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RESEARCH PAPER · Advanced Optical Materials · 2021

LaSiP3 and LaSi2P6: Two Excellent Rare‐Earth Pnictides with Strong SHG Responses as Mid‐ and Far‐Infrared Nonlinear Optical Crystals

Yingshuang Sun, Jindong Chen, Shunda Yang, Bingxuan Li, Guoliang Chai, Chensheng Lin, Min Luo, Ning Ye

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LaSiP3 and LaSi2P6: Two Excellent Rare‐Earth Pnictides with Strong SHG Responses as Mid‐ and Far‐Infrared Nonlinear Optical CrystalsOriginalStructural diversity of the Zintl pnictides with rare-earth metals14The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks36Pnictides: An emerging class of infrared nonlinear optical material candidates47BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects22Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal15Machine Learning-Guided Discovery of Ternary Compounds Containing La, P, and Group 14 Elements14AIn 3 Si 4 P 9 (A = Ca, Sr): quaternary phosphides with double-helix structures exhibiting high laser-induced damage thresholds19Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS324Theoretical investigations on ternary defective diamond-like infrared nonlinear optical materials in Be-Ga-Se system18Chiral cadmium–amine complexes for stimulating non-linear optical activity and photoluminescence in solids based on aurophilic stacks8Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals13EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response4Synthesis of LaCN3, TbCN3, CeCN5, and TbCN5 Polycarbonitrides at Megabar Pressures7FeSi4P4 and CoSi3P3: Hidden Gems of Ternary Tetrel Pnictides with Outstanding Nonlinear Optical Properties11Effect of pressure on the structure, elasticity and optical properties of AgGaSe2 crystal3Achieving strong optical nonlinearity and wide bandgap of pnictides via ionic motif–driven directed assembly of covalent groups40Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy16Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy8Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality30Synthesis challenges, thermodynamic stability, and growth kinetics of La–Si–P ternary compounds1Prediction of lanthanide-containing ternary compounds2Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 1131Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 116Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids9Developing a neural network machine learning interatomic potential for molecular dynamics simulations of La–Si–P systems4CaM 3 Si 4 As 11 (M = Ga, In): arsenide infrared nonlinear optical crystals enforced by novel [As 2 ] linear motifs0中红外非线性光学晶体AVO2SeO3（A=Rb+， Cs+）的结构和光学性能研究（特邀）0Mid-Infrared Transparent Materials: from Mechanisms to Cutting-Edge Applications10Design of a High-Performance Infrared Nonlinear Optical Crystal via a Multiple Flexible-Group Synergistic Polarization Strategy12Halogen‐Rich Design Strategy: Rational Synthesis of High‐Performance Tetrahedron‐Based Chalcohalides for Advanced Infrared Optical Materials2Halogen‐Rich Design Strategy: Rational Synthesis of High‐Performance Tetrahedron‐Based Chalcohalides for Advanced Infrared Optical Materials2Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects0CaM 3 Si 4 P 11 (M = Al, Ga): [P 2 ] Motifs‐Modified Quasi‐T 3 Supertetrahedra Drive Superior Infrared Nonlinear Optical Performances1Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity0Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides0

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  1. Structural diversity of the Zintl pnictides with rare-earth metals

    Elsevier eBooks · 2021-01-01

    Sviatoslav Baranets, Alexander Ovchinnikov, Svilen Bobev

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  2. The Rise of Infrared Nonlinear Optical Pnictides: Advances and Outlooks

    Chemistry - An Asian Journal · 2021-09-01

    He‐Di Yang, Mao‐Yin Ran, Wenbo Wei, Xin‐Tao Wu, Hua Lin, Qi‐Long Zhu

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  3. Pnictides: An emerging class of infrared nonlinear optical material candidates

    Journal of Alloys and Compounds · 2021-12-22

    Jindong Chen, Xiaotian Jiang, Qingchen Wu, Zheshuai Lin, Min Luo, Ning Ye

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  4. BaSi7P10 and SrSi7P10: Two Infrared Nonlinear Optical Phosphides with T2 Supertetrahedra Exhibiting Strong Second‐Harmonic Generation Effects

    Advanced Optical Materials · 2022-06-05

    Xin Lei Zhao, Chensheng Lin, Jindong Chen, Feng Xu, Shunda Yang, Guang Peng, Haotian Tian, Yinglei Han, Bingxuan Li, Min Luo, Ning Ye

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  5. Tailored Ordered Structures with Functional Units of Distorted [NbO6] and Antiparallel [GeO4] for Enhanced Birefringence in Germanate Crystal

