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RESEARCH PAPER · Chemistry of Materials · 2023

Fluorosulfide La 2+ x Sr 1– x F 4+ x S 2 with a Triple-Fluorite Layer Enabling Interstitial Fluoride-Ion Conduction

Shintaro Tachibana, Chengchao Zhong, Kazuto Ide, Hisatsugu Yamasaki, Takeshi Tojigamori, Hidenori Miki, Takashi Kei SAITO, Takashi Kamiyama, Keiji Shimoda, Yuki Orikasa

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Fluorosulfide La 2+ x Sr 1– x F 4+ x S 2 with a Triple-Fluorite Layer Enabling Interstitial Fluoride-Ion ConductionOriginalFluorosulfide La 2.7 Ba 6.3 F 8.7 S 6 with a double-layer honeycomb structure enabling fluoride-ion conduction3Linking the Molecular Shape with the High Ionic Conduction in MX2-Type Compounds1Versatile metal fluorides in ion battery application18Recent progress, challenges and prospects of electrolytes for fluoride-ion batteries59High Conductivity and Diffusion Mechanism of Oxide Ions in Triple Fluorite-Like Layers of Oxyhalides20Withdrawn: Alternative Oxide-Based Materials for Electrochemical and Catalytic Applications: A Review2Alkaline Earth Bismuth Fluorides as Fluoride-Ion Battery Electrolytes2Advances in alternative metal oxide materials of various structures for electrochemical and catalytic applications9Fluoride-ion conduction in Ba 4 M 3 F 17 (M = Bi 3+ , Y 3+ ) with conductive M 6 F 13 cage units2Highly efficient atomic-scale design of CaF 2 for ultrafast fluoride-ion conduction5Fluoride-ion conductivity of scheelite-type LiYb1-MF4± (M = Mg, Ca, Sr, Hf)0Enhancing fluoride-ion conduction via doping-induced anionic ordering in an n = 1 Ba-based Ruddlesden-Popper oxyfluoride structure0Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities5Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction0Structural chemistry and applications of heteroanionic rare-earth metal chalcogenide halides1The critical role of rare-earth elements in solid-state electrolytes for all-solid-state fluoride-ion batteries2High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide0Fluoride ions as charge carriers in electrochemical energy storage0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0

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  1. Fluorosulfide La 2.7 Ba 6.3 F 8.7 S 6 with a double-layer honeycomb structure enabling fluoride-ion conduction

    Journal of Materials Chemistry A · 2024-01-01

    Shintaro Tachibana, Chengchao Zhong, Takeshi Tojigamori, Hidenori Miki, Toshiyuki Matsunaga, Yuki Orikasa

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  2. Linking the Molecular Shape with the High Ionic Conduction in MX2-Type Compounds

    Springer proceedings in physics · 2024-01-01

    Masaru Aniya

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  3. Versatile metal fluorides in ion battery application

    Journal of Materials Chemistry A · 2024-01-01

    Shanshan Xiao, Pengtao Sun, Yingying Xie, Xianggang Zhou, Yingqi Li, Liyan Wang

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  4. Recent progress, challenges and prospects of electrolytes for fluoride-ion batteries

    Energy Reviews · 2024-03-26

    Ming Zhang, X.W. Cao, Yaowei Hao, Haodong Wang, Jian Pu, Bo Chi, Zhongrong Shen

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  5. High Conductivity and Diffusion Mechanism of Oxide Ions in Triple Fluorite-Like Layers of Oxyhalides

    Journal of the American Chemical Society · 2024-04-09

    Nachi Ueno, Hiroshi Yaguchi, Kotaro Fujii, Masatomo Yashima

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  6. Withdrawn: Alternative Oxide-Based Materials for Electrochemical and Catalytic Applications: A Review

    Preprints.org · 2024-08-20

    Vladіslav Sadykov, Nikita Eremeev, A. V. Shlyakhtina, Elena Yu. Pikalova

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  7. Alkaline Earth Bismuth Fluorides as Fluoride-Ion Battery Electrolytes

    ACS Omega · 2024-09-02

    Spencer Doyle, Edvin Tewolde Berhane, Peichao Zou, Ari B. Turkiewicz, Yang Zhang, Charles M. Brooks, Ismail El Baggari, Huolin L. Xin, Julia A. Mundy

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  8. Advances in alternative metal oxide materials of various structures for electrochemical and catalytic applications

