li 2 CaSiO 4 :Eu 2+ Phosphor via a Heterovalent Substitution Strategy0

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  1. Efficient trivalent chromium ions doped ZnLu2Al4SiO12 garnet phosphor: Crystal structure, optical properties and application

    Journal of Luminescence · 2023-09-07

    Peiying Yang, Shiying Luo, Limin Liu, Keyan Qian, Yachun Zhang, Yachun Zhang, Shuwen Wen, Yu Yang, Changdong Chen, Xuejun Shi, Yanbing Zhang, Xuliang Zhang, Shuang Ma, Xuliang Zhang

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  2. Charge compensators achieve controlled self-reduction of Europium in BaMgP2O7

    Chemical Engineering Journal · 2023-11-17

    Hongling Wang, Ke Su, Bin Ma, Yujia Wang, Lefu Mei, Qingfeng Guo, Libing Liao

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  3. Utilizing diametrically opposite thermal quenching luminescence to achieve highly sensitive temperature measurement and anti-counterfeiting

    Inorganic Chemistry Frontiers · 2023-12-13

    Haijie Guo, Yaqi Chen, Lei Wang, Qiufeng Shi, Cai’e Cui, Ping Huang, Jianwei Qiao

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  4. Crystal structure and microwave dielectric properties of BaZnP2O7-based ceramics with Sr2+ substitution

    Ceramics International · 2023-12-14

    Min Yang, Yong Zheng, Weimin Ding, Jin Lv, Lan Wang, Zhiyi Jiang, Xuepeng Lu, Zuowei Dong

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  5. Design opto-thermo-mechano-multi-responsive luminescence from Sr4Al14O25: Eu2+, Nd3+, Tm3+ for optical information storage

    Ceramics International · 2023-12-29

    Zhichao Liu, Xiuxia Yang, Xue Yu, Jianqiang Xiao, Peng Zhang, Daiyuan Liu, Jian Zhang, Xuhui Xu, Jianbei Qiu

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  6. Defect regulation of a distinctive synthetic Eu2+-doped SiAlON S-phase towards controllable spectra and thermal quenching for white-light-emitting diode

    Chemical Engineering Journal · 2024-02-22

    Wanying Geng, Xing Han, Zhengyue Sun, Anzheng Wang, Jinlei Zhao, Xufeng Zhou

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  7. Achieving multi-wavelength excitation and multi-color tunable emission in self-reducing phosphor of Ba2MgSi2O7: Eu2+/Eu3+

    Journal of Luminescence · 2024-02-29

    Wenying Teng, Houhe Dong, Chen Hu, Xiaowei Yang, Jiaqi Wang, Xukun Liang, Bowen Yang, Jinrui Ru, Bing Teng, Degao Zhong

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  8. Europium Ions Self‐Reduction Benefiting from AlO4/Si(Al)O4 Network Structure for Multimode Optical Thermometry Manometry

    Laser & Photonics Review · 2024-06-14

    Ruiying Lu, Xinyao Zhang, Yuanyuan Fang, Xue Wu, Mochen Jia, Kai Wang, Jinfei Wu, Qian Li, Zhen Hui Sun

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  9. Structure Modulation and Charge Transfer in Self‐Reduction Phosphors: A Review

    Laser & Photonics Review · 2024-08-09

    Hongling Wang, Lefu Mei, Ke Su, Jingyi Liu, Qi Wang, Zhaojie Wu, Qingfeng Guo, Libing Liao

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  10. Wide Range Near‐Zero Thermal Quenching of Orange–Yellow Phosphor via Impeding Self‐Oxidation of Eu 2+ for Versatile Optoelectronic Applications

    Small · 2024-09-03

    Yang Ding, Xinyue Lu, Soumyajit Maitra, Yan Wang, Qinan Mao, Meijiao Liu, Ning Han, Jiasong Zhong

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  11. Cation substitution strategy realizing controllable spectral shape and multiple applications in a novel blue-cyan emitting KBaScSi2O7:Bi3+ phosphor

