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RESEARCH PAPER · eScience · 2022

Defect engineering in molybdenum-based electrode materials for energy storage

Weixiao Wang, Fangyu Xiong, Shaohua Zhu, Jinghui Chen, Jun Lin Xie, Qinyou An

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Defect engineering in molybdenum-based electrode materials for energy storageOriginalA multifunctional cathode sodiation additive for high-performance sodium-ion batteries23From crystalline to amorphous: heterostructure design of MoO 2 /MoS 2 in situ supported by nitrogen-doped carbon with robust sodium storage at −40 °C10Homogenization of electric field distribution facilitating the Zn anode reversibility17A self-assembled nanoflower-like Ni 5 P 4 @NiSe 2 heterostructure with hierarchical pores triggering high-efficiency electrocatalysis for Li–O 2 batteries20Cs‐Induced Phase Transformation of Vanadium Oxide for High‐Performance Zinc‐Ion Batteries24Effect of a lattice distortion strategy on the phase transition and properties in KNN‐based ceramics19Surface reconstruction-derived heterostructures for electrochemical water splitting170Iron‐Based Nanocatalysts for Electrochemical Nitrate Reduction166Porous spheres consisting of Li4Ti5O12 nanocrystals prepared through spray drying and their application as anodes for lithium-ion batteries5A Unique, Porous C3N4 Nanotube for Electrochemiluminescence with High Emission Intensity and Long-Term Stability: The Role of Calcination Atmosphere9Studying Performance and Kinetic Differences between Various Anode Electrodes in Proton Exchange Membrane Water Electrolysis Cell18Superhydrophilic molybdenum phosphide quantum dots on porous carbon matrix for boosting hydrogen evolution reaction68Three-Dimensional Macroporous TiO2-MXene Nanostructure-Based Films for Flexible Freestanding Sulfur Cathodes12Electron donor–acceptor (D-A) tuning to achieve soluble covalent organic polymers for optoelectronic devices45Applications of MXenes in human-like sensors and actuators57Strain Regulating and Kinetics Accelerating of Micro‐Sized Silicon Anodes via Dual‐Size Hollow Graphitic Carbons Conductive Additives18A flexible solid-state lithium battery with silver nanowire/lithium composite anode and V2O5 nanowires based cathode10Single crystal H-Nb 2 O 5 growing along the [001] crystal direction for ultrafast lithium storage22Cr/S co-doped carbon nanofibers via electrospinning for high-performance Li/Na ion batteries4Rational design of carbon-based electrocatalysts for enhancing redox reactions in rechargeable metal batteries19Cu 3 (OH) 2 V 2 O 7 ·2H 2 O@rGO with bimetallic redox activity as a novel cathode material for calcium–ion batteries7Electronic structure manipulation of MoSe 2 nanosheets with fast reaction kinetics toward long-life sodium-ion half/full batteries29In situ solvothermal reduction engineering enables delicate control over surface-rich oxygen vacancies on Bi 2 WO 6 for highly efficient photocatalytic CO 2 reduction19Magnetoelectric synergy strategy for superior iron disulfide anode3Synergy of oxygen defects and structural modulation on titanium niobium oxide with a constructed conductive network for high-rate lithium-ion half/full batteries13Tailoring of Transition Metal Chalcogenides with Different Dimensions and Applications in Fuel Cells0Uncovering the origin of the anomalously high capacity of a 3d anode via in situ magnetometry12Engineering sulfur vacancies on Mo-doped nickel sulfide for enhanced electrochemical energy storage32MoS2 encapsulated in N-doped mesoporous carbon nanowires as high-rate anode for K-ion capacitors5Recent Progress and Perspectives of Solid State Na-CO2 Batteries16Ni/Fe Bimetallic Ions Co-Doped Manganese Dioxide Cathode Materials for Aqueous Zinc-Ion Batteries24The versatile family of molybdenum oxides: synthesis, properties, and recent applications31Oriented tuning yolk-shell structure for well-confinement and constructing durability of silicon/carbon composite18On the bramble way to Mg metal anodes in secondary Mg ion batteries22High‐Performance Aqueous Zn 2+ /Al 3+ Electrochromic Batteries based on Niobium Tungsten Oxides66Sn‐doped induced stable 1T‐WSe 2 nanosheets entrenched on N‐doped carbon with extraordinary half/full sodium/potassium storage performance37The challenges and perspectives of developing solid-state electrolytes for rechargeable multivalent battery38A critical review of vanadium-based electrode materials for rechargeable magnesium