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RESEARCH PAPER · ACS Applied Energy Materials · 2021

Experimental Visualization of the Interstitialcy Diffusion of Anions in the LaOF-Based Oxyfluoride La0.9Sr0.1O0.45F2

Keisuke Hibino, M. Tanaka, Satoshi Kozakai, Kotaro Fujii, Tatsumi Ishihara, James Hester, Masatomo Yashima

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Experimental Visualization of the Interstitialcy Diffusion of Anions in the LaOF-Based Oxyfluoride La0.9Sr0.1O0.45F2OriginalAIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses11Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.526Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 2037High Oxide‐Ion Conductivity through the Interstitial Oxygen Site in Sillén Oxychlorides34Fluorosulfide La 2+ x Sr 1– x F 4+ x S 2 with a Triple-Fluorite Layer Enabling Interstitial Fluoride-Ion Conduction20Electropositive Metal Doping into Lanthanum Hydride for H− Conducting Solid Electrolyte Use at Room Temperature22Phase transition process and mechanism of LaOF in air: From experiment to theory9Recent progress, challenges and prospects of electrolytes for fluoride-ion batteries59High Conductivity and Diffusion Mechanism of Oxide Ions in Triple Fluorite-Like Layers of Oxyhalides20A novel thermal battery based on fluoride ion conduction5The First Members of the Monoclinic Lanthanoid(III) Fluoride Oxoarsenate(III) Series Ln2F2[As2O5] (Ln=La – Nd and Sm)2Phase transition process and mechanism of LaOF in N2: From theory to experiment0Unlocking F-O synergistic effects in TiOF2-based nano-thermites: Enhanced combustion performance and reaction kinetics1LaF 3 & LaOF Nanophases Enhance High‐Voltage Electrochemical Performance of LiCoO 23Unveiling anionic migration mechanisms governed by mixed-anion chemistry in melilite oxyfluorides2Enhancing nano-thermite performance: Iron oxyfluoride (FeOF) as a novel oxidizer1Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)0High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Sm-modified Bi3YO6 electrolyte for low-temperature solid oxide fuel cells: Structure, transport behavior and microscopic mechanisms0

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  1. AIn 4 S 6 Cl (A = Rb and Cs) and Pb 5 Sn 3 Q 10 Cl 2 (Q = S and Se): quaternary chalcohalides with mixed anionic coordination exhibit photocurrent responses

    Dalton Transactions · 2022-01-01

    Lin‐Tao Jiang, Mingze Li, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  2. Oxide-Ion Occupational Disorder, Diffusion Path, and Conductivity in Hexagonal Perovskite Derivatives Ba3WNbO8.5 and Ba3MoNbO8.5

    The Journal of Physical Chemistry C · 2022-01-27

    Yuta Yasui, Takafumi Tsujiguchi, Yuichi Sakuda, James Hester, Masatomo Yashima

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  3. Simultaneous Reduction of Proton Conductivity and Enhancement of Oxide-Ion Conductivity by Aliovalent Doping in Ba 7 Nb 4 MoO 20

    Inorganic Chemistry · 2022-05-03

    Yuki Suzuki, Taito Murakami, Kotaro Fujii, James Hester, Yuta Yasui, Masatomo Yashima

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  4. High Oxide‐Ion Conductivity through the Interstitial Oxygen Site in Sillén Oxychlorides

    Advanced Functional Materials · 2023-04-20

    Hiroshi Yaguchi, Daisuke Morikawa, Takashi Saito, Kenji Tsuda, Masatomo Yashima

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  5. Fluorosulfide La 2+ x Sr 1– x F 4+ x S 2 with a Triple-Fluorite Layer Enabling Interstitial Fluoride-Ion Conduction

    Chemistry of Materials · 2023-06-01

    Shintaro Tachibana, Chengchao Zhong, Kazuto Ide, Hisatsugu Yamasaki, Takeshi Tojigamori, Hidenori Miki, Takashi Kei SAITO, Takashi Kamiyama, Keiji Shimoda, Yuki Orikasa

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  6. Electropositive Metal Doping into Lanthanum Hydride for H− Conducting Solid Electrolyte Use at Room Temperature

    Advanced Energy Materials · 2023-09-24

    Yoshiki Izumi, Fumitaka Takeiri, Kei Okamoto, Takashi Kei SAITO, Takashi Kamiyama, Akihide Kuwabara, Genki Kobayashi

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  7. Phase transition process and mechanism of LaOF in air: From experiment to theory

    Ceramics International · 2023-10-09

    Xianmin Tan, Zheng Zhao, Ning Wang, Zhenyu Zhang, Xingzi Wang, Zongyu Feng, Yuanyuan Zheng, Juanyu Yang, Xiaowei Huang

