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RESEARCH PAPER · Journal of Materials Chemistry A · 2021

Synthesis, band structure and photocatalytic properties of Sillén–Aurivillius oxychlorides BaBi 5 Ti 3 O 14 Cl, Ba 2 Bi 5 Ti 4 O 17 Cl and Ba 3 Bi 5 Ti 5 O 20 Cl with triple-, quadruple- and quintuple-perovskite layers

Daichi Ozaki, Hajime Suzuki, Kanta Ogawa, Ryota L. Sakamoto, Yoshiyuki Inaguma, Kouichi Nakashima, Osamu Tomita, Hiroshi Kageyama, Ryu Abe

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Synthesis, band structure and photocatalytic properties of Sillén–Aurivillius oxychlorides BaBi 5 Ti 3 O 14 Cl, Ba 2 Bi 5 Ti 4 O 17 Cl and Ba 3 Bi 5 Ti 5 O 20 Cl with triple-, quadruple- and quintuple-perovskite layersOriginalLayered Perovskite Oxyiodide with Narrow Band Gap and Long Lifetime Carriers for Water Splitting Photocatalysis95Durable Metal Heteroanionic Photocatalysts24Bi4AO6Cl2 (A = Ba, Sr, Ca) with Double and Triple Fluorite Layers for Visible-Light Water Splitting17PbBi3O4X3 (X = Cl, Br) with Single/Double Halogen Layers as a Photocatalyst for Visible-Light-Driven Water Splitting: Impact of a Halogen Layer on the Band Structure and Stability24Crystal and Band Engineering in Photocatalytic Materials0Local structure analysis and structure mining for design of photocatalytic metal oxychloride intergrowths2Facile Synthesis of Sillén-Aurivillius Layered Oxide Bi7Fe2Ti2O17Cl with Efficient Photocatalytic Performance for Degradation of Tetracycline11Lone-Pair-Induced Intra- and Interlayer Polarizations in Sillén-Aurivillius Layered Perovskite Bi4NbO8Br23Bi12O17Cl2 with a Sextuple BiO Layer Composed of Rock‐Salt and Fluorite Units and its Structural Conversion through Fluorination to Enhance Photocatalytic Activity31Bi-based layered perovskite oxyhalides: Up-and-coming catalysts for efficient energy harvesting and conversion18Bi 4 TaO 8 Cl as a New Class of Layered Perovskite Oxyhalide Materials for Piezopotential Driven Efficient Seawater Splitting64A Sillén oxyhalide SrBi 3 O 4 Cl 3 as a promising photocatalyst for water splitting: impact of the asymmetric structure on light absorption and charge carrier dynamics14Flux-assisted synthesis of tungsten-doped layered perovskite oxychloride with promoted visible-light-responsive O 2 evolution performance7Single-Crystalline Bi2YO4Cl with Facet-Aided Photocarrier Separation for Robust Solar Water Splitting27Synthesis and Structure of the Double-Layered Sillén–Aurivillius Perovskite Oxychloride La2.1Bi2.9Ti2O11Cl as a Potential Photocatalyst for Stable Visible Light Solar Water Splitting19Synthesis of multi-layered perovskite oxyiodides: Impact of number of perovskite layers and type of halide layer for band levels and photocatalytic properties14Orbital Engineering in Sillén–Aurivillius Phase Bismuth Oxyiodide Photocatalysts through Interlayer Interactions37Coupling of surface oxygen vacancy and 2D structure of Aurivillius-phase CaBi2Ta2O9 nanoplates for enhanced photocatalytic H2 production14Honeycomb layered frameworks with metallophilic bilayers8Theoretical and experimental investigation of the coordination effect on photocatalytic CO2 reduction efficiency of cobalt single atom catalyst36Exploring the potential of perovskite structures for chemical looping technology: A state-of-the-art review100Advances in the structural engineering of layered bismuth-based semiconductors for visible light-driven photocatalytic water splitting34Band engineering of layered oxyhalide photocatalysts for visible-light water splitting42Emerging polynary bismuth-based photocatalysts: Structural classification, preparation, modification and applications16Perovskite Oxynitrides and Oxysulfides toward Photocatalytic Green Hydrogen Production: Scalability Prospects5Tutorial on Describing, Classifying, and Visualizing Common Crystal Structures in Nanoscale Materials Systems20Perovskite materials for highly efficient Photo(electro)catalytic water splitting: A mini-review22Environmental application of versatile Bi-based perovskite photocatalysts and their Z-scheme and S-scheme heterojunctions25Synthetically Enforced Cation Migration in Sillén–Aurivillius Hybrid Perovskites Boosts Photocatalytic Hydrogen Evolution4Electrostatic Control of Electronic Structure in Modular Inorganic Crystals8Conduction Band and Defect Engineering for the Prominent Visible‐Light Responsive Photocatalysts10Conduction Band and Defect Engineering for the Prominent Visible‐Light Responsive Photocatalysts0Recent advances in lead-free carbon supported perovskites based on Z-scheme and S-scheme heterojunctions for photocatalytic energy conversion31Vanadium-based oxyhalide photocatalysts for visible-light-driven Z-scheme water splitting: advancing conduction band engineering0Structure-tailored superlattice Bi7Ti4NbO21: Coupling octahedral tilting and rotation induced high ferroelectric polarization for efficient piezo-photocatalytic CO2 reduction35Engineering (001) crystallinity for efficient photocatalytic water splitting in strontium-rich A3X1 Type-Bi4Sr2Ti2NbO14Cl perovskites0Enhanced Photocatalytic O2 Evolution over Layered Perovskite Oxyiodide Ba2Bi3Nb2O11I through Flux Synthesis and Surface Modifications7Layered perovskite Bi7Fe2Ti2O17Cl: Universally efficient photo-piezocatalysis and mechanismic insight into the origin of polarity4Plasma trap channels accelerate carrier migration in Sillén-Aurivillius perovskite heterojunctions for triple-effect pollutant degradation in recyclable foams0Hydrogen defects in LaBi 2 O 4 X (X = Cl, Br, and I) Sillén oxyhalide phases and their impacts on ionic transport0Structural origins of photocatalytic properties in Ruddlesden–Popper Sr n +1 Ti n O 3 n +1 ( n = 1, 2) and their topochemically fluorinated phases Sr n +1 Ti n O (3 n +1)− x F 2 x ( x ≈ n )3Synergistic Effect of Ultrasonication-Induced Surface Activation and A-Site Sr/Ba Distribution Unlocks Cocatalyst-Free Hydrogen Evolution in Sillén–Aurivillius Photocatalysts0