batteries45A Composite of Nb2O5 and MoO2 as a High‐Capacity High‐Rate Anode Material for Lithium‐Ion Batteries6The construction of defect-rich CoP@CoP@(Co/Ni)2P triple-shell hollow nanospheres with boosted electrocatalytic hydrogen evolution performances over a wide pH range44Moiré Superlattice Structure in Two‐Dimensional Catalysts: Synthesis, Property and Activity23Flowers Like α-MoO3/CNTs/PANI Nanocomposites as Anode Materials for High-Performance Lithium Storage21Facile synthesis of the Mn3O4 polyhedron grown on N-doped honeycomb carbon as high-performance negative material for lithium-ion batteries16Mg2+ Ion Pre‐Insertion Boosting Reaction Kinetics and Structural Stability of Ammonium Vanadates for High‐Performance Aqueous Zinc‐Ion Batteries34Ultra-high-performance aluminum-based hybrid supercapacitors prepared for nitrogen-doped micro-mesoporous carbon sphere17Semi-ionic C-F bond inducing fast ion storage and electron transfer in carbon anode for potassium-ion batteries19Van der Waals Forces between S and P Ions at the CoP‐C@MoS2/C Heterointerface with Enhanced Lithium/Sodium Storage79Defect engineering of MoS2-based materials as supercapacitors electrode: A mini review54A high‐capacity dual‐ion full battery based on nitrogen‐doped carbon nanosphere anode and concentrated electrolyte45Copper Tetraselenophosphate Cathode for Rechargeable Magnesium Batteries: A Redox-Active Polyatomic Anion Strategy to Design the Cathode Material19Enabling Ultrafast Single Mg 2+ Insertion Kinetics of Magnesium-Ion Batteries via In Situ Dynamic Catalysis and Re-equilibration Effects14Nitrogen doping induced by intrinsic defects of recycled polyethylene terephthalate‐derived carbon nanotubes62An Amorphous Molybdenum Polysulfide Cathode for Rechargeable Magnesium Batteries15Dissolution Mechanism of Eutectic and Hypereutectic Mg–Sn Alloy Anodes for Magnesium Rechargeable Batteries6Understanding the influence of crystal packing density on electrochemical energy storage materials93Covalently Functionalized MoS2 Initiated Gelation of Hydrogels for Flexible Strain Sensing11Sustainable circular biorefinery approach for novel building blocks and bioenergy production from algae using microbial fuel cell33Phosphorus and Nitrogen Codoped Carbon Nanoparticles as Both Anode and Cathode Materials with Enhanced Li+/PF6– Storage for High Energy Density Lithium-Ion Capacitors11Cathode materials for calcium‐ion batteries: Current status and prospects68Electronic modulation induced by decorating single-atomic Fe-Co pairs with Fe-Co alloy clusters toward enhanced ORR/OER activity136Carbonized Polymer Dots for Controlling Construction of MoS2 Flower‐Like Nanospheres to Achieve High‐Performance Li/Na Storage Devices41Modulating p‐d orbital hybridization by CuO/Cu nanoparticles enables carbon nanofibers high cycling stability as anode for sodium storage31Two birds, one stone: Deep eutectic solvent (DES) modified graphite felt electrode significantly improves performance of DES-electrolyte non-aqueous flow battery6Insight into the Effect of Cu2+ Doping on CuxNb2–xO5–3/2x for High-Power Lithium-Ion Batteries18K 3 v 2 (Po 4 ) 3 /C as a New High‐Voltage Cathode Material for Calcium‐Ion Batteries with a Water‐In‐Salt Electrolyte21Recent progress on metal-organic framework derived carbon and their composites as anode materials for potassium-ion batteries59Zinc‐Ion and Proton as Joint Charge Carriers of S‐MoO 2 for High‐Capacity Aqueous Zinc‐Ion Batteries35TiO2-Coated MoO3 Nanorods for Lithium/Sodium-Ion Storage19Electrospun TiO2/V3S4/Carbon Nanotube Composite Nanofibers as Anodes for Lithium-Ion Batteries with Enhanced Cycling Performance13Defect-rich hollow double-shell bimetallic phosphides for electrocatalytic hydrogen evolution over a wide pH range2Development of Carbon Nanotube-Supported Metal (Mo, Ga, Bi)-Doped Polyacrylic Acid Electrodes for Supercapacitor Applications2“Triple-synergistic effect” of K+ and PANI co-intercalation enabling the high-rate capability and stability of V2O5 for aqueous zinc-ion batteries39Elastic MXene conductive layers and electrolyte engineering enable robust potassium storage10Regulating d 0 transition metals and facilitating high-performance Li-excess cation-disordered rock salt cathode materials18Selenium doping induced phase transformation and interlayer expansion boost the zinc storage performance of molybdenum disulfide26Structural and vacancy assisted engineering of cobalt selenide for ultrahigh energy density