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RESEARCH PAPER · Materials Today · 2021

Crystal defect modulation in cathode materials for non-lithium ion batteries: Progress and challenges

Fangyu Xiong, Shuangshuang Tan, Xuhui Yao, Qinyou An, Liqiang Mai

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Crystal defect modulation in cathode materials for non-lithium ion batteries: Progress and challengesOriginalA room-temperature rechargeable dual-plating lithium–aluminium battery3Facile hydrothermal synthesis and enhanced electrochemical properties of a layered NiSiO/RGO nanocomposite with an interesting dandelion-like structure3Binder-free MnO2 as a high rate capability cathode for aqueous magnesium ion battery31Interlayer Engineering of Preintercalated Layered Oxides as Cathode for Emerging Multivalent Metal-ion Batteries: Zinc and Beyond182Iron metal anode for aqueous rechargeable batteries88Zirconium‐Doped Vanadium Oxide and Ammonium Linked Layered Cathode to Construct a Full‐Cell Magnesium‐Ion Battery: A Realization and Structural, Electrochemical Study19Engineering the doping amount of rare earth element erbium in CdWO4: Influence on the electrochemical performance and the application to the electrochemical detection of bisphenol A17Dual redox groups enable organic cathode material with a high capacity for aqueous zinc-organic batteries41Polyaniline nanoarrays/carbon cloth as binder-free and flexible cathode for magnesium ion batteries64Boron-doping-induced defect engineering enables high performance of a graphene cathode for aluminum batteries28Completely suppressed high-voltage phase transition of P2/O3-Na 0.7 Li 0.1 Ni 0.1 Fe 0.2 Mn 0.6 O 2 via Li/Ni co-doping for sodium storage31Low‐strain TiP2O7 with three‐dimensional ion channels as long‐life and high‐rate anode material for Mg‐ion batteries117Anionic Te-Substitution Boosting the Reversible Redox in CuS Nanosheet Cathodes for Magnesium Storage113Synthesis of self-modified black BaTiO3−x nanoparticles and effect of oxygen vacancy for the expansion of piezocatalytic application97Regulation of ferric iron vacancy for Prussian blue analogue cathode to realize high-performance potassium ion storage112Defect engineering in molybdenum-based electrode materials for energy storage166A Vanadium‐Based Fluoroxide Cathode Material for Lithium‐Ion Storage with High Energy Density32Defect‐rich bronze titanium dioxide ultrathin nanosheets supported on carbon nanotubes for enhanced lithium‐ion storages2MnO 2 Polymorphs as Cathode Materials for Rechargeable Ca‐Ion Batteries75Laser-radiated tellurium vacancies enable high-performance telluride molybdenum anode for aqueous zinc-ion batteries57Modification of a Cu Mesh with Nanowires and Magnesiophilic Ag Sites to Induce Uniform Magnesium Deposition30Electrolytes for Multivalent Metal‐Ion Batteries: Current Status and Future Prospect33Accelerated ion/electron transport kinetics and increased active sites via local internal electric fields in heterostructured VO2-carbon cloth for enhanced zinc-ion storage37Theoretical Progress of 2D Six‐Membered‐Ring Inorganic Materials as Anodes for Non‐Lithium‐Ion Batteries16Advances on Defect Engineering of Vanadium‐Based Compounds for High‐Energy Aqueous Zinc–Ion Batteries255Basal Planes Unlocking and Interlayer Engineering Endows Proton Doped-MoO2.8F0.2 with Fast and Stable Magnesium Storage46Effects of Mg-doping on distorted structure and enhanced electrochemical performance of V1-Mg O2 nanorods2Millisecond-induced defect chemistry realizes high-rate fiber-shaped zinc-ion battery as a magnetically soft robot30Mg‐Doped Na4Fe3(PO4)2(P2O7)/C Composite with Enhanced Intercalation Pseudocapacitance for Ultra‐Stable and High‐Rate Sodium‐Ion Storage182Effects of Position and Quantity of the Cyano Group in Organic Electrode Materials on Electrochemical Performance10Vanadium-based cathode materials for rechargeable magnesium batteries28Unexpectedly High Cycling Stability Induced by a High Charge Cut‐Off Voltage of Layered Sodium Oxide Cathodes99Molten-salt assisted synthesis of a high-performance oxide cathode for sodium-ion batteries: Na 0.44 MnO 2 as a case15Ni/Fe Bimetallic Ions Co-Doped Manganese Dioxide Cathode Materials for Aqueous Zinc-Ion Batteries24Efficient boron-based electrolytes constructed by anionic and interfacial co-regulation for rechargeable magnesium batteries41Insights into the oxygen vacancies in transition metal oxides for aqueous Zinc-Ion batteries84Cationic Co-doping in copper sulfide nanosheet cathodes for efficient magnesium storage41Stable zinc metal anode with an ultrathin carbon coating for zinc-ion batteries46Confined Assembly of Hydrated Vanadium Oxide into Hollow Mesoporous Carbon Nanospheres for Fast and Stable K + Storage