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RESEARCH PAPER · Advanced Functional Materials · 2023

Wide‐Bandgap Perovskite‐Inspired Materials: Defect‐Driven Challenges for High‐Performance Optoelectronics

Gopal Krishnamurthy Grandhi, David F. Hardy, Krishnaiah Mokurala, Brenda Cabral Vargas, Basheer Al‐Anesi, Mahesh P. Suryawanshi, Diego Solís-Ibarra, Feng Gao, Robert L. Z. Hoye, Paola Vivo

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Wide‐Bandgap Perovskite‐Inspired Materials: Defect‐Driven Challenges for High‐Performance OptoelectronicsOriginalDefect passivation engineering of wide-bandgap perovskites for high-performance solar cells30Multibit, Lead‐Free Cs2SnI6 Resistive Random Access Memory with Self‐Compliance for Improved Accuracy in Binary Neural Network Application28Effects of Palladium Doping on Structural, Mechanical,And Opto-Electronic Behavior of Cs2pt1-Xpdxbr6 Double Perovskites*Zhenyun Chang#, Xiuhong Cao#, Jing Chang0Enhanced photodynamic therapy efficacy of Ni-doped/oxygen vacancy double-defect Ni-ZnO@C photosensitizer in bacteria-infected wounds based on ROS damage and ATP synthesis inhibition35Empowering Indoor Photovoltaics: Stable Lead‐Free Perovskites and Beyond13Enhanced Conversion Efficiency in MAPbI3 Perovskite Solar Cells through Parameters Optimization via SCAPS-1D Simulation51Super narrow bandgap (<1.2 eV) halide double perovskites: Recent advancements and future perspectives11Carrier transport layer engineering of Cs2TiI2Br4 halide double perovskite solar cell via SCAPS 1D: Approaching the Shockley-Queisser limit14Data-driven strategy for bandgap database construction of perovskites and the potential segregation study11Effects of palladium doping on structural, mechanical，and opto-electronic behavior of Cs2Pt1-xPdxBr6 double perovskites2Theoretical Design of Tellurium-Based Two-Dimensional Perovskite Photovoltaic Materials1Device engineering of lead‐free FaCsSnI3/Cs2AgBiI6‐based dual‐absorber perovskite solar cell architecture for powering next‐generation wireless networks12Enhancing Charge Transfer in Perovskite‐Inspired Silver Iodobismuthate‐Based Solar Cells via Cesium Iodide Interlayer4A review of chalcogenide-based perovskites as the next novel materials: Solar cell and optoelectronic applications, catalysis and future perspectives111Radiative recombination model for BiSeI microcrystals: unveiling deep defects through photoluminescence5Leveraging ordered voids in microporous perovskites for intercalation and post-synthetic modification5Solution‐Processed Tin‐Antimony Quaternary Chalcohalides for Self‐Powered Broadband Photodetectors6Defect characterization and prospective applications of Cs3Bi2I9 perovskite: Insights from surface photovoltage spectroscopy10Solar Cells Based on Pb-Free and Perovskite-Inspired Materials: Futuristic of Perovskite Solar Cells44Assessing the Environmental Impact of Pnictogen‐based Perovskite‐Inspired Materials for Indoor Photovoltaics8Exploring the Physical, Electrical and Optical Properties of Cs2LiInBr6 Perovskite: An Extensive study Utilizing DFT Based GGA-PBE and HSE06 Functionals21Perovskite‐Inspired Cs₂AgBi₂I₉: A Promising Photovoltaic Absorber for Diverse Indoor Environments28Effects of Cationic Substitution on the Properties of Sb1-Xbixsei (X = 0 to 1) Compounds0From optoelectronics to scintillation applications: the versatility of lead-free halide double perovskites21Lead-Free Perovskites and Their Derivatives for Indoor Photovoltaic Applications0The promise of operational stability in pnictogen-based perovskite-inspired solar cells10Revisiting the effects of spin-orbit coupling and dispersion correction on the structural and electronic properties of APbI3 (A=MA, FA) halide perovskite6In-situ spectroelectrochemical analysis for understanding photophysical properties of halide perovskite nanocrystals1High-performance flexible deep ultraviolet photodetector based on crossed microwires heterojunction for real-time target trajectory tracking system19Structural-disorder-induced enhancement of second-harmonic generation in bismuth-based perovskite-inspired materials7Wide Bandgap Perovskites: A Comprehensive Review of Recent Developments and Innovations40The Rise of Chalcohalide Solar Cells: Comprehensive Insights From Materials to Devices21Synthesis and physical properties of (CdO)1-x(ZnO)x thin films obtained by electron beam evaporation for solar cell application2Perovskite‐Inspired Materials (PIMs): Exploring Their Potential for Photovoltaic Applications8Optimization of Near Infrared Transparent p‐i‐n Perovskite Solar Cells with Active Area >1 cm2 for Four‐Terminal Perovskite/Si Tandem Solar Cells8High-Performance Ammonia Plasma-Processed CsPbBr 3 Perovskite Photodetectors5Effects of cationic substitution on the properties of Sb1-xBixSeI (x = 0–1) compounds2Theoretical defect engineering in AgBiI4 for enhanced photovoltaic performance2Near-Unity PLQY in Lead-Free Halide Perovskites and Perovskite-Inspired Halides for Light-Emitting Diode Applications18Molecular Engineering of Layered Halide Double Perovskites: Challenges and Opportunities in Optoelectronics and Beyond22Dual-functional Cu-MOF modifies buried interfaces for high-performance and stable MAPbI3 photodetectors1Electro-Optical Analysis of Carrier Dynamics in Lead-Free Cs 3 Bi 2 I 9 Perovskite10Atomistic Mechanism of Defect Self-Passivation in Metal Halide Perovskites6Enhanced Broadband Photodetectors Based on Cu-Doped Cs2AgBiBr6 Nanocrystals via Localized States Driving Improved Device Performance2Lead-free perovskites for indoor photovoltaics2Silver–bismuth perovskite-inspired materials: chemistry, optoelectronic properties, and emerging applications in photovoltaics and beyond17Rudorffite Silver‐Bismuth Iodides: Emerging Eco‐Friendly Wide‐Bandgap Absorbers for Indoor Photovoltaics5Atomic Cartography of High‐Entropy Cs 2 B Cl 6 Perovskite‐Inspired Materials: The Vital Role of Solid‐State NMR Spectroscopy in Identifying Elemental Disorder5Vertically aligned lead-free Cs3Bi2I9 nanosheet forest via ZnO nanorod epitaxy for enhanced self-powered photodetection0Interplay of Manganese Doping in Lead-Free Cs 3 Bi 2 Br 9 Nanocrystals2Mixed‐Cation Engineering for Enhanced Efficiency and Stability of Mo 4+ ‐Doped Lead‐Free Perovskite for Near‐Infrared Phosphors3Flexible Cu2AgBiI6-based perovskite-inspired solar cells using large-scale processing methods1Stage‐Resolved Synergy of Tri‐Functional Additive in Perovskite Crystallization for High‐Efficiency Wide‐Bandgap Perovskite and Tandem Solar Cells8Back-contact charge selectivity enables efficient Cs 2 AgBi 2 I 9 indoor photovoltaics under ambient office lighting0Layered mixed-anion chalcohalides Pb 4 Sb 4 Q 9 Cl 2 (Q = S, Se): puckered 2D frameworks, indirect band gaps, and low thermal conductivity0Photocatalytic valorization of biomass derivatives for fine chemicals and fuels production over halide perovskite catalysts5Ferroelectric Metal–Organic Frameworks as Wide Band Gap Materials0Synthesis and characterization of polyvinyl alcohol-based ZnGa2O4 nanocomposites: structural, optical, and dielectric properties0Silyl Hot-Injection Versus Thiocyanate Heat-Up Synthesis of Chalcohalides: Pushing the Size and Composition Envelope0Mechanochemical Synthesis of Lead‐Free Halide Layered Double Perovskites: A Green and Scalable Approach2Unravelling Hybrid AI–SCAPS‐1D Framework for 29% Efficient CsSnGeI 3 /DNMO Dual‐Absorber Perovskite Solar Cells1Light Activated Charge‐Ionic Transport in Cs 2 AgBi 2 I 9 for Self‐Powered Synaptic Photodetection0Interfacial Engineering for Perovskite Photovoltaics: Multimolecular Synergy Versus All‐In‐One Integration0Single‐Crystal Perovskite High‐Energy Radiation Detectors: From Bulk Crystals to Micro/Nano Integration0Eco-friendly biochar-modified ZnO nanoparticles for enhanced optoelectronic properties0

