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RESEARCH PAPER · Energy Reviews · 2024

Recent progress, challenges and prospects of electrolytes for fluoride-ion batteries

Ming Zhang, X.W. Cao, Yaowei Hao, Haodong Wang, Jian Pu, Bo Chi, Zhongrong Shen

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Recent progress, challenges and prospects of electrolytes for fluoride-ion batteriesOriginalTlSn 2 F 5 , a SnF 2 -based solid electrolyte with high ionic conductivity and electrochemical stability for all-solid-state fluoride ion batteries11Oxygen-Doped FeF 3 Nanosheets Prepared by the Liquid-Phase Exfoliation Method for Lithium Storage7Thermal Conductivity of Ca1–x–ySrxNdyF2+y Solid Solution Single Crystals0Alkaline Earth Bismuth Fluorides as Fluoride-Ion Battery Electrolytes2Highly Reversible Conversion‐Type CoSn 2 Cathode for Fluoride‐Ion Batteries5Neural Network Potential Molecular Dynamics Simulations of (La,Ce,Pr,Nd)0.95(Mg,Zn,Pb,Cd,Ca,Sr,Ba)0.05F2.955Optimization of the Composition of Solid Electrolytes in MF2−LaF3−NdF3 and MF2−CeF3−PrF3 (M = Ca, Sr, Ba) Systems by Room-Temperature Ionic Conductivity2Unlocking the potential of sepiolite: Designing high-performance energy storage materials12Manganese electrode for all-solid-state fluoride batteries2Design and synthesis of a weakly solvated electrolyte for high-performance fluoride-ion batteries5Design and synthesis of asymmetric anhydrous quaternary ammonium fluoride electrolytes for fluoride ion batteries5Graphite fluoride interface blocking for higher capacity fluoride ion thermal batteries3Development of all-solid-state fluoride ion battery with enhanced electrochemical stability2Low-Temperature Synthesis and Electrical Conductivity of (La1–хNdх)0.95Sr0.05F2.95 Nanofluorides with a Tysonite Structure1Tailored 3‐Alkoxy‐ N , N , N ,2,2‐Pentamethylpropan‐1‐Ammonium Bis (trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries5Tailored 3‐Alkoxy‐N,N,N,2,2‐Pentamethylpropan‐1‐Ammonium Bis(trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries1Ionic Conductivity of the Three Solid Phases in the CaF2–HoF3 System: A Comparative Analysis1Enhancing electrochemical performance of BaCe0.3Fe0.7O3-δ cathodes via fluorine doping for proton-conducting solid oxide fuel cells6On the Ionic Conductivity of Tysonite Nanofluorides R0.85Pb0.15F2.85 (R = La, Pr) Obtained by Mechanosynthesis1Superionic Glasses: Potential and Challenges in Solid‐State Batteries and Fuel Cells2Effect of pressure on the ionic conduction and relaxation properties of Pb0.7Sn0.3F2 fluoride ion conductors0Development of tin oxide-embedded phosphovanadate glass-ceramics as cathode and anode materials for high-performance secondary batteries2The extraction of hopping frequencies of mobile fluorine ions in the superionic conductor Ba0.5La0.5F2.5 from electrical modulus spectroscopy data1Exploring the structural and conductivity behaviours of mechanochemically and hydrothermally synthesized Ce3+-doped BaSnF4 solid electrolytes for all-solid-state fluoride-ion batteries1Fast Solid-State Defluorination/Fluorination of FeFx (x = 3–0) as Fluoride-Ion Battery Cathode1Highly conductive solid electrolytes in the PbF2-CaF2-KF system: mechanochemical synthesis, electrical properties, microstructure and stability3Optimizing the dopant concentration of solid electrolyte for room temperature fluoride ion battery applications0Ion‐Pump‐Regulated Highly Conductive Polymer Electrolyte to Enable the First All‐Solid‐State Rechargeable Fluoride‐Ion Pouch Cells8High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper2Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities5Recent advancements and future challenges of perovskite-based supercapacitors17Defect Structure and Anion Conduction in Lanthanum Oxychloride Solid Solutions Revealed by X-ray Excited Optical Luminescence and Auger Emission2Conjugated polymer-based nanocomposites for rechargeable batteries0Role of optical phonon in fluoride-ion conductivity of LaF30Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction0Synthesis of Concentrated Phases Pb1–xRxF2+x (R = La, Pr, Nd) with Fluorite Structure from Aqueous Solutions and Their Ionic Conductivity0Influence of Na+/Li+ Co-doping on the structure, thermal behavior, and ionic conductivity of fluorapatite-based materials1In-depth analysis of next-generation hybrid PV–SOFC power system for nearly-zero energy building using an advanced thermodynamic and multi-objective optimization approach2Ionic Conductivity of CeF3 Crystals Produced by Gradient Melt Freezing under Temperature Exposure in Vacuum0An aqueous fluoride-ion battery regulated by sulfolane induced hydrogen bonding0Site-Selective Modification of Lanthanum Oxychloride to Modulate Halide-Ion Conduction0Transport–interphase–conversion coupling in room-temperature fluoride-ion batteries: a resistance-hierarchy framework0Single-Crystal Growth and Fluorine-Ionic Conductivity of Tysonite-type Ternary (R, R')0.95Sr0.05F2.95 (R, R' = La−Nd) Solid Electrolytes0Fluoride Electrolyte Discovery via Reactivity Guided Genetic Algorithms0Aerogel‐Derived Mesoporous MgO for Fluoride Removal: Mechanisms and In Situ Groundwater Remediation Potential0Melting Entropy as a Criterion for Searching for Fluoride Compounds with High Anionic Conductivity0Transitioning From Primary to Rechargeable Li/CF x Batteries: Mechanistic Insights and Design Strategies0Mechanochemical synthesis and physicochemical properties of fluorite- and tysonite-type solid electrolytes in the PbF2-LaF3 system0Fluoride ions as charge carriers in electrochemical energy storage0Propylene Carbonate-Based Liquid Electrolyte with Enhanced Chemical Stability for Fluoride Ion Batteries0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Fluoride‐Ion Batteries: Unraveling the Fundamental Science for Next‐Generation Energy Storage0Electrochemical and structural properties of Ce0.95Sr0.05F2.95 and La0.95Sr0.05F2.95 fluoride-ion-conducting materials0Plasma‐Induced Surface Fluorination of Metal Foils as Reliable Reference Electrodes for Fluoride‐Ion Batteries0Analysis of Creativity of Prospective Chemistry Teacher Students in Volta Cell Learning Using Project-Based Learning0Rationalizing the downward- and upward-convex crossover in the Arrhenius behavior of ionic conductivity in PbSnF4-based solid solutions0Generative Inverse Design of Solid-State Fluoride-Ion Electrolyte Candidates in Data-Sparse Chemical Space0