Capability6Doping FePSe3 with Mg and Ca ions: A Density Functional Theory Study1Multiple defects engineering on VO2(B) nanorods by Fe3+ substitution with enhanced electrochemical performance17Technological penetration and carbon-neutral evaluation of rechargeable battery systems for large-scale energy storage39Application of nanomaterials with sulfur vacancy for enhanced cancer theranostics3Hydrogen, Ammonia and Symbiotic/Smart Fertilizer Production Using Renewable Feedstock and CO2 Utilization through Catalytic Processes and Nonthermal Plasma with Novel Catalysts and In Situ Reactive Separation: A Roadmap for Sustainable and Innovation-Based Technology26Cation-Vacancy Modulated 2D Manganese Oxide Nanobelts for High-Performance Aqueous Zinc-Ion Storage18Tailored design the redox chemistry and microstructures of bronze-type VO2(B) via Co/Zn doping towards enhanced sodium storage5Current Challenges and Advanced Design Strategy of Vanadium Dioxide Cathode for Low‐Cost Aqueous Zinc Metal Battery18Facile construction of ZnWO4/ZnO porous nanoplates on reduced graphene oxide for superior lithium storage8Ammonium intercalation engineering regulated structural stability of V6O13 cathodes for durable zinc ion batteries58Design of an effective air electrode using highly porous carbon‐aerogel on carbon cloth for oxygen intake toward improved reaction kinetics of aluminum‐air battery13Enhanced Electrochemical Performance of Ca-Doped Na3V2(PO4)2F3/C Cathode Materials for Sodium-Ion Batteries32A review of metal sulfide cathode materials for non-aqueous multivalent ion (Mg2+, Ca2+, Al3+) batteries19Nanocomposite of Nb-based binary phase for lowering the activation energy of Li + intercalation as an anode for high-performance aqueous dual-ion batteries5Multifunctional Silane Additive Enhances Inorganic–Organic Compatibility with F‐rich Nature of Interphase to Support High‐Voltage LiNi0.5Mn1.5O4//graphite Pouch Cells24Transition metal oxides and transition metal sulfides as cathodes for magnesium-ion batteries: current status and modification strategies34Understanding the synergistic improving adsorbed and catalytic activity of polysulfide by design of oxygen vacancies and Li+ lithiation/delithiation behavior in Titanium Oxide separator6In situ construction of ultra-stable zincophilic sodium alginate artificial interface layer for dendrite-free anode in aqueous zinc-ion batteries35Vanadium‐Based Cathodes Modification via Defect Engineering: Strategies to Support the Leap from Lab to Commercialization of Aqueous Zinc‐Ion Batteries119Hollow Core‐Shelled Na 4 Fe 2.4 Ni 0.6 (PO 4 ) 2 P 2 O 7 with Tiny‐Void Space Capable Fast‐Charge and Low‐Temperature Sodium Storage119Hollow Core‐Shelled Na4Fe2.4Ni0.6(PO4)2P2O7 with Tiny‐Void Space Capable Fast‐Charge and Low‐Temperature Sodium Storage7Layered Cathode with Ultralow Strain Empowers Rapid‐Charging and Slow‐Discharging Capability in Sodium Ion Battery27Topotactic Syntopogenous Sodium Vanadium Fluoride for High-Performance Sodium-Ion Batteries: Electron and Sodium-Ion Reservoirs in Perovskite/Diperovskite Superlattice23Non-Ti MXene: An emerging class of 2D materials for non-Li batteries28Enhanced sunlight-driven photocatalysis of non-metal doped zinc oxide via wet impregnation for the removal of organic compounds10Rational design of 2D blue phosphorene/Ti2BT2 (T=Se, Te) heterostructures as high-performance anode materials for alkali-metal ion batteries: A first principles study6Doping enhanced charge transportation in NASICONs for energy storage16Mitigating Jahn–Teller effect of MnO2 via charge regulation of Mn-local environment for advanced calcium storage24Design and preparation of carbon-coated NaZnFe(MoO4)3 composite as novel anode materials for lithium/sodium-ion batteries4Defect Engineering: Can it Mitigate Strong Coulomb Effect of Mg2+ in Cathode Materials for Rechargeable Magnesium Batteries?43Challenges and Modification Strategies on High‐Voltage Layered Oxide Cathode for Sodium‐Ion Batteries8Defect Chemistry in High‐Voltage Cathode Materials for Lithium‐Ion Batteries40Copper-induced lattice distortion in Na4Fe3(PO4)2(P2O7) cathode enabling high power density Na-ion batteries with good cycling stability70Grid‐Like Structured Sb@DNC Anode by Self‐Sacrificial Etching for Fast and Durable Sodium Storage7Aqueous “rocking-chair” Mn-ion battery based on an industrial pigment anode30Chelator optimization enabled defect engineering for cation disordered rocksalt cathodes via solution-based synthesis method7Coordination Environment Regulation of Na4Fe3(PO4)2P2O7 via Entropy Engineering for Fast-Charging and Durable Sodium-Ion Full Batteries0Superionic conduit of alkaline earth metals confined by two-dimensional boron–carbon layers13Activating fast and reversible sodium