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RESEARCH ARTICLE · Chemistry of Materials · 2020

Tuning between Proper and Hybrid-Improper Mechanisms for Polar Behavior in Cs Ln 2Ti2NbO10 Dion-Jacobson Phases

Vanessa A. Cascos, Jennifer Roberts-Watts, Chloe Skingle, Igor Levin, Weiguo Zhang, P. Shiv Halasyamani, Martin Christopher. Stennett, Neil Christian Hyatt, Éric Bousquet, Emma E. McCabe

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Tuning between Proper and Hybrid-Improper Mechanisms for Polar Behavior in Cs Ln 2Ti2NbO10 Dion-Jacobson PhasesOriginalThe influence of the 6s 2 configuration of Bi 3+ on the structures of A′BiNb 2 O 7 (A′ = Rb, Na, Li) layered perovskite oxides10Perovskite-derived structure modulation in the iron sulfate family0Designing new polar materials1Hybrid Improper Ferroelectricity: A Theoretical, Computational, and Synthetic Perspective45Local atomic structure distortions in the Dion-Jacobson ferroelectric CsBiNb2O71Synthesis, crystal structure and photocatalytic activity of new Dion-Jacobson type titanoniobates18Syntheses, structures, and optical properties of n = 3 layered Dion–Jacobson perovskites, RbEu2-Bi Ti2NbO10 (0 ≤ x ≤ 2)1Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases42Hydrogen generation ability of B-site substituted two-dimensional Can-1Tin-3Nb3O3n+1− perovskite nanosheets in photoelectrochemical cell4Second Harmonic Generation in the Polar A′SmNb2O7 (A′ = Rb, Cs) Dion–Jacobson Layered Perovskites11Chemical Trends of Surface Reconstruction and Band Positions of Nonmetallic Perovskite Oxides from First Principles19Basic and advanced spectrometric methods for complete nanoparticles characterization in bio/eco systems: current status and future prospects29Geometrical Designing of a Soft‐Layered Halide Perovskite Improper Photoferroelectric for Boosted Photostriction12Competing polar and antipolar phases in n=2 Ruddlesden-Popper niobates and tantalates from first principles6Structural chemistry of the n = 3 Dion–Jacobson phases: controlling polarity and band gap3Investigation of energy storage in 2D Dion-Jacobson type materials using promised DFT + U approach4Structural Phase Transitions in Layered Perovskite CsFeF4${\rm CsFeF}_{4}$ and Weak Polar Response in CsFeF4${\rm CsFeF}_{4}$/RbFeF4${\rm RbFeF}_{4}$ Superlattice0Synthesis, crystal structure and high-temperature investigation of new Dion-Jacobson type titanoniobates0Atomic-Scale Visualization of Competing Polar Orders in Dion–Jacobson Layered Perovskites2Unexpected Structural Complexity in Pseudo-Ruddlesden–Popper Phases02D dielectrics and ferroelectrics: emerging materials, physics and design principles0Microwave-Assisted Synthesis of (C12H25NH3)2MCl4 Hybrid Perovskites (M: Zn, Cu, and Mn): Metal-Ion Effects on Structural and Thermal Properties0

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  1. The influence of the 6s 2 configuration of Bi 3+ on the structures of A′BiNb 2 O 7 (A′ = Rb, Na, Li) layered perovskite oxides

    Dalton Transactions · 2021

    Subhadip Mallick, Guru Khalsa, Jeffrey Z. Kaaret, Weiguo Zhang, Maria Batuk, Alexandra S. Gibbs, Joke Hadermann, P. Shiv Halasyamani, Nicole A. Benedek, Michael A. Hayward

    Read original paper ↗ ·

  2. Perovskite-derived structure modulation in the iron sulfate family

    Chemical Communications · 2022

    Yuanqi Lan, Yan Qi, Xinyuan Zhang, Wenjiao Yao, Chenchen Wang, Chun‐Sing Lee, Philip Lightfoot, Yongbing Tang