    Materials Research Bulletin · 2024-10-01

    Minliang Deng, Yixin Sun, Yining Wang, Xiaole Xing, Mengmeng Shang

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  12. Phase Transition of α-Mg2P2O7 at High-Pressure and High-Temperature Conditions: The Third Polymorph of Mg2P2O7

    Inorganic Chemistry · 2024-10-08

    Shuangmeng Zhai, Xiangping Gu, Yu He, Weihong Xue, Hexiong Yang

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  13. Non‐volatile and Secure Optical Storage Medium with Multilevel Information Encryption

    Advanced Science · 2024-10-16

    Jie Shao, Xiyang Li, Meng Liu, Haiqin Sun, Dengfeng Peng, Fuchi Liu, Qiwei Zhang

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  14. Defect-Enabled Superior Negative Thermal Quenching in Palmierite Ba9La(VO4)7:Eu3+ for WLED In Situ Temperature Measuring

    Inorganic Chemistry · 2024-10-23

    Juanjuan Kong, Naijia Liu, Yun Xu, Yunjian Wang, Zibo Wang, Lei Geng

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  15. Cl− skeleton modification and K+ charge compensation construct Eu2+ subcrystalline luminescent structure in NaAlSiO4

    Optical Materials · 2024-10-24

    Wenjiao Deng, Jingwen Zhang, Weihua Zhu, Zhifeng Zhang, Fabin Cao, Weiming Liu, Xingmei Shen

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  16. Ce3+-doped CaSrSiO4 blue phosphor prepared via a novel self-reduction strategy for high-CRI solid-state lighting and visible light communication

    Journal of Rare Earths · 2024-12-27

    Yuqi Cai, Chunyu Zuo, Weiling Yang, Yifeng Zhu, Shuai Yang, Yingchao Li, Yingchao Li, Xin Qiao Zhao, Chunzhong Li, Chunzhong Li

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  17. Tunable broadband visible emission achieved by phase transformation-driven self-reduction of Eu 3+ to Eu 2+ in a calcium phosphate matrix

    Dalton Transactions · 2025-01-01

    Sapargali Pazylbek, Jonas Stadulis, Guna Doke, Andris Antuzevičš, Vladimir A. Pankratov, Greta Merkininkaitė, Artūras Katelnikovas, Aleksej Žarkov

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  18. Reduction process and energy transfer from Eu 3+ /Sm 3+ co-doped Sr 2 MgSi 2 O 7 phosphors by heat treatment in 100% H 2 gas environment

    Journal of Physics and Chemistry of Solids · 2025-01-28

    Nguyen Thi Quynh Lien, Lê Xuân Hưng, Nguyễn Thị Phương Thảo, Tran Thi Hong, Trinh Ngoc Đat, Nguyen Ngoc Trac, Phan Văn Độ, Hồ Văn Tuyến

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  19. Toward Recyclable, Luminescent Transparent Wood Film via Synergistic Light Responses of Lignocellulose and Phosphors for Plant Growth Lighting and Optical Thermometer

    Advanced Functional Materials · 2025-04-14

    Huan Chen, Junqing Chen, Ruiyu Mi, Yangai Liu, Lefu Mei, Xin Min, Minghao Fang, Xiaowen Wu, Zhaohui Huang, Chaoji Chen

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  20. Charge-space dual effects inducing Eu2 +-Ce3 + ions occupancy luminescence in NaSiAlO4 constructed by waste glass coupled aluminum air batteries byproduct Al(OH)3

    Construction and Building Materials · 2025-05-02

    Wenjiao Deng, Zhifeng Zhang, Chaoyu Qin, Fabin Cao, Weiming Liu, Xingmei Shen

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  21. Facilitated self-reduction of manganese through alkali metal ions co-doping and photoluminescence properties in CaSb2O6 host lattice

    Ceramics International · 2025-07-01

    Fenzhong Long, Jiawei Fu, Lu Xie, Xinmin Zhang, Jin Han

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  22. Self-reduction regulation in NaZr2(PO4)3: Eu2+/Eu3+ phosphor and their potential optical thermometric applications

    Journal of Alloys and Compounds · 2025-07-15

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  23. Achieving defect resistance engineering through alkaline charge compensation: Synergistic enhancement of luminescence and thermal stability for Ca3Ga2Ge3O12:Dy3+