storage in NASICON cationic defect sites through fluorine doping27Developing inorganic-rich interphases through single-solvent siloxane electrolytes with weak solvation characteristics for high-voltage Ni-rich batteries16Modifying anionic sites for Fe spin activation to enhance performance in NASICON cathodes13Mixed ionic-electronic conduit of Ca2+ confined by two-dimensional multicomponent boron-carbon layers4Recent status and future prospects of emerging oxygen vacancy-/defect-rich electrode materials: from creation mechanisms to detection/quantification techniques, and their electrochemical performance for rechargeable batteries3Phase Purification and Crystallology Engineering Enable Fast‐Charging Na 5 Fe 2.9 Ni 0.1 (PO 4 ) 2 (P 2 O 7 ) Cathode for Wide‐Temperature Sodium‐Ion Batteries6Remodeling Interfacial Electrical Field for Superhigh Capacity and Ultralong Lifespan Aqueous Zinc‐Ion Batteries30Helical carbon nanofibers-enhanced nickel silicate: An innovative anode material for high-performance lithium-ion batteries7Fast-charging Na4Fe3(PO4)2P2O7 cathode for sodium-ion batteries3Research Progress on Synthesis Methods and Electrochemical Properties of Spinel‐Structured Lithium Nickel Manganese Oxide0Regulating the Microstructure of the Layered Oxide Cathode through the Annealing Process for High-Performance Potassium-Ion Batteries3Synthesis and investigation of zinc-based Ca-doped ferrites composite for high-performance energy storage hybrid devices7Phase engineering of copper sulfide via selenium doping for high-performance aqueous zinc ion batteries1Boosting supercapacitor efficiency with δ-MnO2 nanoflakes on electrochemically exfoliated graphene nanosheets7Development of high-performance asymmetric supercapacitors based on MXene and Mn-doped Zn ferrite composites for energy storage applications2Fe/Zn co-doped MnO 2 nanoflowers for high-performance aqueous zinc-ion batteries1Structure Engineering of Na 4 Fe 3 (PO 4 ) 2 P 2 O 7 via W-doping Enhanced Cycling Stability and Rate Performance for Sodium-Ion Batteries3Ion-Defective High-Entropy NASICON Cathode Enabled by Multicomponent Substitution for Long-Life and Wide-Temperature Workability1An orbital-coupling-driven bifunctional prelithiation additive for enhanced practical Li-ion full cells0Transition metal doping enhances pseudocapacitive energy storage in monoclinic molybdenum dioxide0Unlocking Fast-Charging and Durable Sodium-Ion Full Batteries via Entropy-Driven Coordination Regulation of Na 4 Fe 3 (PO 4 ) 2 P 2 O 76Oxygen Vacancies in Low‐Positive Thermal Expansion Al 2 W 3 O 12 ‐Based Electrodes for Lithium‐Ion Batteries2An efficient Mo-doped VS2 cathode material for rechargeable magnesium batteries1Tailoring electrochemical kinetics in Mg-ion batteries using defect-rich Mg-doped iron vanadium oxide as cathode material0Unraveling Water–Defect Coupled Degradation via Deuterium Isotope Labeling in Prussian Blue Analogue Cathodes for Long‐Life Sodium‐Ion Batteries1Unraveling Water–Defect Coupled Degradation via Deuterium Isotope Labeling in Prussian Blue Analogue Cathodes for Long‐Life Sodium‐Ion Batteries1Stabilizing zinc-ion battery systems: Cathode materials, recent trends and future directions0Suppression of Jahn-Teller Distortion by Cyanide Vacancies in Mn-Based Prussian Blue Analog Cathodes: A Symmetry-Breaking Mechanism0Utility-scale non-lithium-ion battery energy storage systems: A comprehensive review, performance comparison, and path forward0Critical advances in charge separation regulation for photocatalytic CO2 reduction0Bismuth chloride additive regulated anode interphase and kinetics in manganese-ion batteries0The Effect of Oxygen Vacancies on Surface and Bulk Charge Storage in La0.5Sr0.5FeO3−δ0

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  46. Tailored design the redox chemistry and microstructures of bronze-type VO2(B) via Co/Zn doping towards enhanced sodium storage

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  48. Facile construction of ZnWO4/ZnO porous nanoplates on reduced graphene oxide for superior lithium storage

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  49. Ammonium intercalation engineering regulated structural stability of V6O13 cathodes for durable zinc ion batteries

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    Ziang Wu, Jia Yao, Chi Chen, Xiang Chen, Xiaoxin Pan, Junjie Zheng, Yi Gan, Jingying Li, Xingtai Liu, Chao Xia, Lin Lv, Hao Wang, Houzhao Wan

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  50. Design of an effective air electrode using highly porous carbon‐aerogel on carbon cloth for oxygen intake toward improved reaction kinetics of aluminum‐air battery

    Energy Storage · 2023-12-19

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