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  1. TlSn 2 F 5 , a SnF 2 -based solid electrolyte with high ionic conductivity and electrochemical stability for all-solid-state fluoride ion batteries

    Dalton Transactions · 2024-01-01

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  2. Oxygen-Doped FeF 3 Nanosheets Prepared by the Liquid-Phase Exfoliation Method for Lithium Storage

    Energy & Fuels · 2024-06-17

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  3. Thermal Conductivity of Ca1–x–ySrxNdyF2+y Solid Solution Single Crystals

    Inorganic Materials · 2024-09-01

    Pavel A. Popov, A.V. Shchelokov, A. I. Zentsova, A. A. Alexandrov, Elena V. Chernova, Pavel Pavlovich Fedorov

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  4. Alkaline Earth Bismuth Fluorides as Fluoride-Ion Battery Electrolytes

    ACS Omega · 2024-09-02

    Spencer Doyle, Edvin Tewolde Berhane, Peichao Zou, Ari B. Turkiewicz, Yang Zhang, Charles M. Brooks, Ismail El Baggari, Huolin L. Xin, Julia A. Mundy

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  5. Highly Reversible Conversion‐Type CoSn 2 Cathode for Fluoride‐Ion Batteries

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    Shun Sasano, Ryo Ishikawa, Kazuaki Kawahara, Naoya Shibata, Yuichi Ikuhara

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  6. Neural Network Potential Molecular Dynamics Simulations of (La,Ce,Pr,Nd)0.95(Mg,Zn,Pb,Cd,Ca,Sr,Ba)0.05F2.95

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  7. Optimization of the Composition of Solid Electrolytes in MF2−LaF3−NdF3 and MF2−CeF3−PrF3 (M = Ca, Sr, Ba) Systems by Room-Temperature Ionic Conductivity

    Crystallography Reports · 2024-12-01

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  8. Unlocking the potential of sepiolite: Designing high-performance energy storage materials

    Energy Reviews · 2024-12-19

    Yanhuai Ding, Yizhi Jiang, Dongzhao Jin, Yunhong Jiang, Ana C. S. Alcântara

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  9. Manganese electrode for all-solid-state fluoride batteries

    Chemical Communications · 2024-12-24

    Atsushi Inoishi, Naoko Setoguchi, Megumi Motoyama, Shigeto Okada, Hikarí Sakaebe

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  10. Design and synthesis of a weakly solvated electrolyte for high-performance fluoride-ion batteries

    Journal of Materials Chemistry A · 2025-01-01

    jia xiang, Wei Hua Zou, Ying Lei, Hua‐Jun Fan, Rongwen Lu, Shufen Zhang

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  11. Design and synthesis of asymmetric anhydrous quaternary ammonium fluoride electrolytes for fluoride ion batteries

    Sustainable Energy & Fuels · 2025-01-01

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  12. Graphite fluoride interface blocking for higher capacity fluoride ion thermal batteries

    Journal of Materials Chemistry A · 2025-01-01

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  13. Development of all-solid-state fluoride ion battery with enhanced electrochemical stability

    Journal of Alloys and Compounds · 2025-02-01

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  14. Low-Temperature Synthesis and Electrical Conductivity of (La1–хNdх)0.95Sr0.05F2.95 Nanofluorides with a Tysonite Structure