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  1. Layered Perovskite Oxyiodide with Narrow Band Gap and Long Lifetime Carriers for Water Splitting Photocatalysis

    Journal of the American Chemical Society · 2021-05-17

    Kanta Ogawa, Hajime Suzuki, Chengchao Zhong, Ryota L. Sakamoto, Osamu Tomita, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

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  2. Durable Metal Heteroanionic Photocatalysts

    ACS Applied Materials & Interfaces · 2021-07-28

    Kaustav Chatterjee, Sara E. Skrabalak

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  3. Bi4AO6Cl2 (A = Ba, Sr, Ca) with Double and Triple Fluorite Layers for Visible-Light Water Splitting

    Inorganic Chemistry · 2021-10-01

    Chengchao Zhong, Daichi Kato, Kanta Ogawa, Cédric Tassel, Fujio Izumi, Hajime Suzuki, Shogo Kawaguchi, Takashi Kei SAITO, Akinori Saeki, Ryu Abe, Hiroshi Kageyama

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  4. PbBi3O4X3 (X = Cl, Br) with Single/Double Halogen Layers as a Photocatalyst for Visible-Light-Driven Water Splitting: Impact of a Halogen Layer on the Band Structure and Stability

    Chemistry of Materials · 2021-12-07

    Hajime Suzuki, Masanobu Higashi, Osamu Tomita, Yusuke Ishii, Takafumi Yamamoto, Daichi Kato, Tetsu Kotani, Daichi Ozaki, Shunsuke Nozawa, Kouichi Nakashima, Koji Fujita, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