sodium ion pouch cell10Te doped 1T/2H-MoSe 2 nanosheets with rich defects as advanced anode materials for high-rate sodium ion half/full batteries28Two-dimensional carbon/boron nitrides: modification, machine learning and beyond9Research progress of alkaline earth metal iron-based oxides as anodes for lithium-ion batteries14Environmentally and economical method for Na2Fe(SO4)2 with a broken, hollow cuboid structure as high performance sodium battery electrode25Revolutionizing energy storage: A critical appraisal of MXene-based composites for material designing and efficient performance28Molecular dynamics simulations in hydrogel research and its applications in energy utilization: A review34Multi-dimensional engineering of transition metal dichalcogenides for enhanced performance in fuel cell technologies13Development of an ultra-thin electrode for the oxygen evolution reaction in proton exchange membrane water electrolyzers32Nb-doping of cation-disordered rocksalt oxides with B2O3 surface modification for superior performance cathode7First‐Principles Studies on Transition Metal Doped Mo2B2 as Anode Material for Li‐Ion Batteries12Selectively etched inhomogeneous metal-organic framework-derived CoS/N-codoped hierarchical hollow carbon for long-cycling lithium sulfur batteries21Defective state regulation of Ru-doped Nb2O5 boosts fast lithium storage13Exploring the potential Ru-based catalysts for commercial-scale polymer electrolyte membrane water electrolysis: A systematic review88Improving discharge voltage and ion storage dynamic in polyaniline via modulation of carrier charge density for magnesium-metal batteries15Synergistic Effects of Confinement Structure and Local‐Expanded Interlayer Spacing in Fe2Mo3O8@C@MoS2 Toward High‐Efficient Sodium Ion Storage51Mechanism and enhanced performance of low-dose low-valence molybdenum-doped Na3V2(PO4)2F2O cathodes for sodium batteries9Recent Development of Phosphate Based Polyanion Cathode Materials for Sodium‐Ion Batteries155Superlong cycle-life sodium-ion batteries supported by electrode/active material interaction and heteroatom doping: Mechanism and application12Low-resistivity molybdenum-carbide thin films formed by thermal atomic layer deposition with pressure-assisted decomposition reaction0Trivalent Cation Defect Optimization Spin State of Nickel(II) in NiFe-Layered Double Hydroxide Nanosheets for Oxygen Evolution20Understanding the Role of Oxygen Vacancy Defects in Iridium‐Leveraged MOFs‐Type Catalyst34Hierarchical Co Ni layered double hydroxide nanosheets enwrapped CuO nanorods by electrodeposition for excellent energy storage devices7Recent advances of oxygen vacancies in MoO3: preparation and roles85Recent progress in organosulfur cathode materials containing heteroatoms1Direct kinetic loss analysis with hierarchy configuration of catalyst coated membrane in proton exchange membrane water electrolysis cell12Tuning the Electronic Structures of Mo-Based Sulfides/Selenides with Biomass-Derived Carbon for Hydrogen Evolution Reaction and Sodium-Ion Batteries11Low-crystalline 1T/2H-MoSe2 heterostructure as the high-rate and ultra-long-lifespan cathode materials for magnesium ion batteries14FeSex-SnSe/C nanofibers decorated with selenium-doped carbon nanosheets as advanced anode materials for lithium/potassium ion batteries5Improvement of OER kinetics of calcium zirconate by molybdenum doping method in basic media25Inducing amorphous domains by P-doping to improve the Li-ion storage capacity of Nb2O5 anode10Amorphous mesoporous sulfur-rich 1T/2H-MoS2 nanospheres as high-capacity cathode materials for advanced magnesium ion batteries6Optimized few-layer MoS2 confined in carbon bowls via pore filling and chemical bond enabling fast kinetics for high-rate potassium storage12Alloying Strategy Regulating Size and Electronic Structure of Mo 0.25 Nb 0.75 Se 2 to Achieve High‐Performance Lithium−Sulfur Batteries30Alloying Strategy Regulating Size and Electronic Structure of Mo 0.25 Nb 0.75 Se 2 to Achieve High‐Performance Lithium−Sulfur Batteries2Modification strategies on nickel-based electrocatalysts for energy-efficient anodic reactions10Enhanced interfacial solar desalination using nano-engineered MoO x photothermal evaporators3Exploring layered nanocomposite of MoS 2 and rGO as a highly efficient supercapattery and OER electrocatalyst15Pt cluster catalysts on N-doped carbon for an efficient formic acid oxidation reaction0Tailoring a multilayer fine-grained solid