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  1. Defect passivation engineering of wide-bandgap perovskites for high-performance solar cells

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  2. Multibit, Lead‐Free Cs2SnI6 Resistive Random Access Memory with Self‐Compliance for Improved Accuracy in Binary Neural Network Application

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  3. Effects of Palladium Doping on Structural, Mechanical,And Opto-Electronic Behavior of Cs2pt1-Xpdxbr6 Double Perovskites*Zhenyun Chang#, Xiuhong Cao#, Jing Chang

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  4. Enhanced photodynamic therapy efficacy of Ni-doped/oxygen vacancy double-defect Ni-ZnO@C photosensitizer in bacteria-infected wounds based on ROS damage and ATP synthesis inhibition

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  6. Enhanced Conversion Efficiency in MAPbI3 Perovskite Solar Cells through Parameters Optimization via SCAPS-1D Simulation

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  7. Super narrow bandgap (<1.2 eV) halide double perovskites: Recent advancements and future perspectives

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  8. Carrier transport layer engineering of Cs2TiI2Br4 halide double perovskite solar cell via SCAPS 1D: Approaching the Shockley-Queisser limit

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  9. Data-driven strategy for bandgap database construction of perovskites and the potential segregation study

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  10. Effects of palladium doping on structural, mechanical，and opto-electronic behavior of Cs2Pt1-xPdxBr6 double perovskites

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  11. Theoretical Design of Tellurium-Based Two-Dimensional Perovskite Photovoltaic Materials

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  12. Device engineering of lead‐free FaCsSnI3/Cs2AgBiI6‐based dual‐absorber perovskite solar cell architecture for powering next‐generation wireless networks

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  16. Leveraging ordered voids in microporous perovskites for intercalation and post-synthetic modification

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  18. Defect characterization and prospective applications of Cs3Bi2I9 perovskite: Insights from surface photovoltage spectroscopy

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  19. Solar Cells Based on Pb-Free and Perovskite-Inspired Materials: Futuristic of Perovskite Solar Cells

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  20. Assessing the Environmental Impact of Pnictogen‐based Perovskite‐Inspired Materials for Indoor Photovoltaics

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  22. Perovskite‐Inspired Cs₂AgBi₂I₉: A Promising Photovoltaic Absorber for Diverse Indoor Environments

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  49. Vertically aligned lead-free Cs3Bi2I9 nanosheet forest via ZnO nanorod epitaxy for enhanced self-powered photodetection

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  50. Interplay of Manganese Doping in Lead-Free Cs 3 Bi 2 Br 9 Nanocrystals

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