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  5. Crystal and Band Engineering in Photocatalytic Materials

    Springer eBooks · 2022-01-01

    Ryu Abe, Hajime Suzuki

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  6. Local structure analysis and structure mining for design of photocatalytic metal oxychloride intergrowths

    Journal of Materials Chemistry A · 2022-01-01

    Kaustav Chatterjee, Nicolas P. L. Magnard, Jette K. Mathiesen, Kirsten M. Ø. Jensen, Sara E. Skrabalak

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  7. Facile Synthesis of Sillén-Aurivillius Layered Oxide Bi7Fe2Ti2O17Cl with Efficient Photocatalytic Performance for Degradation of Tetracycline

    Catalysts · 2022-02-15

    Yan Gu, Yu Fang, Jikun Chen, Qinfang Zhang

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  8. Lone-Pair-Induced Intra- and Interlayer Polarizations in Sillén-Aurivillius Layered Perovskite Bi4NbO8Br

    Inorganic Chemistry · 2022-06-15

    Chengchao Zhong, Yui Ishii, Cédric Tassel, Tong Zhu, Daichi Kato, Kosuke Kurushima, Yukihiro Fujibayashi, Takashi Kei SAITO, T. Ogawa, Akihide Kuwabara, Shigeo Mori, Hiroshi Kageyama

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  9. Bi12O17Cl2 with a Sextuple BiO Layer Composed of Rock‐Salt and Fluorite Units and its Structural Conversion through Fluorination to Enhance Photocatalytic Activity

    Advanced Functional Materials · 2022-08-02

    Daichi Kato, Osamu Tomita, Ryky Nelson, Maria A. Kirsanova, Richard Dronskowski, Hajime Suzuki, Chengchao Zhong, Cédric Tassel, K. Ishida, Yosuke Matsuzaki, Craig M. Brown, Koji Fujita, Kotaro Fujii, Masatomo Yashima, Yoji Kobayashi, Akinori Saeki, Itaru Oikawa, Hitoshi Takamura, Ryu Abe, Hiroshi Kageyama, Tatiana E. Gorelik, Artem M. Abakumov

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  10. Bi-based layered perovskite oxyhalides: Up-and-coming catalysts for efficient energy harvesting and conversion

    Current Opinion in Green and Sustainable Chemistry · 2022-08-06

    Zijian Zhu, Fang Chen, Na Tian, Yihe Zhang, Hongwei Huang

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  11. Bi 4 TaO 8 Cl as a New Class of Layered Perovskite Oxyhalide Materials for Piezopotential Driven Efficient Seawater Splitting

    Nano Letters · 2022-11-08

    Maqsuma Banoo, Raj Sekhar Roy, Monika Bhakar, Jaspreet Kaur, Aman Jaiswal, Goutam Sheet, Ujjal Kumar Gautam

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  12. A Sillén oxyhalide SrBi 3 O 4 Cl 3 as a promising photocatalyst for water splitting: impact of the asymmetric structure on light absorption and charge carrier dynamics

    Journal of Materials Chemistry A · 2023-01-01

    Hajime Suzuki, Daichi Ozaki, Yusuke Ishii, Osamu Tomita, Daichi Kato, Shunsuke Nozawa, Kouichi Nakashima, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

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  13. Flux-assisted synthesis of tungsten-doped layered perovskite oxychloride with promoted visible-light-responsive O 2 evolution performance

    Chemical Communications · 2023-01-01

    Xiangyao Song, Shiwen Du, Xiangying Xing, Beibei Dong, Zhaochi Feng, Fei Cheng

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  14. Single-Crystalline Bi2YO4Cl with Facet-Aided Photocarrier Separation for Robust Solar Water Splitting

    ACS Catalysis · 2023-03-03

    Jinxing Yu, Shufang Chang, Li Shi, Xiaoxiang Xu

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  15. Synthesis and Structure of the Double-Layered Sillén–Aurivillius Perovskite Oxychloride La2.1Bi2.9Ti2O11Cl as a Potential Photocatalyst for Stable Visible Light Solar Water Splitting

