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RESEARCH PAPER · Chemistry of Materials · 2021

Creating a Green-Emitting Phosphor through Selective Rare-Earth Site Preference in NaBaB 9 O 15 :Eu 2+

Ya Zhuo, Shruti Hariyani, Jiyou Zhong, Jakoah Brgoch

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Creating a Green-Emitting Phosphor through Selective Rare-Earth Site Preference in NaBaB 9 O 15 :Eu 2+OriginalGlutathione-Capped Au Nanoclusters Embedded in NaCl Crystals for White Light-Emitting Devices22Synthesis, optical and magnetic study of nicotinic acid ligand lanthanum, neodymium and terbium complexes5Enhanced self-host blue emission of CaSrSb2O7 materials via Bi3+ ion doping for high CRI WLEDs, security inks and flexible displays19Suppression of Eu2+ Luminescence Loss14Improvement of the thermal stability of bluish-cyan emitting phosphor Y 2 MgAl 4 SiO 12 :Eu 2+ using substitution cations (Zn, Ca, Sr) for white LEDs10Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping13Designing ultra-highly efficient Mn2+-activated Zn2GeO4 green-emitting persistent phosphors toward versatile applications62Spectral Design of Phosphor-Converted LED Lighting Guided by Color Theory26(INVITED)Narrow-band violet and blue emission of Bi3+ in M10P6O25 (M = Ca, Sr) based on highly symmetric crystal structure10A novel red-emitting phosphor with an unusual concentration quenching effect for near-UV-based WLEDs40Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+12Modulating A site compositions of europium( iii )-doped double-perovskite niobate phosphors32Effects of activated Sr 2+ ion content on strong blue‐emitting Ca 2 Sb 2 O 7 materials for high‐quality WLED devices5Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor77Full-spectrum solid-state white lighting with high color rendering index exceeding 96 based on a bright broadband green-emitting phosphor45Sensitive and Reliable Fluorescent Thermometer Based on a Red-Emitting Li2MgHfO4:Mn4+ Phosphor21Hetero-valent substitution design of high thermal stability reddish-orange Sr3Ga2Sn1·5Si2·5O14:Sm3+ phosphor for healthy lighting white-light-emitting-diodes applications31A novel sulfide phosphor, BaNaAlS3:Eu2+, discovered via particle swarm optimization24Co-existence and unique co-emission properties of Eu3+/Eu2+ and Sm3+/Sm2+ in LiSrB9O15 host lattice15Ultrastable Photoluminescence Enabled by 1D Rare-Earth Metal–Organic Frameworks Based on Double Thiacalix[4]arene-Capped Nodes19Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting89Defect and energy transfer induced abnormal thermally stable and highly efficient narrow-band green emission19Bright green emitting Terbium-MOF with high quantum yield achieved through post synthetic modifications20Directly imaging of the atomic structure of luminescent centers in CaYAlO4:Ce3+6Novel near-ultraviolet-excited and thermally-stable blue-emitting phosphor for healthy WLED lighting30Luminescence in the solid state7Design of novel cyan phosphor Ca7NaLu(PO4)6:Eu2+ for full-visible-spectrum white LED: enhanced thermal stability and tuned emission by neighbor cation effect30From lab to lamp: Understanding downconverter degradation in LED packages7Fluorescence modulation in Pr3+-doped MGd2O4 (M = Sr, Ba) by the site engineering strategy4Highly Efficient Narrow‐Band Green Emission in LaZn 1 ‐ x Mn x Al 11 O 19 Magnetoplumbite Phosphors toward White LED Application and Optical Thermometer46On The Validity of the Defect- Induced Negative Thermal Quenching of Eu2+-Doped Phosphors7A multi-centre activated single-phase white light phosphor with high efficiency for near-UV based WLEDs69High performance of broad excitation and narrow emission green phosphor