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RESEARCH PAPER · Chemical Science · 2024

Band engineering of layered oxyhalide photocatalysts for visible-light water splitting

Daichi Kato, Hajime Suzuki, Ryu Abe, Hiroshi Kageyama

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Band engineering of layered oxyhalide photocatalysts for visible-light water splittingOriginalA surface reconstruction route for increasingly improved photocatalytic H 2 O 2 production using Sr 2 Bi 3 Ta 2 O 11 Cl6Γ-Pga-Dependent Growth of Biobr Nanosheets with Exposed {010} Facets for Enhanced Photocatalytic Rhb Degradation0Rational construction p-n heterojunction Ni(OH)2/NiS2 on g-C3N4 nanosheet to promote the charge carriers separation efficiency for boosting photocatalytic hydrogen evolution14Emergence of Tetragonal Phase and Reentrant Transition in Tensile-Strained Bi2(La1–xBix)O4Cl Solid Solution5Electronic and optical properties of halogen-substituted LaBi 2 Cl 1− y X y O 4 : a promising candidate for energy-efficient devices0Sr-doped LaTiO 2 N photocatalyst for hydrogen evolution reaction synthesized from perovskite-type La–Ti oxide nanoparticles1Structural and electronic tuning of hybrid metal thiocyanate N -oxides0Structural stability and polymorphic transitions in LnSI (Ln = lanthanides)2The mixed-halogen layer approach of band engineering and anisotropic charge migration in X1X2 Sillén nanosheets boost cocatalyst-free photocatalytic hydrogen evolution4Vanadium-based oxyhalide photocatalysts for visible-light-driven Z-scheme water splitting: advancing conduction band engineering0Visible-light H 2 evolution using dye-sensitized TiO 2 : effects of physicochemical properties of TiO 2 on excited carrier dynamics and activity3γ-PGA-dependent growth of BiOBr nanosheets with exposed {010} facets for enhanced photocatalytic RhB degradation16Flux Synthesis of Sillén–Aurivillius Oxyiodide for Visible Light Water Splitting Photocatalysis12In-situ silver (Ag) clusters strengthed spatial separation of photogenerated charge-carriers for efficient photocatalytic tetracycline antibiotic purification22Engineering (001) crystallinity for efficient photocatalytic water splitting in strontium-rich A3X1 Type-Bi4Sr2Ti2NbO14Cl perovskites0Layer Width Engineering in Carbon Nitride for Enhanced Exciton Dissociation and Solar Fuel Generation3Enhanced Photocatalytic O2 Evolution over Layered Perovskite Oxyiodide Ba2Bi3Nb2O11I through Flux Synthesis and Surface Modifications7Interface Engineering between Photocatalyst and Cocatalyst: A Strategy for Enhancing Interfacial Charge Transfer and Water Oxidation of Layered Oxyhalides22In Situ Assembly of Recyclable Polyoxometalate-Derived Photocatalysts for Sustainable Photocatalytic H2 Generation3Layered Perovskite Materials for Photocatalytic Overall Water Splitting: Recent Advances, Enhanced Strategies, and Future Challenges12Tailoring optical and ferroelectric properties in Sb 1− x Bi x SI van der Waals chalcohalides towards solar absorber applications4Mg-based thermoelectric materials and devices: a review4Sculpting Low-Dimensional Hybrid Lead Halides via Pressure-Induced Polymerization8Carbon dot-mediated hydrogen sulfide dynamics: mechanisms, environmental transformations, and sustainable applications0Molten salt-mediated cyano group augmentation and morphology modulation in carbon nitride for boosting photocatalytic activity2Photocorrosion in semiconductor photocatalysts: mechanisms, suppression, and use in functional material design2Structural origins of photocatalytic properties in Ruddlesden–Popper Sr n +1 Ti n O 3 n +1 ( n = 1, 2) and their topochemically fluorinated phases Sr n +1 Ti n O (3 n +1)− x F 2 x ( x ≈ n )3Thermodynamic and Kinetic Descriptors for Photocatalytic Lithium Extraction from Spent LiFePO40Constructing a porous CuO/TiO2 heterojunction catalyst for enhanced photodegradation of dyes in wastewater3Electronic structures, optical properties and reaction mechanism of the Ta3N5/LaTaON2 heterojunction photocatalyst3Band Engineering of Aurivillius Perovskites through Halogen Incorporation for Enhanced Photocatalytic H 2 Production0Directed Substitutional Control Unlocks Intrinsic Water Oxidation and Reduction Activity in an Oxyhalide Photocatalyst1Fabrication of novel praseodymium iron-titanate perovskite composites with different compositions and evaluation of their visible-light photocatalytic activity0Solvent-free synthesis of BiOI films via BiI3 oxidation: structural, optical, and electrical properties toward optoelectronic applications0Solid‐State or Flux‐Assisted Doping of Hydrogen‐Evolving Y 2 Ti 2 O 5 S 2 Photocatalyst With Lower‐Valence Cations1Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Growth and Characterization of Arsenic-Based Polymorphs of Co 2 AsO 4 F: Visible-Light-Induced Photocatalytic Dye Degradation, Electrocatalytic Hydrogen Evolution, and Catalytic Solvent-Free Sustainable Knoevenagel Condensation0Aliovalent Cl Substitution Modulates Oxygen‐Vacancy‐Related Defect States in Bi 2 O 2 S Toward Efficient Photocatalytic CO 2 ‐to‐CO Conversion0Band Gap Narrowing in Oxychlorosulfide Photocatalysts through Aliovalent Cl-to-S Anion Substitution0

