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RESEARCH PAPER · Inorganic Chemistry · 2021

Bi4AO6Cl2 (A = Ba, Sr, Ca) with Double and Triple Fluorite Layers for Visible-Light Water Splitting

Chengchao Zhong, Daichi Kato, Kanta Ogawa, Cédric Tassel, Fujio Izumi, Hajime Suzuki, Shogo Kawaguchi, Takashi Kei SAITO, Akinori Saeki, Ryu Abe, Hiroshi Kageyama

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Bi4AO6Cl2 (A = Ba, Sr, Ca) with Double and Triple Fluorite Layers for Visible-Light Water SplittingOriginalNew Modification of Polar Nonlinear Optical Iodate Fluoride PbF(IO3), the Family MX(IO3), M = Bi, Ba, Pb, X = O, F, (OH) Related to Aurivillius Phases and Similar Iodates3A Sillén oxyhalide SrBi 3 O 4 Cl 3 as a promising photocatalyst for water splitting: impact of the asymmetric structure on light absorption and charge carrier dynamics14Zn3Sb4O6F6 and KI-Doped Zn3Sb4O6F6: A Metal Oxyfluoride System for Photocatalytic Activity, Knoevenagel Condensation, and Bacterial Disinfection21First-Principles Calculations on Narrow-Band Gap d10 Metal Oxides for Photocatalytic H2 Production: Role of Unusual In2+ Cations in Band Engineering13Advances in the structural engineering of layered bismuth-based semiconductors for visible light-driven photocatalytic water splitting34Band engineering of layered oxyhalide photocatalysts for visible-light water splitting42Fluorosulfide La 2.7 Ba 6.3 F 8.7 S 6 with a double-layer honeycomb structure enabling fluoride-ion conduction3Internal strain-driven bond manipulation and band engineering in Bi 2− x Sb x YO 4 Cl photocatalysts with triple fluorite layers7Synthetically Enforced Cation Migration in Sillén–Aurivillius Hybrid Perovskites Boosts Photocatalytic Hydrogen Evolution4Electrostatic Control of Electronic Structure in Modular Inorganic Crystals8The mixed-halogen layer approach of band engineering and anisotropic charge migration in X1X2 Sillén nanosheets boost cocatalyst-free photocatalytic hydrogen evolution4Spontaneous Electric Field Directionality in One-Dimensional Semiconductors: Key to Efficient Charge Migration, Minimizing Recombination, and Enhancing Photocatalytic Performance8d10 Metal s-Orbital-Derived Conduction Band Enables Efficient Charge Separation in LiIn2SbO6: A Combined Band Structure and Molecular Orbital Analysis2Synergistic Effect of Ultrasonication-Induced Surface Activation and A-Site Sr/Ba Distribution Unlocks Cocatalyst-Free Hydrogen Evolution in Sillén–Aurivillius Photocatalysts0Band Engineering of Aurivillius Perovskites through Halogen Incorporation for Enhanced Photocatalytic H 2 Production0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity0

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  1. New Modification of Polar Nonlinear Optical Iodate Fluoride PbF(IO3), the Family MX(IO3), M = Bi, Ba, Pb, X = O, F, (OH) Related to Aurivillius Phases and Similar Iodates

    Symmetry · 2022-12-30

    Elena L. Belokoneva, Olga Reutova, Anatoly S. Volkov, Olga V. Dimitrova, Sergey Yu. Stefanovich

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  2. A Sillén oxyhalide SrBi 3 O 4 Cl 3 as a promising photocatalyst for water splitting: impact of the asymmetric structure on light absorption and charge carrier dynamics

    Journal of Materials Chemistry A · 2023-01-01

    Hajime Suzuki, Daichi Ozaki, Yusuke Ishii, Osamu Tomita, Daichi Kato, Shunsuke Nozawa, Kouichi Nakashima, Akinori Saeki, Hiroshi Kageyama, Ryu Abe

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  3. Zn3Sb4O6F6 and KI-Doped Zn3Sb4O6F6: A Metal Oxyfluoride System for Photocatalytic Activity, Knoevenagel Condensation, and Bacterial Disinfection

    Inorganic Chemistry · 2023-01-04

    Sayantani Paul, Bibaswan Sen, Nilendu Basak, Nirman Chakraborty, Kiron Bhakat, Sangita Das, Ekramul Islam, Swastik Mondal, Sk Jahir Abbas, S. Ali

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  4. First-Principles Calculations on Narrow-Band Gap d10 Metal Oxides for Photocatalytic H2 Production: Role of Unusual In2+ Cations in Band Engineering