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  15. Tailored 3‐Alkoxy‐ N , N , N ,2,2‐Pentamethylpropan‐1‐Ammonium Bis (trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries

    Angewandte Chemie International Edition · 2025-04-07

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  16. Tailored 3‐Alkoxy‐N,N,N,2,2‐Pentamethylpropan‐1‐Ammonium Bis(trifluoromethylsulfonyl)Imide Ionic Liquids for Room‐Temperature Fluoride‐Ion Batteries

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  17. Ionic Conductivity of the Three Solid Phases in the CaF2–HoF3 System: A Comparative Analysis

    Russian Journal of Inorganic Chemistry · 2025-05-01

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  18. Enhancing electrochemical performance of BaCe0.3Fe0.7O3-δ cathodes via fluorine doping for proton-conducting solid oxide fuel cells

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  19. On the Ionic Conductivity of Tysonite Nanofluorides R0.85Pb0.15F2.85 (R = La, Pr) Obtained by Mechanosynthesis

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  20. Superionic Glasses: Potential and Challenges in Solid‐State Batteries and Fuel Cells

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  21. Effect of pressure on the ionic conduction and relaxation properties of Pb0.7Sn0.3F2 fluoride ion conductors

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  22. Development of tin oxide-embedded phosphovanadate glass-ceramics as cathode and anode materials for high-performance secondary batteries

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  23. The extraction of hopping frequencies of mobile fluorine ions in the superionic conductor Ba0.5La0.5F2.5 from electrical modulus spectroscopy data

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  24. Exploring the structural and conductivity behaviours of mechanochemically and hydrothermally synthesized Ce3+-doped BaSnF4 solid electrolytes for all-solid-state fluoride-ion batteries

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  25. Fast Solid-State Defluorination/Fluorination of FeFx (x = 3–0) as Fluoride-Ion Battery Cathode

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  26. Highly conductive solid electrolytes in the PbF2-CaF2-KF system: mechanochemical synthesis, electrical properties, microstructure and stability

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  27. Optimizing the dopant concentration of solid electrolyte for room temperature fluoride ion battery applications

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  28. Ion‐Pump‐Regulated Highly Conductive Polymer Electrolyte to Enable the First All‐Solid‐State Rechargeable Fluoride‐Ion Pouch Cells

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  29. High-Capacity Intercalation-Based Anodes for Solid-State Fluoride-Ion Batteries Enabled by the Substitution of Conductive Carbon by Metallic Copper

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  30. Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities

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  31. Recent advancements and future challenges of perovskite-based supercapacitors

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  32. Defect Structure and Anion Conduction in Lanthanum Oxychloride Solid Solutions Revealed by X-ray Excited Optical Luminescence and Auger Emission

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  33. Conjugated polymer-based nanocomposites for rechargeable batteries

    Elsevier eBooks · 2025-12-05

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  34. Role of optical phonon in fluoride-ion conductivity of LaF3

    The Journal of Chemical Physics · 2025-12-22

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  35. Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction

    Journal of Materials Chemistry A · 2026-01-01

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  36. Synthesis of Concentrated Phases Pb1–xRxF2+x (R = La, Pr, Nd) with Fluorite Structure from Aqueous Solutions and Their Ionic Conductivity

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  37. Influence of Na+/Li+ Co-doping on the structure, thermal behavior, and ionic conductivity of fluorapatite-based materials

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  38. In-depth analysis of next-generation hybrid PV–SOFC power system for nearly-zero energy building using an advanced thermodynamic and multi-objective optimization approach

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  39. Ionic Conductivity of CeF3 Crystals Produced by Gradient Melt Freezing under Temperature Exposure in Vacuum

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  40. An aqueous fluoride-ion battery regulated by sulfolane induced hydrogen bonding

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  41. Site-Selective Modification of Lanthanum Oxychloride to Modulate Halide-Ion Conduction

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  42. Transport–interphase–conversion coupling in room-temperature fluoride-ion batteries: a resistance-hierarchy framework

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  43. Single-Crystal Growth and Fluorine-Ionic Conductivity of Tysonite-type Ternary (R, R')0.95Sr0.05F2.95 (R, R' = La−Nd) Solid Electrolytes

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  44. Fluoride Electrolyte Discovery via Reactivity Guided Genetic Algorithms

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  45. Aerogel‐Derived Mesoporous MgO for Fluoride Removal: Mechanisms and In Situ Groundwater Remediation Potential

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  46. Melting Entropy as a Criterion for Searching for Fluoride Compounds with High Anionic Conductivity

    Russian Journal of Inorganic Chemistry · 2026-07-01

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  47. Transitioning From Primary to Rechargeable Li/CF x Batteries: Mechanistic Insights and Design Strategies

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  48. Mechanochemical synthesis and physicochemical properties of fluorite- and tysonite-type solid electrolytes in the PbF2-LaF3 system

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  49. Fluoride ions as charge carriers in electrochemical energy storage

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  50. Propylene Carbonate-Based Liquid Electrolyte with Enhanced Chemical Stability for Fluoride Ion Batteries

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