NaAl 11 O 17 :Eu 2+ , Mn 2+ for backlight displays20KSrVO4:Tb3+−A potential green-emitting nanophosphor candidate for white LEDs13Near ultraviolet light excitable highly efficient blue-green multicolour warwickite phosphor, ScCaO(BO 3 ):Ce 3+ , Tb 3+7Tunable Salt-Inclusion Chalcogenides for Ion Exchange, Photoluminescence, and Scintillation12Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries21Luminescence characteristics of Ce3+/Eu2+ activated (Ba, Sr)3YB3O9 phosphors3Colossal Chromatic Shift in the Ba 2 Ca 2 B 4 O 10 :Ce 3+ Phosphor45Thiogallate phosphor for white LEDs with water-resistance and green light-emitting capability7Intense narrow band blue emission in CuCrO 2 delafossite by Ni 2+ -Mg 2+ dual cation doping2A guide to comprehensive phosphor discovery for solid-state lighting245Enhanced photoluminescence of K7CaY2(B5O10)3:Eu3+,Sm3+/Gd3+ phosphors through energy transfer and their applications in LED lights for plant growth29Green‐Emitting Oxonitridoberyllosilicate Ba[BeSiON 2 ]:Eu 2+ for Wide Gamut Displays17A highly Mn 2+ -doped narrowband green phosphor toward wide color-gamut display applications26Near UV-photons excited highly pure and thermally stable Ca2B2O5: Sm3+ phosphor for filling the amber gap12Unusual red luminescence and super thermal stability of a new narrow-band emission phosphor for backlight display application21Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting42Negative Thermal Quenching of Photoluminescence: An Evaluation from the Macroscopic Viewpoint28Occupation site and chemical composition preference-driven high-sensitivity lifetime thermometry in single Tb3+-doped double-perovskite phosphors3A thermally stable narrow-band green phosphor Na2MgAl10O17: Eu2+, Mn2+ for NUV LED application25Absolutely Structural Disorder Boosting Bandwidth toward Full‐Spectrum White Light from Single Occupancy of Activator36Bright and persistent green emitting MgGa 2 O 4 :Mn 2+ for phosphor converted white light emitting diodes21High-performance, narrow-band green-emitting phosphors for white LEDs: recent advances and perspectives36Achieving successful reduction of Eu3 + to Eu2+ in NaYSiO4 lattice towards lighting & display applications by a two-pronged approach6A narrow band blue phosphor NaBa 4 Al 2 B 8 O 18 Cl 3 :Eu 2+ for white light emitting diodes5Tunable photoluminescence in Eu2+-activated KCaLa(PO4)2 phosphor through structural disorder3A review of recent advances in Ce3+-activated garnet phosphors for blue-chip-pumped pc-WLEDs81Synthesis, optical properties and warm white LED applications of dysprosium ion (Dy3+)- activated barium orthoborate yellow phosphors9Topological Understanding of Luminescence in Eu 2+ -Doped Borate Phosphors3Compositional Design of Mn 2+ ‐Activated Phosphors: Toward Narrow‐Band Green Emission for Wide Color Gamut Displays11Activating Deep‐Red Emission in Borate Phosphors via Low‐Coordination Engineering for Efficient Plant Lighting7Breaking Concentration Quenching for Excellent Highly Efficient and Stable Narrowband Luminescence by Structural Ordering and Defect Regulation2Rare‐Earth Coordination Hydrogels Enabling Self‐Powered and Self‐Luminous Closed‐Loop Systems5Photoluminescence Enhancement through Anion Sublattice Engineering in (dien)In(Cl 1– x Br x ) 6 Hybrid Halides2Luminescence properties and Judd-Ofelt analysis of cool green emitting terbium fumarate MOF synthesized via microwave assisted co-precipitation method2Site-selective Eu2+ occupation in multi-polyhedral Ca3Al2O6 for tunable high-color-purity blue and red emission0Synthesis and luminescence properties of Ba3Y2B6O15: Ce3 +, Eu3+/Eu2+ phosphors with Ca2+-induced auto-reduction for high-performance pc-wLEDs0