    Inorganic Chemistry · 2023-03-28

    Rong Wang, Shiyu Lu, Pengfei Jiang, Guangxiang Lu, Han Zhang, Bi Jia, Yongjiang Di, Yilong Ma, Xiaohui Yang

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  5. Advances in the structural engineering of layered bismuth-based semiconductors for visible light-driven photocatalytic water splitting

    Chemical Communications · 2024-01-01

    Xiaoping Tao, Xiaoyuan Zhou, Rengui Li

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  6. Band engineering of layered oxyhalide photocatalysts for visible-light water splitting

    Chemical Science · 2024-01-01

    Daichi Kato, Hajime Suzuki, Ryu Abe, Hiroshi Kageyama

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  7. Fluorosulfide La 2.7 Ba 6.3 F 8.7 S 6 with a double-layer honeycomb structure enabling fluoride-ion conduction

    Journal of Materials Chemistry A · 2024-01-01

    Shintaro Tachibana, Chengchao Zhong, Takeshi Tojigamori, Hidenori Miki, Toshiyuki Matsunaga, Yuki Orikasa

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  8. Internal strain-driven bond manipulation and band engineering in Bi 2− x Sb x YO 4 Cl photocatalysts with triple fluorite layers

    Chemical Science · 2024-01-01

    Artem Gabov, Daichi Kato, Hiroki Ubukata, Ryotaro Aso, Naoji Kakudou, Koji Fujita, Hajime Suzuki, Osamu Tomita, Akinori Saeki, Ryu Abe, Smagul Zh. Karazhanov, Hiroshi Kageyama

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  9. Synthetically Enforced Cation Migration in Sillén–Aurivillius Hybrid Perovskites Boosts Photocatalytic Hydrogen Evolution

    ACS Applied Energy Materials · 2024-09-11

    Shubham Kumar, Jaideep Malik, Anil Kumar, Parul Yadav, Tapas Kumar Mandal

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  10. Electrostatic Control of Electronic Structure in Modular Inorganic Crystals

    Journal of the American Chemical Society · 2024-12-19

    Kanta Ogawa, Aron Walsh

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  11. The mixed-halogen layer approach of band engineering and anisotropic charge migration in X1X2 Sillén nanosheets boost cocatalyst-free photocatalytic hydrogen evolution

    Journal of Materials Chemistry A · 2025-01-01

    Parul Yadav, Tapas Kumar Mandal

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  12. Spontaneous Electric Field Directionality in One-Dimensional Semiconductors: Key to Efficient Charge Migration, Minimizing Recombination, and Enhancing Photocatalytic Performance

    Chemistry of Materials · 2025-06-24

    Zhi Yang, Guangxiang Lu, Pengfei Jiang, Rihong Cong, Tao Yang

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  13. d10 Metal s-Orbital-Derived Conduction Band Enables Efficient Charge Separation in LiIn2SbO6: A Combined Band Structure and Molecular Orbital Analysis

    ACS Applied Energy Materials · 2025-09-09

    Jinyu Zhang, Guangxiang Lu, Zien Cheng, Rihong Cong, Tao Yang

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  14. Synergistic Effect of Ultrasonication-Induced Surface Activation and A-Site Sr/Ba Distribution Unlocks Cocatalyst-Free Hydrogen Evolution in Sillén–Aurivillius Photocatalysts

    ACS Applied Energy Materials · 2026-01-10

    Parul Yadav, Tapas Kumar Mandal

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  15. Band Engineering of Aurivillius Perovskites through Halogen Incorporation for Enhanced Photocatalytic H 2 Production

    ACS Applied Engineering Materials · 2026-03-24

    Parul Yadav, Tapas Kumar Mandal

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  16. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

    Angewandte Chemie · 2026-07-23

    Daichi Kato, Yosuke Matsuzaki, Kohei Miyazaki, Kousuke Noi, Miwa Murakami, K. Takegoshi, Akihide Kuwabara, Shunsuke Kobayashi, Kei Nakayama, Masashi Taniguchi, Hiroki Ubukata, Yang Zhang, Koji Fujita, Yusuke Nambu, Takashi Saito, Takeshi Abe, Hiroshi Kageyama

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  17. Intergrowth Fluorite Slabs Modulate Interstitial Fluorine to Enhance Fluoride‐Ion Conductivity

    Angewandte Chemie International Edition · 2026-07-24

    Daichi Kato, Yosuke Matsuzaki, Kohei Miyazaki, Kousuke Noi, Miwa Murakami, K. Takegoshi, Akihide Kuwabara, Shunsuke Kobayashi, Kei Nakayama, Masashi Taniguchi, Hiroki Ubukata, Yang Zhang, Koji Fujita, Yusuke Nambu, Takashi Saito, Takeshi Abe, Hiroshi Kageyama

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