    International Journal of Hydrogen Energy · 2024-11-11

    Vladіslav Sadykov, Nikita Eremeev, A. V. Shlyakhtina, Elena Yu. Pikalova

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  9. Fluoride-ion conduction in Ba 4 M 3 F 17 (M = Bi 3+ , Y 3+ ) with conductive M 6 F 13 cage units

    Journal of Materials Chemistry A · 2025-01-01

    Chengchao Zhong, Saya Hirakawa, Keiji Shimoda, Ken‐ichi Okazaki, Yuki Orikasa

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  10. Highly efficient atomic-scale design of CaF 2 for ultrafast fluoride-ion conduction

    Journal of Materials Chemistry A · 2025-01-01

    Yurong Liu, Zeyu Zhang, Xinyi Yan, Jinquan Hou, Zhi‐Wei Liu, Wenjie Liu, Xianyou Wang, Yong Pei, Zhenhua Yang

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  11. Fluoride-ion conductivity of scheelite-type LiYb1-MF4± (M = Mg, Ca, Sr, Hf)

    Solid State Ionics · 2025-04-04

    Kota Onuki, Naoki Matsui, Masaaki Hirayama, Masaaki Hirayama, Masaaki Hirayama

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  12. Enhancing fluoride-ion conduction via doping-induced anionic ordering in an n = 1 Ba-based Ruddlesden-Popper oxyfluoride structure

    Solid State Ionics · 2025-04-12

    Chanachai Pattanathummasid, Ryoji Asahi, Alex Kutana, Kazuhiro John Mori, Toshiyuki Matsunaga, Tsuyoshi Takami

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  13. Fluoride-Ion Batteries: A Review of Recent Advances and Future Opportunities

    Electrochemical Energy Reviews · 2025-12-01

    Enhao Liu, Youkang Duan, Yu Li, Cong Peng, Wei Feng

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  14. Engineering sintering-induced secondary phases in La 0.9 Ba 0.1 F 2.9 -based composite electrolytes for fluoride-ion conduction

    Journal of Materials Chemistry A · 2026-01-01

    Enhao Liu, You‐Kang Duan, Cong Peng, Yu Li, Wei Feng

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  15. Structural chemistry and applications of heteroanionic rare-earth metal chalcogenide halides

    Elsevier eBooks · 2026-01-01

    Thimira Kandabadage, Sviatoslav Baranets

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  16. The critical role of rare-earth elements in solid-state electrolytes for all-solid-state fluoride-ion batteries

    Materials Science and Engineering R Reports · 2026-01-24

    Jichang Sun, Ruixiang Wang, Pengyu Meng, Liansheng Li, Jin‐Zhi Guo, Liang Qinghua, Xing‐Long Wu

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  17. High Conductivity and Diffusion Mechanism of Oxide‐Ion in Sillén‐Aurivillius Phase Oxobromide

    Advanced Functional Materials · 2026-02-24

    Shuhang Liu, Yanru Dong, Wencui Li, Wenrui Zhang, An‐Hui Lu

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  18. Fluoride ions as charge carriers in electrochemical energy storage

    Nature Materials · 2026-07-10

    George Agbeworvi, Shruti Hariyani, Jing‐Xiang Cheng, Alice R. Giem, Anindya Pakhira, Victor Alexander Gomez, Sarbajit Banerjee

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  19. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

    Angewandte Chemie · 2026-07-23

    Daichi Kato, Yosuke Matsuzaki, Kohei Miyazaki, Kousuke Noi, Miwa Murakami, K. Takegoshi, Akihide Kuwabara, Shunsuke Kobayashi, Kei Nakayama, Masashi Taniguchi, Hiroki Ubukata, Yang Zhang, Koji Fujita, Yusuke Nambu, Takashi Saito, Takeshi Abe, Hiroshi Kageyama

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  20. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

    Angewandte Chemie International Edition · 2026-07-24

    Daichi Kato, Yosuke Matsuzaki, Kohei Miyazaki, Kousuke Noi, Miwa Murakami, K. Takegoshi, Akihide Kuwabara, Shunsuke Kobayashi, Kei Nakayama, Masashi Taniguchi, Hiroki Ubukata, Yang Zhang, Koji Fujita, Yusuke Nambu, Takashi Saito, Takeshi Abe, Hiroshi Kageyama

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