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  1. A surface reconstruction route for increasingly improved photocatalytic H 2 O 2 production using Sr 2 Bi 3 Ta 2 O 11 Cl

    Chemical Science · 2024-01-01

    Maqsuma Banoo, Arjun Kumar Sah, Raj Sekhar Roy, Komalpreet Kaur, Bramhaiah Kommula, Dirtha Sanyal, Ujjal Kumar Gautam

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  2. Γ-Pga-Dependent Growth of Biobr Nanosheets with Exposed {010} Facets for Enhanced Photocatalytic Rhb Degradation

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    Meiying Liu, Yaoxiang Li, Jingyuan Liu, Li Wang, Han Wang, Siyi Wang, Bo Wu

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  3. Rational construction p-n heterojunction Ni(OH)2/NiS2 on g-C3N4 nanosheet to promote the charge carriers separation efficiency for boosting photocatalytic hydrogen evolution

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    Jianfa Jia, Guanghui Zhang, Huoli Zhang, Yichen Jiang, Yan Zhang, Mingzhi Shi, Yuanbo Du, Ran Wei, Yichen Ji, Jianliang Cao

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  4. Emergence of Tetragonal Phase and Reentrant Transition in Tensile-Strained Bi2(La1–xBix)O4Cl Solid Solution

    Chemistry of Materials · 2024-12-25

    Artem Gabov, Daichi Kato, Takamasa Tsukamoto, Yosuke Matsuzaki, Naoji Kakudou, Akinori Saeki, Hajime Suzuki, Ryu Abe, Koji Fujita, Smagul Zh. Karazhanov, Hiroshi Kageyama

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  5. Electronic and optical properties of halogen-substituted LaBi 2 Cl 1− y X y O 4 : a promising candidate for energy-efficient devices

    RSC Advances · 2025-01-01

    Dipendra Prasad Kalauni, Kedar Nath Jaiswal, Sarita Lawaju, Krishna Bahadur Rai, Ram Jeewan Yadav, Akkal Dev Mishra, Madhav Prasad Ghimire

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  6. Sr-doped LaTiO 2 N photocatalyst for hydrogen evolution reaction synthesized from perovskite-type La–Ti oxide nanoparticles

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    Mayu Inose, Shuhei Nakakura, Takashi Hisatomi, Kazunari Domen

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  7. Structural and electronic tuning of hybrid metal thiocyanate N -oxides

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  8. Structural stability and polymorphic transitions in LnSI (Ln = lanthanides)

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    Shohei Kawanishi, Suguru Yoshida, Hiroki Ubukata, Congling Yin, Yang Yang, Ryusei Morimoto, Simon J. Clarke, Hiroshi Kageyama

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  9. The mixed-halogen layer approach of band engineering and anisotropic charge migration in X1X2 Sillén nanosheets boost cocatalyst-free photocatalytic hydrogen evolution

    Journal of Materials Chemistry A · 2025-01-01

    Parul Yadav, Tapas Kumar Mandal

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  10. Vanadium-based oxyhalide photocatalysts for visible-light-driven Z-scheme water splitting: advancing conduction band engineering

    Journal of Materials Chemistry A · 2025-01-01

    Hajime Suzuki, Ryuki Tomita, Yusuke Ishii, Osamu Tomita, Akinobu Nakada, Akinori Saeki, Ryu Abe

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  11. Visible-light H 2 evolution using dye-sensitized TiO 2 : effects of physicochemical properties of TiO 2 on excited carrier dynamics and activity

    Journal of Materials Chemistry A · 2025-01-01

    Kakeru Harada, Haruka Yamamoto, Megumi Okazaki, Thomas E. Mallouk, Kazuhiko Maeda

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  12. γ-PGA-dependent growth of BiOBr nanosheets with exposed {010} facets for enhanced photocatalytic RhB degradation

    Applied Surface Science · 2025-01-17

    Yaoxiang Li, Dan Wang, Jingyuan Liu, Li Wang, Han Wang, Han Wang, Bo Wu, Meiying Liu

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  13. Flux Synthesis of Sillén–Aurivillius Oxyiodide for Visible Light Water Splitting Photocatalysis

    Chemistry of Materials · 2025-01-21

    Makoto Ogawa, Hajime Suzuki, Kanta Ogawa, Hiroki Ubukata, Osamu Tomita, Akinobu Nakada, Shunsuke Nozawa, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