    Inorganic Chemistry · 2023-04-20

    Valérie Werner, Ulrich Aschauer, Günther Josef Redhammer, Jürgen Schoiber, Gregor A. Zickler, Simone Pokrant

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  16. Synthesis of multi-layered perovskite oxyiodides: Impact of number of perovskite layers and type of halide layer for band levels and photocatalytic properties

    Solid State Sciences · 2023-05-25

    Makoto Ogawa, Hajime Suzuki, Kanta Ogawa, Osamu Tomita, Ryu Abe

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  17. Orbital Engineering in Sillén–Aurivillius Phase Bismuth Oxyiodide Photocatalysts through Interlayer Interactions

    Chemistry of Materials · 2023-07-12

    Kanta Ogawa, Hajime Suzuki, Aron Walsh, Ryu Abe

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  18. Coupling of surface oxygen vacancy and 2D structure of Aurivillius-phase CaBi2Ta2O9 nanoplates for enhanced photocatalytic H2 production

    Applied Surface Science · 2023-10-02

    Xiaowei Jia, Ruyu Zhang, Xianchun Liu, Mingliang Sun, Yunfeng Li, Cong Wang, Xiaodan Yu, Yan Xing

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  19. Honeycomb layered frameworks with metallophilic bilayers

    Progress in Materials Science · 2023-10-21

    Godwill Mbiti Kanyolo, Titus N. Masese, Yoshinobu Miyazaki, Shintaro Tachibana, Chengchao Zhong, Yuki Orikasa, Tomohiro Saito

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  20. Theoretical and experimental investigation of the coordination effect on photocatalytic CO2 reduction efficiency of cobalt single atom catalyst

    Chemical Engineering Journal · 2023-12-02

    Qingmei Xu, Yucheng Jin, Tingting Sun, Tianyu Zheng, Pianpian Zhang, Yuesheng Han, Yuhui Wang, Tongxuan Li, Dongdong Qi, Lianbin Xu, Dingsheng S. Wang, Jianzhuang Jiang

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  21. Exploring the potential of perovskite structures for chemical looping technology: A state-of-the-art review

    Fuel Processing Technology · 2023-12-30

    Tenzin Dawa, Baharak Sajjadi

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  22. Advances in the structural engineering of layered bismuth-based semiconductors for visible light-driven photocatalytic water splitting

    Chemical Communications · 2024-01-01

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  23. Band engineering of layered oxyhalide photocatalysts for visible-light water splitting

    Chemical Science · 2024-01-01

    Daichi Kato, Hajime Suzuki, Ryu Abe, Hiroshi Kageyama

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  24. Emerging polynary bismuth-based photocatalysts: Structural classification, preparation, modification and applications

    CHINESE JOURNAL OF CATALYSIS (CHINESE VERSION) · 2024-02-01

    Min Li, Shixin Yu, Hongwei Huang

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  25. Perovskite Oxynitrides and Oxysulfides toward Photocatalytic Green Hydrogen Production: Scalability Prospects

    ACS symposium series · 2024-05-15

    Sumanth Dongre S, R. Shwetharani, R. Geetha Balakrishna

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  26. Tutorial on Describing, Classifying, and Visualizing Common Crystal Structures in Nanoscale Materials Systems

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  27. Perovskite materials for highly efficient Photo(electro)catalytic water splitting: A mini-review

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  28. Environmental application of versatile Bi-based perovskite photocatalysts and their Z-scheme and S-scheme heterojunctions

    Journal of environmental chemical engineering · 2024-06-15

    Artem S. Belousov, Alina A. Parkhacheva, Artyom N. Markov, Anton N. Petukhov, Alexander A. Kapinos, Artem Anatolevich Atlaskin, Sergey S. Suvorov, Andrey Vladimirovich Vorotyntsev

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  29. Synthetically Enforced Cation Migration in Sillén–Aurivillius Hybrid Perovskites Boosts Photocatalytic Hydrogen Evolution