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  1. Glutathione-Capped Au Nanoclusters Embedded in NaCl Crystals for White Light-Emitting Devices

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  2. Synthesis, optical and magnetic study of nicotinic acid ligand lanthanum, neodymium and terbium complexes

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  3. Enhanced self-host blue emission of CaSrSb2O7 materials via Bi3+ ion doping for high CRI WLEDs, security inks and flexible displays

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  4. Suppression of Eu2+ Luminescence Loss

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  5. Improvement of the thermal stability of bluish-cyan emitting phosphor Y 2 MgAl 4 SiO 12 :Eu 2+ using substitution cations (Zn, Ca, Sr) for white LEDs

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  6. Enhancement of Eu2+ photoluminescence behavior in NaBaB9O15 based on the K+ doping

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  7. Designing ultra-highly efficient Mn2+-activated Zn2GeO4 green-emitting persistent phosphors toward versatile applications

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  8. Spectral Design of Phosphor-Converted LED Lighting Guided by Color Theory

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  9. (INVITED)Narrow-band violet and blue emission of Bi3+ in M10P6O25 (M = Ca, Sr) based on highly symmetric crystal structure

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    Peipei Dang, Wei Yang, Qianqian Zhang, Dongjie� Liu, Hongzhou Lian, Guogang Li, Jun Lin

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  10. A novel red-emitting phosphor with an unusual concentration quenching effect for near-UV-based WLEDs

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  11. Local environment rigidity and the evolution of optical properties in the green-emitting phosphor Ba 1− x Sr x ScO 2 F:Eu 2+

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  12. Modulating A site compositions of europium( iii )-doped double-perovskite niobate phosphors

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  13. Effects of activated Sr 2+ ion content on strong blue‐emitting Ca 2 Sb 2 O 7 materials for high‐quality WLED devices

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  14. Eu2+ Doping Concentration-Induced Site-Selective Occupation and Photoluminescence Tuning in KSrScSi2O7:Eu2+ Phosphor

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  15. Full-spectrum solid-state white lighting with high color rendering index exceeding 96 based on a bright broadband green-emitting phosphor

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  16. Sensitive and Reliable Fluorescent Thermometer Based on a Red-Emitting Li2MgHfO4:Mn4+ Phosphor

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  17. Hetero-valent substitution design of high thermal stability reddish-orange Sr3Ga2Sn1·5Si2·5O14:Sm3+ phosphor for healthy lighting white-light-emitting-diodes applications

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  18. A novel sulfide phosphor, BaNaAlS3:Eu2+, discovered via particle swarm optimization

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  19. Co-existence and unique co-emission properties of Eu3+/Eu2+ and Sm3+/Sm2+ in LiSrB9O15 host lattice

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  20. Ultrastable Photoluminescence Enabled by 1D Rare-Earth Metal–Organic Frameworks Based on Double Thiacalix[4]arene-Capped Nodes

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  21. Ultra‐Broadband Green‐Emitting Phosphors without Cyan Gap Based on Double‐Heterovalent Substitution Strategy for Full‐Spectrum WLED Lighting

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  22. Defect and energy transfer induced abnormal thermally stable and highly efficient narrow-band green emission

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  23. Bright green emitting Terbium-MOF with high quantum yield achieved through post synthetic modifications

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  31. On The Validity of the Defect- Induced Negative Thermal Quenching of Eu2+-Doped Phosphors

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  33. High performance of broad excitation and narrow emission green phosphor NaAl 11 O 17 :Eu 2+ , Mn 2+ for backlight displays

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  34. KSrVO4:Tb3+−A potential green-emitting nanophosphor candidate for white LEDs

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  35. Near ultraviolet light excitable highly efficient blue-green multicolour warwickite phosphor, ScCaO(BO 3 ):Ce 3+ , Tb 3+

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  37. Site‐Engineering for Controlling Multiple‐Excitation and Emission in Eu2+‐Activated CaSrSiO4 Phosphors in Marine Fisheries

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  38. Luminescence characteristics of Ce3+/Eu2+ activated (Ba, Sr)3YB3O9 phosphors

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  46. Near UV-photons excited highly pure and thermally stable Ca2B2O5: Sm3+ phosphor for filling the amber gap

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  47. Unusual red luminescence and super thermal stability of a new narrow-band emission phosphor for backlight display application

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  48. Progress of Ce 3+ /Eu 2+ doped phosphors for violet chip based full-spectra lighting

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  49. Negative Thermal Quenching of Photoluminescence: An Evaluation from the Macroscopic Viewpoint

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  50. Occupation site and chemical composition preference-driven high-sensitivity lifetime thermometry in single Tb3+-doped double-perovskite phosphors

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