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RESEARCH PAPER · Chemical Reviews · 2024

Electrocatalysis in Solid Oxide Fuel Cells and Electrolyzers

Inyoung Jang, Juliana S. A. Carneiro, J Crawford, Yoon Jin Cho, Sahanaz Parvin, Diego Alexander Gonzalez‐Casamachin, Jonas Baltrušaitis, Ryan P. Lively, Eranda Nikolla

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Electrocatalysis in Solid Oxide Fuel Cells and ElectrolyzersOriginalA comprehensive review on hydrogen production, storage, and applications473Concurrent surface and bulk modification of ceria-based cathodic catalyst for CO 2 reduction in solid oxide electrolysis cell under strong polarization conditions4Recent Progress in Sr 2 Fe 1.5 Mo 0.5 O 6‐δ ‐Based Multifunctional Materials for Energy Conversion and Storage57Highly active and stable oxygen electrode PrBaCo2O5+δ-Ba2CoWO6 enabled by In Situ formed misfit dislocation interface for reversible solid oxide cell21Co‐Generation of Electricity and Chemicals From Methane Using Direct Internal Reforming Solid Oxide Fuel Cells33Electrosynthesizing high-value fuels from CO2 in solid oxide electrolysis cells: Fundamentals, advances, and perspectives6Recent Progress on the Materials of Oxygen Ion-Conducting Solid Oxide Fuel Cells and Experimental Analysis of Biogas-Assisted Electrolysis over a LSC Anode11Modeling and control of a protonic membrane steam methane reformer7Metal-organic-framework-derived dual-atom catalysts: from synthesis to electrocatalytic applications91Introduction to Green Hydrogen385Synthesis, characterization and CMP property of neat and doped mesoporous ceria as defective active particle abrasives5Toward Advanced Fuel Electrodes for High‐Performance Proton‐Conducting Ceramic Cells26Excellent energy storage performance of (Bi0.4Na0.2K0.2Ba0.2)TiO3-Bi(Zn2/3Nb1/3)O3 high-entropy ceramics under medium electric fields6Incorporating high acidity cations in Co-free BiFeO 3 -based air electrodes for enhancing their electrocatalytic activity and durability in reversible solid oxide cells3Divulging the potential role of wide band gap semiconductors in electro and photo catalytic water splitting for green hydrogen production29Electrochemical impedance spectroscopy measurements of solid oxide cells: beyond open circuit voltage conditions19Machine-learning-assisted prediction of highly active and stable PrBaCo 2 O 5+ δ -based oxygen electrodes for solid oxide cells3Recent advances in perovskite air electrode materials for protonic solid oxide electrochemical cells51Status and outlook of solid electrolyte membrane reactors for energy, chemical, and environmental applications52Temperature-induced relaxation for determining oxygen transport kinetics of nonstoichiometric oxides: fundamentals and experiments1Tuning electrocatalytic activity via Mn doping in Ca 2 Fe 2 O 5 for OER and ORR applications0Local lattice distortion regulation in high entropy engineering to enhance the triple conductivity of layered Ruddlesden-Popper perovskite cathode in H+-SOFCs42Novel High‐Entropy Air Electrodes Enhancing Electrochemical Performances of Reversible Protonic Ceramic Cells23Progress and challenges in the research on cathodes for Co-electrolysis of CO2/H2O in solid oxide electrolysis cells1Efficient ammonia synthesis in perovskite cathode-supported protonic ceramic electrochemical cell with dendritic porous structure9Industrial Perspective of Electrified Ethylene Production via Membrane-Assisted Nonoxidative Dehydrogenation of Ethane10A novel high-entropy perovskite electrolyte of BaSn0.15Ce0.45Zr0.15Y0.1Yb0.1Gd 0.05O3-δ with enhanced proton conduction performance11Internal biogas reforming in solid oxide and proton conducting fuel cells: progress, challenges and perspectives6In Situ Exsolved Mangosteen‐Type Nanoalloy Clusters and Engineered Heterogeneous Interfaces for High‐Performance Fuel‐Flexible Solid Oxide Cells7Nanostructured fuel electrodes for low-temperature proton- and oxygen-ion-conducting solid oxide cells28Mechanistically Interpretable AI for Accelerated Energy Materials Design0How AI guided the development of green hydrogen production: in the case