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  14. In-situ silver (Ag) clusters strengthed spatial separation of photogenerated charge-carriers for efficient photocatalytic tetracycline antibiotic purification

    Environmental Research · 2025-02-11

    Zhili Chen, Li Huang, Xingmeng Zhou, Yunxiang Zhang, Xin Chen, Chenliang Zhou, Hazem Abdelsalam, Wei Chen, Zhongjie Wang, Qinfang Zhang

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  15. Engineering (001) crystallinity for efficient photocatalytic water splitting in strontium-rich A3X1 Type-Bi4Sr2Ti2NbO14Cl perovskites

    Separation and Purification Technology · 2025-03-04

    Zhongsheng Ge, Sonu Kumar, Sk Abdul Moyez, Lizhuang Dong, Yixi Wang, Hassan Karimi‐Maleh, Udayabhaskararao Thumu

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  16. Layer Width Engineering in Carbon Nitride for Enhanced Exciton Dissociation and Solar Fuel Generation

    ACS Materials Letters · 2025-03-14

    Raj Sekhar Roy, Supriya Sil, Samita Mishra, Maqsuma Banoo, Abhishek Swarnkar, Bramhaiah Kommula, Arijit K. De, Ujjal Kumar Gautam

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  17. Enhanced Photocatalytic O2 Evolution over Layered Perovskite Oxyiodide Ba2Bi3Nb2O11I through Flux Synthesis and Surface Modifications

    Inorganic Chemistry · 2025-04-25

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  18. Interface Engineering between Photocatalyst and Cocatalyst: A Strategy for Enhancing Interfacial Charge Transfer and Water Oxidation of Layered Oxyhalides

    Journal of the American Chemical Society · 2025-06-19

    Hajime Suzuki, Kengo Minamimoto, Yusuke Ishii, Osamu Tomita, Akinobu Nakada, Shunsuke Nozawa, Akira Yamakata, Ryu Abe

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  19. In Situ Assembly of Recyclable Polyoxometalate-Derived Photocatalysts for Sustainable Photocatalytic H2 Generation

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  20. Layered Perovskite Materials for Photocatalytic Overall Water Splitting: Recent Advances, Enhanced Strategies, and Future Challenges

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    Na Li, Chao Cheng, Yilin Wang, Alex W. Robertson, Zhenyu Sun

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  21. Tailoring optical and ferroelectric properties in Sb 1− x Bi x SI van der Waals chalcohalides towards solar absorber applications

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    Sara A. López-Paz, Harish K. Singh, Alba S. J. Méndez, Volodymyr Multian, Jeremie Teyssier, Ulrich Aschauer, Fabian O. von Rohr

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  22. Mg-based thermoelectric materials and devices: a review

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  23. Sculpting Low-Dimensional Hybrid Lead Halides via Pressure-Induced Polymerization

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  24. Carbon dot-mediated hydrogen sulfide dynamics: mechanisms, environmental transformations, and sustainable applications

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  25. Molten salt-mediated cyano group augmentation and morphology modulation in carbon nitride for boosting photocatalytic activity

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  26. Photocorrosion in semiconductor photocatalysts: mechanisms, suppression, and use in functional material design

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  27. Structural origins of photocatalytic properties in Ruddlesden–Popper Sr n +1 Ti n O 3 n +1 ( n = 1, 2) and their topochemically fluorinated phases Sr n +1 Ti n O (3 n +1)− x F 2 x ( x ≈ n )

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  28. Thermodynamic and Kinetic Descriptors for Photocatalytic Lithium Extraction from Spent LiFePO4

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  29. Constructing a porous CuO/TiO2 heterojunction catalyst for enhanced photodegradation of dyes in wastewater

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  30. Electronic structures, optical properties and reaction mechanism of the Ta3N5/LaTaON2 heterojunction photocatalyst

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  31. Band Engineering of Aurivillius Perovskites through Halogen Incorporation for Enhanced Photocatalytic H 2 Production

    ACS Applied Engineering Materials · 2026-03-24

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  32. Directed Substitutional Control Unlocks Intrinsic Water Oxidation and Reduction Activity in an Oxyhalide Photocatalyst

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  33. Fabrication of novel praseodymium iron-titanate perovskite composites with different compositions and evaluation of their visible-light photocatalytic activity

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  34. Solvent-free synthesis of BiOI films via BiI3 oxidation: structural, optical, and electrical properties toward optoelectronic applications

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  35. Solid‐State or Flux‐Assisted Doping of Hydrogen‐Evolving Y 2 Ti 2 O 5 S 2 Photocatalyst With Lower‐Valence Cations

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  37. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

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  38. Growth and Characterization of Arsenic-Based Polymorphs of Co 2 AsO 4 F: Visible-Light-Induced Photocatalytic Dye Degradation, Electrocatalytic Hydrogen Evolution, and Catalytic Solvent-Free Sustainable Knoevenagel Condensation

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  40. Band Gap Narrowing in Oxychlorosulfide Photocatalysts through Aliovalent Cl-to-S Anion Substitution

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