    ACS Applied Energy Materials · 2024-09-11

    Shubham Kumar, Jaideep Malik, Anil Kumar, Parul Yadav, Tapas Kumar Mandal

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  30. Electrostatic Control of Electronic Structure in Modular Inorganic Crystals

    Journal of the American Chemical Society · 2024-12-19

    Kanta Ogawa, Aron Walsh

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  31. Conduction Band and Defect Engineering for the Prominent Visible‐Light Responsive Photocatalysts

    Angewandte Chemie International Edition · 2024-12-23

    Akira Yamakata, Kosaku Kato, T. Ogawa, Kanta Ogawa, Makoto Ogawa, Daichi Kato, Chengchao Zhong, Akihide Kuwabara, Ryu Abe, Hiroshi Kageyama

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  32. Conduction Band and Defect Engineering for the Prominent Visible‐Light Responsive Photocatalysts

    Angewandte Chemie · 2024-12-23

    Akira Yamakata, Kosaku Kato, T. Ogawa, Kanta Ogawa, Makoto Ogawa, Daichi Kato, Chengchao Zhong, Akihide Kuwabara, Ryu Abe, Hiroshi Kageyama

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  33. Recent advances in lead-free carbon supported perovskites based on Z-scheme and S-scheme heterojunctions for photocatalytic energy conversion

    Materials Horizons · 2025-01-01

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  34. Vanadium-based oxyhalide photocatalysts for visible-light-driven Z-scheme water splitting: advancing conduction band engineering

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  35. Structure-tailored superlattice Bi7Ti4NbO21: Coupling octahedral tilting and rotation induced high ferroelectric polarization for efficient piezo-photocatalytic CO2 reduction

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  36. Engineering (001) crystallinity for efficient photocatalytic water splitting in strontium-rich A3X1 Type-Bi4Sr2Ti2NbO14Cl perovskites

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  37. Enhanced Photocatalytic O2 Evolution over Layered Perovskite Oxyiodide Ba2Bi3Nb2O11I through Flux Synthesis and Surface Modifications

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  38. Layered perovskite Bi7Fe2Ti2O17Cl: Universally efficient photo-piezocatalysis and mechanismic insight into the origin of polarity

    Applied Surface Science · 2025-05-28

    Sheng Guo, Na Tian, Fang Chen, Yihe Zhang, Hongwei Huang

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  39. Plasma trap channels accelerate carrier migration in Sillén-Aurivillius perovskite heterojunctions for triple-effect pollutant degradation in recyclable foams

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    ZhanMing Yin, Jixiang Duan, Fengming Wang, Rongli Sang, Yuanliang Li, Zhanshen Zheng

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  40. Hydrogen defects in LaBi 2 O 4 X (X = Cl, Br, and I) Sillén oxyhalide phases and their impacts on ionic transport

    Journal of Materials Chemistry A · 2026-01-01

    S. W. Kang, Andrew J. E. Rowberg, Shenli Zhang, Joel Basile Varley

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  41. Structural origins of photocatalytic properties in Ruddlesden–Popper Sr n +1 Ti n O 3 n +1 ( n = 1, 2) and their topochemically fluorinated phases Sr n +1 Ti n O (3 n +1)− x F 2 x ( x ≈ n )

    Journal of Materials Chemistry A · 2026-01-01

    Shama Perween, Kevin Matthias Ries, Anja Hofmann, Tommi Hendrik Aalto, Harol Moreno Fernández, Marc Widenmeyer, Robert Löser, Jana Timm, Guido Schmitz, Petia P. Atanasova, Jan P. Hofmann, Oliver Clemens, Roland Marschall, Chengchao Zhong

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  42. Synergistic Effect of Ultrasonication-Induced Surface Activation and A-Site Sr/Ba Distribution Unlocks Cocatalyst-Free Hydrogen Evolution in Sillén–Aurivillius Photocatalysts

    ACS Applied Energy Materials · 2026-01-10

    Parul Yadav, Tapas Kumar Mandal

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