of solid oxide electrolysis cell?9Co-expression of multi-genes for polynary perovskite electrocatalysts for reversible solid oxide cells36Critical insights into the steam electrolysis electrode in protonic ceramic cells for hydrogen production54Efficient power generation in a solid oxide fuel cell using N 2 O as the oxidant7Direct ammonia protonic ceramic fuel cells through heterogeneous interface engineering8In‐Situ Exsolved Metal Nanoparticles for Solid Oxide Fuel Cell Anode: Mechanism, Design Strategies and Application9Application of Electrochemical Impedance Spectroscopy for Diagnostics in Fuel Cells, Electrolyzers, and Batteries24A-site cation deficiency-based LSCFN cathode achieving electrochemical performance enhancement in GDC-based solid oxide fuel cells6Chlorine doped K2NiF4-type oxide as an efficient oxygen reduction catalyst for protonic ceramic fuel cells9The Regulation Mechanism of Oxygen Vacancies in Ruddlesden–Popper Perovskite Ln2NiO4 (Ln = La, Pr, Nd) Air Electrode for Reversible Protonic Solid Oxide Cells10Optimization of Performance at Air Electrode Side for Protonic Solid Oxide Cells: Advances and Machine Learning Guided Perspectives7Advancement in Solid Oxide and Protonic Ceramic Electrolysis Cells: A Review22Unraveling Double-Exchange Effect Coupling Spin Modulation of Sr 2 Fe 1.5 Mo 0.5 O 6-δ Electrocatalyst for Solid Oxide Cells49Developing solid oxide electrolysis cells for CO2 conversion: A critical power-to-X approach9Advancement in materials and strategies for reliable and high-efficiency proton-conducting electrolytes in solid oxide cells5High-entropy perovskite air electrode with fluorine-induced Electron pair modulation strategy for stable and efficient reversible protonic ceramic cells8Revolutionizing bioenergy production: a review on sustainable biomass feedstock21Design of highly efficient catalysts guided by redox of individual carbon supports2Perovskite-socketed FeCoNiCu quaternary alloy nanoparticles for efficient CO2 reduction in solid oxide electrolyzer6Advanced fibrous matrix air electrode for high performance and durability in reversible solid oxide cells3Magnetic field controlled electrocatalysis from a multidimensional catalytic perspective: Mechanisms, applications, and prospects for energy conversion2Energy‐Saving Hydrogen Production via Small Molecules Electrooxidation‐Assisted Hybrid Systems52Status and Outlook of Solid Oxide Cells for Hydrocarbon Fuel Conversion13Self-assembled high performance composite air electrodes for proton-conducting reversible solid oxide cell1High-Entropy La0.2Pr0.2Sm0.2Nd0.2Sr0.2Co0.2Fe0.8O3 Air Electrode for Solid Oxide Electrolysis Cells0Research and Developments of Heterogeneous Catalytic Technologies20Heterogeneous La 0.75 Sr 0.25 Cr 0.5 Mn 0.5 O 3 ‐Based Nanocomposite Hydrogen Electrode for Efficient and Durable Solid Oxide Cells4Quantifying Interface-Dependent Active Sites Induced by Topotactic Exsolution for CO 2 Electrolysis24Advancements in electrocatalytic technologies for metal-supported solid oxide fuel cells: enhancing efficiency and durability for biofuel-powered mobility applications4High‐Entropy Co‐Based Oxygen Electrodes with Enhanced Thermomechanical Compatibility for Reversible Protonic Ceramic Cells6Advancements in dual-atom-site catalysts for electrocatalysis8Spin-State Tuning in PrFeO3-δ Perovskite for High-Temperature Oxygen Evolution Reaction21Disordered Pr-alumina: Enabling fast proton dynamics across energy systems7Hydrogen and Japan’s Energy Transition: A Blueprint for Carbon Neutrality15Advances, practical applications, and future prospects of layered perovskite oxides (LnBaCo 2 O 5+ δ ) for electrocatalysis reactions5Scientific peripheralism in Green Hydrogen: Morocco's collaboration patterns and strategic misalignment5Enhancing performance and stability of Sm0.2Ce0.8O1.9-decorated La0.6Sr0.4CoO3−δ composite cathode in flat-tube solid oxide fuel cell4An electrochemical micromonolithic membrane reactor for one-step sustainable covalorization of CH4 and CO2 to C2+ and CO1Dual-Donor Doped Perovskite as Bifunctional Oxygen Electrode Catalyst for Reversible Protonic Ceramic