electrolyte interphase by pulse electrochemical activation maneuver for stable Si/C anodes41Zinc-ion batteries: Drawbacks, opportunities, and optimization performance for sustainable energy storage35Modulating oxygen reduction reaction activity in nitrogen-doped porous carbon via Al-N-C incorporation for enhanced performance in liquid and solid-state Zn-air batteries3Tailoring Urchin‐Like Nb2O5 Nanostructures with Molybdenum Doping to Enhance Adsorption Efficiency and Selectivity toward Cationic Dyes in Wastewater Treatment17Doping Engineering of Sodium Vanadium Fluorophosphates Cathodes for Sodium-Ion Batteries9Advances on Defect Engineering of Niobium Pentoxide for Electrochemical Energy Storage20Nanocrystal-in-glass Prussian blue thin films for quasi-solid-state electrochromic devices with long-term stability6High Energy Quasi‐Solid‐State Supercapacitors Totally Derived from Alginate Hydrogel13Biomass‐Derived Stress‐Regulating Additives for Microsilicon Anodes in Lithium‐Ion Batteries4Introducing 3s/p-3p orbital hybridization to stabilize and activate Ni3S4 for efficient hydroxyl ion storage11Interface Optimization Between Porous Transport Layer and Catalyst Layer in Proton Exchange Membrane Water Electrolyzers19Confining PMo12 in flexible nanocages for enhanced electrochemical energy storage1Investigating enhanced OER activity through novel MnMoSe2/ppy composite material in alkaline medium5Hydrogenated Diamond‐Like Carbon ( HDLC ) as Energy Storage Nanomaterials: A Review3Hydrothermal fabrication of BaNiS2 modified with Mo doping as an effective electrocatalyst for OER8Defect engineering of Y2Ti2O5S2 two-dimensional material for broadband ultrafast lasers2Self‐Adapting Lattice Respiration Enabled by Crystal Design and d ‐ p Orbital Hybridization Toward Highly Stable Rechargeable Aluminum Batteries9Self‐Adapting Lattice Respiration Enabled by Crystal Design and d‐p Orbital Hybridization Toward Highly Stable Rechargeable Aluminum Batteries1Revealing the Catalysis Modes for Sulfur Conversion Kinetics in Molten Salt Aluminum‐Sulfur Batteries10Defect-Rich g-C 3 N 4 Nanosheets Catalyze PEO-Based Electrolytes to Create Fluorine-Rich Interfaces for High-Rate All-Solid-State Lithium-Metal Batteries11Progress and challenges in metal oxide-based flexible Li-ion batteries for robust and wearable applications8Controlled Synthesis of Fe3N Sandwiched in Nitrogen-Doped Multilayer Graphene as an Anode Material for Lithium-Ion Batteries9Gadolinium doped ZnS particles as electrode material for supercapacitor application4Embracing the Transition from Conventional Energy to Nonconventional Energy for a Better Future and Sustainability: Innovative Energy Storage Materials1Enhanced Sodium Polysulfide Adsorption by In Situ Construction of NiS 2 /Cu 2 S Heterointerfaces and Sulfur Vacancies Enabling High‐Performance Sodium Storage2Advances in bifunctional electrocatalysts for efficient electrochemical water splitting: Strategies, mechanisms, and applications20Precise Regulation of Zn, S Dual Vacancies in Zn 3 In 2 S 6 Inducing Local Orientated Electrical Field for Photocatalytic H 2 O 2 Generation20Precise Regulation of Zn, S Dual Vacancies in Zn 3 In 2 S 6 Inducing Local Orientated Electrical Field for Photocatalytic H 2 O 2 Generation4Magnetic Susceptibility of High-Purity Molybdenum: Role of Trace Impurities and Theoretical Modeling1Activating Mo2C for methane-to-methanol electrocatalysis through active site formation via dual-metal doping3Eutectic salt-assisted preparation of pine wood-based N,O doped self-supported carbon electrodes for high-performance supercapacitors8High mass loading of flower cluster cobalt iron bimetallic hydroxides for high-performance asymmetric supercapacitors3Enhanced electrochemical performance of ammonium phosphomolybdate for symmetric and asymmetric supercapacitors in an H 2 SO 4 /KI redox additive electrolyte1Covalent organic frameworks for solar- and electricity-driven biomass valorization7Synergistical defect effects and hydrogen bond of carbon nanotubes improving electrochemical performance of PEO‐based lithium metal batteries4Potassium storage in 2D layered TMD anode: Unraveling structure-performance correlations via rational microstructure design1

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  36. Sn‐doped induced stable 1T‐WSe 2 nanosheets entrenched on N‐doped carbon with extraordinary half/full sodium/potassium storage performance

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