    Advanced Optical Materials · 2022-09-01

    Wenli Zhao, Jinmiao Jiao, Yuheng She, Fei Liang, Ning Ye, Zhanggui Hu, Yicheng Wu, Conggang Li

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  6. Machine Learning-Guided Discovery of Ternary Compounds Containing La, P, and Group 14 Elements

    Inorganic Chemistry · 2022-10-11

    Huaijun Sun, Chao Zhang, Weiyi Xia, Ling Tang, Renhai Wang, Georgiy Akopov, Nethmi W. Hewage, Kai‐Ming Ho, Kirill A. Kovnir, Cai‐Zhuang Wang

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  7. AIn 3 Si 4 P 9 (A = Ca, Sr): quaternary phosphides with double-helix structures exhibiting high laser-induced damage thresholds

    Inorganic Chemistry Frontiers · 2022-12-19

    Ming‐Shu Zhang, Bin‐Wen Liu, Xiao‐Ming Jiang, Guo‐Cong Guo

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  8. Theoretical Prediction‐Assisted Synthesis and Characterization of Infrared Nonlinear Optical Material NaSrBS3

    Advanced Optical Materials · 2023-05-05

    Yihan Yun, Mengfan Wu, Congwei Xie, Zhihua Yang, Guangmao Li, Shilie Pan

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  9. Theoretical investigations on ternary defective diamond-like infrared nonlinear optical materials in Be-Ga-Se system

    Materials Today Physics · 2023-09-29

    Linan Wang, Dongdong Chu, Deqiang Yin, Congwei Xie, Zhihua Yang, Junjie Li, Shilie Pan

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  10. Chiral cadmium–amine complexes for stimulating non-linear optical activity and photoluminescence in solids based on aurophilic stacks

    Journal of Materials Chemistry C · 2024-01-01

    Kseniia Boidachenko, Michał Liberka, Junhao Wang, Hiroko Tokoro, Shin‐ichi Ohkoshi, Szymon Chorąży

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  11. Centric Sc(HPO3)(H2PO3)(H2O) and Acentric Sc(H2PO3)3: Two Ultraviolet Scandium Phosphite Optical Crystals

    Inorganic Chemistry · 2024-04-11

    Liang Ma, Yi‐Lei Lv, Xiao-Fang Ao, Wenlong Liu, Sheng‐Ping Guo, Ru‐Ling Tang

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  12. EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response

    Inorganic Chemistry · 2024-05-30

    Yunxia Song, Chensheng Lin, Chao Wang, Yuqiao Zhou, Shenghao Fang, Pengxiang Dong, Bingxuan Li, Ning Ye, Xin Lei Zhao, Min Luo

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  13. Synthesis of LaCN3, TbCN3, CeCN5, and TbCN5 Polycarbonitrides at Megabar Pressures

    Journal of the American Chemical Society · 2024-06-25

    Andrey Aslandukov, Akun Liang, Amanda Ehn, Florian Trybel, Yuqing Yin, Alena A. Aslandukova, Fariia Iasmin Akbar, Umbertoluca Ranieri, James E. Spender, Ross T. Howie, Eleanor Lawrence Bright, Jonathan Wright, Michael Hanfland, GARBARINO Gaston Leonel, Mohamed Mézouar, Timofey Fedotenko, Igor A. Abrikosov, Natalia Dubrovinskaia, Leonid Dubrovinsky, Dominique Laniel

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  14. FeSi4P4 and CoSi3P3: Hidden Gems of Ternary Tetrel Pnictides with Outstanding Nonlinear Optical Properties

    Chemistry of Materials · 2024-09-03

    Ernesto Soto, Shannon Lee, Andrew P. Porter, Gayatri Viswanathan, Georgiy Akopov, Nethmi W. Hewage, Kui Wu, Victor Trinquet, Guillaume Brunin, Geoffroy Hautier, Gian‐Marco Rignanese, Aaron J. Rossini, Kirill A. Kovnir

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  15. Effect of pressure on the structure, elasticity and optical properties of AgGaSe2 crystal

    Physica B Condensed Matter · 2024-10-28

    Zhen Fan, Guangyong Jin, Hongxu Liu, Ye Li

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  16. Achieving strong optical nonlinearity and wide bandgap of pnictides via ionic motif–driven directed assembly of covalent groups

    Science Advances · 2024-11-13

    Lihua Gao, Jindong Chen, Xuemei Shi, Yan Xiao, Yinglei Han, Chensheng Lin, Huikang Jiang, Guangsai Yang, Guang Peng, Ning Ye

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  17. Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy

    Angewandte Chemie International Edition · 2024-12-05

    Chao Wang, Chensheng Lin, Xin Zhao, Shunda Yang, Tao Yan, Shenghao Fang, Lingli Wu, Ning Ye, Min Luo

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  18. Design of High‐Performance Infrared Nonlinear Optical PAs 3 S 3 with Perfectly Aligned Polar Molecular Cage via a Bipolar‐Axis‐Symmetry Coupling Strategy

    Angewandte Chemie · 2024-12-05

    Chao Wang, Chensheng Lin, Xin Yi Zhao, Shunda Yang, Tao Yan, Shenghao Fang, Lingli Wu, Ning Ye, Min Luo

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  19. Prismatic crystal field stabilized divalent rare-earth chalcogenide REIIBII6CIII6QVI16 with bifunctionality

    The Innovation Materials · 2025-01-01

    Linan Wang, Hongshan Wang, Qi Sun, Zuxin Chen, Fei Tang, Shilie Pan, Junjie Li, Miriding Mutailipu

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  20. Synthesis challenges, thermodynamic stability, and growth kinetics of La–Si–P ternary compounds

    Journal of Materials Chemistry A · 2025-01-01

    Ling Tang, Weiyi Xia, Gayatri Viswanathan, Ernesto Soto, Kirill A. Kovnir, Cai Zhuang Wang

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  21. Prediction of lanthanide-containing ternary compounds

    Computational Materials Science · 2025-02-20

    Huaijun Sun, Chao Zhang, Jianbo Huang, Xingdu Fan, Weiyi Xia, Ling Tang, Renhai Wang, Renhai Wang, Kunpeng Cui, Cai‐Zhuang Wang

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  22. Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 11

    Angewandte Chemie International Edition · 2025-02-26

    Shao‐Min Pei, Ming‐Shu Zhang, Xiao‐Ming Jiang, Bin‐Wen Liu, Guo‐Cong Guo

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  23. Reinforced Nonlinear Optical Performances Induced by P‐P Homoatomic Bond in Phosphide SrIn 3 Si 4 P 11

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  24. Nonlinear Optical Series A(VO2)3(SeO3)2 (A = NH4+, K+, and H3O+) with Large Birefringence Derived from High-Anisotropic VO6 Octahedra and SeO3 Pyramids

    Inorganic Chemistry · 2025-06-23

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  25. Developing a neural network machine learning interatomic potential for molecular dynamics simulations of La–Si–P systems

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  26. CaM 3 Si 4 As 11 (M = Ga, In): arsenide infrared nonlinear optical crystals enforced by novel [As 2 ] linear motifs

    Chemical Science · 2026-01-01

    Shusen Yang, Qichao Zhao, Xuemei Shi, Guang Peng, Ning Ye, Jindong Chen

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  27. 中红外非线性光学晶体AVO2SeO3（A=Rb+， Cs+）的结构和光学性能研究（特邀）

    Chinese Journal of Lasers · 2026-01-01

    钟丽 Zhong Li, 吴玲莉 Wu Lingli, Lin Chensheng, 李丙轩 Li Bingxuan, 颜涛 Yan Tao, 罗敏 Luo Min

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  28. Mid-Infrared Transparent Materials: from Mechanisms to Cutting-Edge Applications

    Nano-Micro Letters · 2026-02-28

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  29. Design of a High-Performance Infrared Nonlinear Optical Crystal via a Multiple Flexible-Group Synergistic Polarization Strategy

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  30. Halogen‐Rich Design Strategy: Rational Synthesis of High‐Performance Tetrahedron‐Based Chalcohalides for Advanced Infrared Optical Materials

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    Wen‐Li Zhao, Rui‐Xi Wang, Shuang Zhao, Cui-Er Deng, Li‐Ming Wu, Ling Chen

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  31. Halogen‐Rich Design Strategy: Rational Synthesis of High‐Performance Tetrahedron‐Based Chalcohalides for Advanced Infrared Optical Materials

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  32. Mid‐ to Far‐Infrared Nonlinear Optical Crystals: Design Strategies, Structure–Property Relationships and Engineering Prospects

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  33. CaM 3 Si 4 P 11 (M = Al, Ga): [P 2 ] Motifs‐Modified Quasi‐T 3 Supertetrahedra Drive Superior Infrared Nonlinear Optical Performances

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  34. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

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  35. Topology‐Preserving Ionic‐Unit Substitution Enables Sphalerite‐Like Phosphides Achieving Superior Infrared Optical Nonlinearity

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  36. Beyond the bandgap bottleneck: structure–property design principles for infrared nonlinear optical phosphides

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