Electrochemical Cell24Harvesting blue energy via flow-electrode capacitive mixing (F-CapMix): From fundamental understanding to scalable power generation2Multiple-element-regulated CeO2 with high conductivity and sintering ability as electrolytes/buffer layers for solid oxide fuel cells0A Brief Review of H 2 S and Nitrogen-Based Contaminants from Biogas: Effects on Reforming Catalysts and SOFC Anodes6Orbital-level insights into multifunctional electrocatalysis of transition-metal single atoms anchored on WS 2 monolayers2Advancement in Electrolyte Materials for Solid Oxide Fuel Cells3High-entropy strategies transforming solid oxide cells: Progress and perspectives6Probing the proton exchange kinetics of BaZr 0.1 Ce 0.7 Y 0.1 Yb 0.1 O 3− δ ceramic electrolyte by operando diffuse reflectance infrared Fourier transform spectroscopy6Morphological, structural, and binder-free engineering for enhanced water electrolyzers3Airflow in Solid Oxide Steam Electrolyser Systems: Balancing Oxygen Dilution and Thermodynamic Efficiency0Airflow in Solid Oxide Steam Electrolyser Systems: Balancing Oxygen Dilution and Thermodynamic Efficiency0Is the catalytic current always proportional to the surface area of an electro-catalyst?1Rational design and characterization of RuO 2 -based catalysts for the acidic oxygen evolution reaction guided by reaction pathway regulation2Robust all-in-one multilayered protonic ceramic electrochemical cells using transition-metal-free electrodes via one-step high-temperature sintering0Robust bifunctional Zr and Y co-doped Ba 0.5 Sr 0.5 Co 0.8 Fe 0.2 O 3− δ oxygen electrode for reversible protonic ceramic electrochemical cells0Sacrificial carbon fiber–nickel hydroxide core–shell particles for nickel oxide diffusion from pore surfaces to grain interfaces in zirconia1Toward system-level energy density enhancement in solid oxide cells through 3D structural design0In situ re-constructed oxygen electrodes with enhanced thermomechanical compatibility for reversible protonic ceramic cells1Study on Electrochemical Behavior at a Room and High Temperature at 700 °C Corrosion of Austenite, Ferrite, and Duplex Stainless Steels1Sequential Core–Shell to Alloy Evolution Enables the Structural Stabilization and Catalytic Activation of Solid Oxide Electrolysis Cells2CuxNiy/CeO2 catalyst for CO2 reduction in a creative CO2/H2 solid oxide fuel cell1Insight into A-site deficiency on the cyclic redox behaviors of (La0.2Sr0.8)xTi0.9Ni0.1O3-δ (x=0.95, 0.90 and 0.85) perovskites by CO2 re-oxidation for SOCs1Advances, Challenges, and Future Directions in Materials for Solid Oxide Fuel Cells1Trace vanadium doping triggers the additional oxygen vacancies in the oxygen electrode of solid oxide cells1Salt-Assisted Synthesis of 2D Materials for Electrochemical Applications5Are the ohmic and polarization resistances of solid oxide electrochemical cells independent from each other?1Applications of neutron scattering in solid oxide fuel cells1Contemporary trends and frontiers in oxygen electrode design for protonic ceramic electrochemical cells: A scientometric perspective4Nb and Mo co-doped SrCoO3- perovskite oxide with regulated active sites as bifunctional oxygen electrodes for reversible solid oxide cells0Emerging Materials and Future Strategies for Solid Oxide Electrochemical Cells2Rational design of a lattice-stabilized perovskite oxygen electrode for robust and high-performance solid oxide electrolysis cells0Synergistic optimization of activity and stability in La0.6Sr0.4FeO3-δ fuel electrode via Sm doping for solid oxide electrolysis cells2Surface Modification of Self-Assembled Composite Cathode for Solid Oxide Fuel Cells with NiO Nanoparticles0Structural insights and proton transport features in a hexagonal Ba5Ho2Al2SnO13 perovskite2Proton-conducting electrolytes for high-performance ceramic electrolysis cells: Materials, mechanisms, modification, and process8Hybrid transition metal oxides of nickel and Cobalt as active and robust multifunctional electrode materials for intermediate-temperature symmetrical solid oxide cells0Thermodynamics and kinetics evolution in multicomponent