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RESEARCH PAPER · Inorganic Chemistry · 2026

Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 20

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