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  8. Recent progress, challenges and prospects of electrolytes for fluoride-ion batteries

    Energy Reviews · 2024-03-26

    Ming Zhang, X.W. Cao, Yaowei Hao, Haodong Wang, Jian Pu, Bo Chi, Zhongrong Shen

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  9. High Conductivity and Diffusion Mechanism of Oxide Ions in Triple Fluorite-Like Layers of Oxyhalides

    Journal of the American Chemical Society · 2024-04-09

    Nachi Ueno, Hiroshi Yaguchi, Kotaro Fujii, Masatomo Yashima

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  10. A novel thermal battery based on fluoride ion conduction

    Electrochimica Acta · 2024-10-20

    Zhenyu Xiao, Jiajun Zhu, Wulin Yang, Lingping Zhou, Licai Fu

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  11. The First Members of the Monoclinic Lanthanoid(III) Fluoride Oxoarsenate(III) Series Ln2F2[As2O5] (Ln=La – Nd and Sm)

    European Journal of Inorganic Chemistry · 2025-03-11

    Ralf J. C. Locke, Frank C. Zimmer, Thomas Schleid

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  12. Phase transition process and mechanism of LaOF in N2: From theory to experiment

    Ceramics International · 2025-04-14

    Xianmin Tan, Juanyu Yang, Zheng Zhao, Ning Wang, Zhenyu Zhang, Xingzi Wang, Yuanyuan Zheng, Xiaowei Huang

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  13. Unlocking F-O synergistic effects in TiOF2-based nano-thermites: Enhanced combustion performance and reaction kinetics

    Materials Science and Engineering B · 2025-07-30

    Wenyu Li, Yajun Wang, Qiang Gan, Zhengliang Deng, Junhan Gao

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  14. LaF 3 & LaOF Nanophases Enhance High‐Voltage Electrochemical Performance of LiCoO 2

    Chinese Journal of Chemistry · 2025-09-22

    Biqi Chen, Peng Sun, Laiba Abrar, Jinli Zhang, Jiangjiexing Wu, Wei Li

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  15. Unveiling anionic migration mechanisms governed by mixed-anion chemistry in melilite oxyfluorides

    Inorganic Chemistry Frontiers · 2025-11-05

    Lijia Zhou, Li Yang, Aydar I. Rakhmatullin, Shipeng Geng, Xiaoyan Yang, Mathieu M. B. Allix, Jiazheng Hao, Lunhua He, Mingxue Tang, Zewei Quan, Xiaojun Kuang

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  16. Enhancing nano-thermite performance: Iron oxyfluoride (FeOF) as a novel oxidizer

    Materials Today Communications · 2025-11-17

    Wenyu Li, Yajun Wang, Ruihua Liu, Qiang Gan, Zhengliang Deng

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  17. Oxide-Ion Occupational Disorder, Conductivity, and Diffusion Pathways in Ba3MNbO8.5 (M = W, Mo)

    Springer theses · 2026-01-01

    Yuta Yasui

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  18. High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide

    Advanced Functional Materials · 2026-02-24

    Shuhang Liu, Yanru Dong, Wencui Li, Wenrui Zhang, An‐Hui Lu

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  19. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

    Angewandte Chemie · 2026-07-23

    Daichi Kato, Yosuke Matsuzaki, Kohei Miyazaki, Kousuke Noi, Miwa Murakami, K. Takegoshi, Akihide Kuwabara, Shunsuke Kobayashi, Kei Nakayama, Masashi Taniguchi, Hiroki Ubukata, Yang Zhang, Koji Fujita, Yusuke Nambu, Takashi Saito, Takeshi Abe, Hiroshi Kageyama

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  20. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

    Angewandte Chemie International Edition · 2026-07-24

    Daichi Kato, Yosuke Matsuzaki, Kohei Miyazaki, Kousuke Noi, Miwa Murakami, K. Takegoshi, Akihide Kuwabara, Shunsuke Kobayashi, Kei Nakayama, Masashi Taniguchi, Hiroki Ubukata, Yang Zhang, Koji Fujita, Yusuke Nambu, Takashi Saito, Takeshi Abe, Hiroshi Kageyama

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  21. Sm-modified Bi3YO6 electrolyte for low-temperature solid oxide fuel cells: Structure, transport behavior and microscopic mechanisms

    Journal of Alloys and Compounds · 2026-09-01

    Sana Ullah Asif, Deyu Zhang, Shihong Zhang, Muhammad Adnan Qaiser, Asif Ali Haider, Qingqing Wen, Dr Rizwan Raza, Muhammad Wasif Ghauri, Nusrat Shaheen, Shuangbao Wang

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