high-entropy perovskite: a molecular dynamics study1Synergistic multi-heterointerface engineering of nanocomposite oxide fuel electrodes for highly active and durable high-temperature CO2 electrolysis0Tailoring Active Components of Nanoparticles via Sequential In Situ Exsolution for High‐Performance Solid Oxide CO 2 Electrolyzers2Artificial intelligence and machine learning models for electrolyzers and fuel cells optimization: A review on empowering sustainable hydrogen economy2Boosting electrocatalytic activity of oxygen electrodes PrBa0.475Sr0.475(Co1.5Fe0.5)0.9Ni0.2O6-δ by cation defects engineering for reversible protonic ceramic cells0(Ga1/2V1/2)4+-doped lanthanum silicate apatites with improved ionic conductivity for solid oxide fuel cell electrolytes0Ru‐Doping‐Induced Dual‐Functionality in La 0.6 Sr 0.4 Co 0.2 Fe 0.8 O 3‐δ : Enhancing Efficient Multi‐Fuels Oxidation and Suppressing Sr Segregation for Robust Symmetric Solid Oxide Cells1Prussian blue analogue-assisted asymmetric flow-electrode capacitive mixing (F-CapMix) with high positive net power density0Electric Field and Oxygen Spillover Coupling Governs Electrode Migration in Solid Oxide Electrolysis Cells0Dynamic operation and reaction network coupling in solid oxide electrochemical reactors0Overcoming chromium poisoning in solid oxide cells through multiscale perovskite engineering1Solid Oxide Cells for Power‐to‐X: Advances, Challenges, and Pathways to Carbon‐Neutral Fuels and Chemicals0Synergistic Ni Single Atoms/Nanoparticles on CeO 2 for High‐Performance and Durable SOFC Hydrogen Electrodes0Defect Engineering Through Ni/Co/Fe‐Doping in LaMnO 3 Perovskite Oxides for Enhanced Dielectric and Electrochemical Properties0Nanomaterials for the supercapacitor electrode: Various dimensional structures, constructed architectures and enhancement strategies2A review of reversible solid oxide cell technologies for hydrogen-based and multi-fuel energy systems2Mechanistically Interpretable Artificial Intelligence for Designing Oxygen Electrocatalysts0Modification strategies for fuel electrodes in solid oxide electrolysis cells: Co-electrolysis of CO2/H2O to value-added chemicals0Promoting the selective electrochemical upgrading of light alkanes to ethylene via advanced solid oxide electrolysis cells: Advances and outlook0Phonon‐Driven Tetrahedral Tilts Enable Ultralow Bulk Thermal Expansion and Interstitial Oxide‐Ion Migration in Phenacite Solid Electrolytes0Linking the past and future of solid oxide cells: A bibliometric analysis based on recent articles from two premier review journals0Design Principles of Electrocatalysts for Industrial‐Scale Water Electrolysis0High-Temperature CO2 Reduction: Operando Analysis and Reaction Dynamics0Synergistic modulation of oxygen vacancies and electronic structure for efficient CO2 electroreduction in perovskite cathodes0Boosting oxygen evolution reaction of La0.8Sr0.2MnO3 electrodes by modulating the conductive mechanism with Co element in SOEC0Multiphase Co-Fe phosphide/selenide heterostructures for efficient alkaline overall water splitting2In situ/operando X-ray methods for investigating high-temperature electrocatalysis0Minimal Transport Units Govern Oxygen‐Defect Stabilization and Transport for Lightweight Solid Electrolytes0High‑Entropy Perovskite Anodes for Efficient Water Oxidation Reaction in Protonic Ceramic Electrolysis Cells0Sr-doping induces lattice modulation in perovskite for enhanced reversible solid oxide cell performance0Unraveling the coupled mechanisms of heat conduction and oxygen ion migration in rare earth elements co-doped YSZ by non-equilibrium molecular dynamics0AI-assisted multi-objective optimization of Ni anode microstructure for enhanced electrochemical performance and long-term stability of solid oxide fuel cells0Ionic-Layer Engineering Enables Propeller-Type Interstitialcy Oxygen Migration in Close-Packed Perovskite Solid Electrolytes0Structure-transport-reactivity relationships for advanced SOFC cathodes0High‐Entropy Perovskites for Solid Oxide Cells: Mechanistic Insights to Practical Applications0

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