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RESEARCH ARTICLE · Inorganic Chemistry · 2021

A Geometrically Frustrated Family of MIIMIIIF5(H2O)2 Mixed–Metal Fluorides with Complex Magnetic Interactions

Navindra Keerthisinghe, Anna A. Berseneva, Vladislav V. Klepov, Gregory W. Morrison, Hans‐Conrad zur Loye

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A Geometrically Frustrated Family of MIIMIIIF5(H2O)2 Mixed–Metal Fluorides with Complex Magnetic InteractionsOriginalComparative Study on Crystal Structures and Synthetic Techniques of Ternary Hafnium/Zirconium Fluorides7Crystal Growth and Magnetism of Transition Metal Pyrochlore Fluorides7Investigation of Charge-Ordered Barium Iron Fluorides with One-Dimensional Structural Diversity and Complex Magnetic Interactions6Intimately mixed copper, cobalt, and iron fluorides resulting from the insertion of fluorine into a LDH template3Polymorphisms in M2+AlF5(H2O)7 (M2+ = Fe2+, Co2+, or Ni2+): Syntheses, Crystal Structures, and Characterization of New Mixed Metal Fluoride Hydrates0Crystal Growth and Characterization of the Rare Earth Fluoride Carbonates NaLnCO3F2 (Ln = Eu–Lu)5Sensitivity of Mild Hydrothermal Synthesis to the Reaction Conditions: Targeting Mixed-Metal Hexagonal Tungsten Bronze Fluorides AxM2+xM3+(1–x)F3 to Investigate Their Magnetic Behavior3Variable one-dimensional Manganese(III) chains with bridging fluoride: Synthesis, structures, and magnetic properties1Ni/Fe Fluorides (Hydroxide) Nanocomposite as Efficient OER Catalyst3New mixed 3d metal-based oxyfluorinated materials as anodic catalysts for water splitting : from elaboration to mechanistic study0From Magnetic Chains to Sheets: The Impact of Hydrofluoric Acid Quantities in Mild Hydrothermal Synthesis on Mixed-Metal Fluoride Formation2Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy24Crystal Growth of Ternary NaRESe 2 (RE = Sm, Gd–Lu) Using the Boron Chalcogen Mixture (BCM) Method: Magnetism in Triangular Lattices and Optical Properties4Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 200

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  1. Comparative Study on Crystal Structures and Synthetic Techniques of Ternary Hafnium/Zirconium Fluorides

    Inorganic Chemistry · 2023

    Navindra Keerthisinghe, Gyanendra B. Ayer, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  2. Crystal Growth and Magnetism of Transition Metal Pyrochlore Fluorides

    Inorganic Chemistry · 2023

    Lakshani W. Masachchi, Navindra Keerthisinghe, Gregory W. Morrison, Anna A. Berseneva, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  3. Investigation of Charge-Ordered Barium Iron Fluorides with One-Dimensional Structural Diversity and Complex Magnetic Interactions

    Inorganic Chemistry · 2023

    Qingqing Huang, Dan Chen, Feifan Li, Bruno J. C. Vieira, Joao Carlos Waerenborgh, Xiedong Cheng, Laura C. J. Pereira, Yaping Li, Yanling Jin, Wenxuan Zhu, Minfeng Lü

    Read original paper ↗ ·

  4. Intimately mixed copper, cobalt, and iron fluorides resulting from the insertion of fluorine into a LDH template

    Dalton Transactions · 2024

    Abderraouf Rouag, Régis Porhiel, Kévin Lemoine, Fabrice Leroux, Jean−Marc Grenèche, Diane Delbègue, Cristina Iojoiu, Katia Guérin

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  5. Polymorphisms in M2+AlF5(H2O)7 (M2+ = Fe2+, Co2+, or Ni2+): Syntheses, Crystal Structures, and Characterization of New Mixed Metal Fluoride Hydrates

    Crystals · 2024

    Jun Min Seo, Hongil Jo, Myung Ho Choi, Kang Min Ok, Hong Young Chang, Sun Woo Kim

    Read original paper ↗ ·

  6. Crystal Growth and Characterization of the Rare Earth Fluoride Carbonates NaLnCO3F2 (Ln = Eu–Lu)

    Crystal Growth & Design · 2024

    Navindra Keerthisinghe, Gregory W. Morrison, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  7. Sensitivity of Mild Hydrothermal Synthesis to the Reaction Conditions: Targeting Mixed-Metal Hexagonal Tungsten Bronze Fluorides AxM2+xM3+(1–x)F3 to Investigate Their Magnetic Behavior

    Inorganic Chemistry · 2024

    Lakshani W. Masachchi, Navindra Keerthisinghe, Anna A. Berseneva, Gregory W. Morrison, Mark D. Smith, Logan S. Breton, Juliano Schorne Pinto, Mina Aziziha, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  8. Variable one-dimensional Manganese(III) chains with bridging fluoride: Synthesis, structures, and magnetic properties

    Journal of Solid State Chemistry · 2024

    Rui Cui, Xiedong Cheng, Feifan Li, Qingqing Huang, Yaping Li, Minfeng Lü

    Read original paper ↗ ·

  9. Ni/Fe Fluorides (Hydroxide) Nanocomposite as Efficient OER Catalyst

    ChemPhysChem · 2024

    Yanli Zhang, Liangliang Dong, Qiang Zhang, Li Wang, Xiangming He

    Read original paper ↗ ·

  10. New mixed 3d metal-based oxyfluorinated materials as anodic catalysts for water splitting : from elaboration to mechanistic study

    Venue not supplied by source · 2024

    Alexandre Terry

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  11. From Magnetic Chains to Sheets: The Impact of Hydrofluoric Acid Quantities in Mild Hydrothermal Synthesis on Mixed-Metal Fluoride Formation

    Chemistry of Materials · 2025

    Navindra Keerthisinghe, Gregory W. Morrison, Logan S. Breton, Mark D. Smith, Qiang Zhang, Melanie Kirkham, Vladislav V. Klepov, Hans‐Conrad zur Loye

    Read original paper ↗ ·

  12. Fluorine as a Key Element in Solid-State Chemistry of Mixed Anions 3d Transition Metal-Based Materials for Electronic Properties and Energy

    Chemical Reviews · 2025

    Helies Hyrondelle, Alexandre Terry, Jérôme Lhoste, Sophie Tencé, Kévin Lemoine, Jacob Olchowka, Damien Dambournet, Cédric Tassel, Jacinthe Gamon, Alain Demourgues

    Read original paper ↗ ·

  13. Crystal Growth of Ternary NaRESe 2 (RE = Sm, Gd–Lu) Using the Boron Chalcogen Mixture (BCM) Method: Magnetism in Triangular Lattices and Optical Properties

    Crystal Growth & Design · 2026

    Habiba Binte Kashem, Gregory W. Morrison, Abdullah Al Muhit, Buddhima K. P. Maldeni Kankanamalage, Natalia B. Shustova, Hans‐Conrad zur Loye

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  14. Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 20

    Inorganic Chemistry · 2026

    Timothy E. Whitesell, Hope Eden Catalano, Mark D. Smith, Hans‐Conrad zur Loye

    Read original paper ↗ ·
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