    Ceramics International · 2025-08-15

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  24. Thermal modulation of Cr3 + excited states population in BaLu2Al4SiO12 garnet for biological window temperature sensing and precision agricultural lighting

    Journal of Alloys and Compounds · 2025-09-01

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  25. Oxygen vacancy‐induced cerium self‐reduction in cyan‐emitting phosphors for high‐quality white lighting and visible light communication applications

    Rare Metals · 2025-09-02

    Yuqi Cai, Chunyu Zuo, Weiling Yang, Xiaoqing Pei, Yifeng Zhu, Shuai Yang, Yingchao Li, Xin Le Zhao, Zhuang Liu, Chun Li

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  26. Novel Bi3+/Eu3+ co-doped Sr3Gd(BO3)3 phosphors with high thermal stability and near-white light emission via energy transfer

    Ceramics International · 2025-09-24

    Wenzhi Wang, Xiangyang Guo, Liwei Wang, Ying Tong, Weixian Chen, Zhuo Zhang

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  27. Facile Reversible Eu2+/Eu3+ Redox in Y2SiO5 via Spark Plasma Sintering: Dwell Time-Dependent Luminescence Tuning

    Inorganics · 2025-09-30

    Fernando Juárez-López, Merlina Angélica Navarro-Villanueva, Rubén Cuamatzi-Meléndez, Margarita García-Hernández, María José Soto-Miranda, Ángel de Jesús Morales-Ramírez

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  28. Ce3+ → Pr3+ energy transfer and traps boosting thermal stability of KSrScSi2O7: Ce3+, Pr3+ phosphor for full-spectrum solid-state lighting

    Ceramics International · 2025-10-10

    Liang Dong, Sihan Yang, Jian He, Qi Zhu, Ji‐Guang Li, Xuejiao Wang

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  29. A multifunctional phosphor CaLaAl3O7: Eu2+, Eu3+ capable of achieving high sensitivity thermometry and wide color gamut ‘temperature mapping’

    Journal of Alloys and Compounds · 2025-11-01

    Jialin Cui, Shikun Su, Ruimao Li, Hui Xu, Wenhua Yang, Lizhen Zhao, Wei Qin, Bing Teng, Chen Hu, Shijia Sun, Wei Wang, Haiyang Zhang, Degao Zhong

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  30. Smart tri-mode imaging material for on-demand visual encryption and dynamic displays

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  31. A dual-reduction strategy for Eu3 + via air-atmosphere calcination: Achieving efficient white-light emission and enhanced thermal stability in Ba3P4O13: Eu2+ phosphors

    Journal of Alloys and Compounds · 2025-11-24

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  32. Constructing Framework Defects via B3+/B3+-P5+ Substitution for Si4+ to Regulate Mn2+ Site Occupancy Luminescence

    SSRN Electronic Journal · 2026-01-01

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  33. Molten salt synthesis of Eu 2+ -doped Sr 5 (PO 4 ) 3 Cl in air atmosphere: europium self-reduction and optical properties

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  34. Preparation of Ba[B 8 O 11 (OH) 4 ]:Eu 2+ High Efficiency UVA Phosphor by Low-temperature Self-reduction Method

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  35. Suppressing concentration quenching in Eu3+/Tb3+-doped phosphates via site-self-limiting crystal structures

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  36. Photochromism and dynamic photoluminescence in CaAl12O19:Eu, Ce phosphor for dual-mode anti-counterfeiting and encryption applications

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  37. Multi-site regulation and luminescence enhancement of narrow-band green-emitting Sr2Li(Al,Ga)(O,N)4: Eu2+ phosphors

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  38. Defect-Engineered NaTb(MoO 4 ) 2 : Linking Structural Distortion to Enhanced Green Emission and Formaldehyde Sensing

    ACS Applied Optical Materials · 2026-07-04

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  39. Enhanced Photoluminescence Quantum Efficiency and Thermal Stability of Cyan‐Emitting Li 2 CaSiO 4 :Eu 2+ Phosphor via a Heterovalent Substitution Strategy

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