    Read original paper ↗ ·

  3. Designing new polar materials

    Elsevier eBooks · 2022

    Emma E. McCabe

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  4. Hybrid Improper Ferroelectricity: A Theoretical, Computational, and Synthetic Perspective

    Annual Review of Materials Research · 2022

    Nicole A. Benedek, Michael A. Hayward

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  5. Local atomic structure distortions in the Dion-Jacobson ferroelectric CsBiNb2O7

    Physical review. B./Physical review. B · 2022

    Jing Kong, Sanjeev K. Nayak, Jue Liu, S. P. Alpay, Abhijit Pramanick

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  6. Synthesis, crystal structure and photocatalytic activity of new Dion-Jacobson type titanoniobates

    Journal of Solid State Chemistry · 2022

    О. В. Крашенинникова, E.V. Syrov, S. M. Smirnov, Evgeny V. Suleimanov, Diana Georgievna Fukina, Alexander Vladimirovich Knyazev, Dmitry N. Titaev

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  7. Syntheses, structures, and optical properties of n = 3 layered Dion–Jacobson perovskites, RbEu2-Bi Ti2NbO10 (0 ≤ x ≤ 2)

    Journal of Alloys and Compounds · 2022

    Jin Kyu Kim, Kang Min Ok

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  8. Recent developments in oxide ion conductors: focusing on Dion–Jacobson phases

    Chemical Communications · 2022

    Wenrui Zhang, Masatomo Yashima

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  9. Hydrogen generation ability of B-site substituted two-dimensional Can-1Tin-3Nb3O3n+1− perovskite nanosheets in photoelectrochemical cell

    Surfaces and Interfaces · 2023

    Thi Bao Ngoc Le, Chia-Wei Chang, Yen‐Hsun Su

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  10. Second Harmonic Generation in the Polar A′SmNb2O7 (A′ = Rb, Cs) Dion–Jacobson Layered Perovskites

    Chemistry of Materials · 2023

    Sachin Pal, R. Nagarajan, S. Uma

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  11. Chemical Trends of Surface Reconstruction and Band Positions of Nonmetallic Perovskite Oxides from First Principles

    Chemistry of Materials · 2023

    Yasuhide Mochizuki, Ha‐Jun Sung, Tomoya Gake, Fumiyasu Oba

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  12. Basic and advanced spectrometric methods for complete nanoparticles characterization in bio/eco systems: current status and future prospects

    Analytical and Bioanalytical Chemistry · 2023

    Magdalena Borowska, Krzysztof J. Jankowski

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  13. Geometrical Designing of a Soft‐Layered Halide Perovskite Improper Photoferroelectric for Boosted Photostriction

    Advanced Optical Materials · 2023

    Fafa Wu, Xiaoqi Li, Danmei Pan, Zhihua Sun, Junhua Luo, Xitao Liu

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  14. Competing polar and antipolar phases in n=2 Ruddlesden-Popper niobates and tantalates from first principles

    Physical Review Materials · 2023

    Kishwar-E Hasin, Elizabeth Nowadnick

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  15. Structural chemistry of the n = 3 Dion–Jacobson phases: controlling polarity and band gap

    Journal of Materials Chemistry A · 2025

    Areesha Ali, Vanessa A. Cascos, Faith G. Pritchard, Jan R. R. Verlet, Nicole R. Sutherland, Jack Matthew Woolley, James Lloyd‐Hughes, Maxim Avdeev, Andy Beeby, Stewart J. Clark, Emma E. McCabe

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  16. Investigation of energy storage in 2D Dion-Jacobson type materials using promised DFT + U approach

    Journal of Energy Storage · 2025

    Amal Hamdy Mohamed, Abeer Mera, Zia ur Rehman, Ayesha Saddiqa, Muhammad Awais

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  17. Structural Phase Transitions in Layered Perovskite CsFeF4${\rm CsFeF}_{4}$ and Weak Polar Response in CsFeF4${\rm CsFeF}_{4}$/RbFeF4${\rm RbFeF}_{4}$ Superlattice

    Advanced Theory and Simulations · 2025

    Subhajit Sau, H. Paredes Gutiérrez, Andrés Camilo Garcia-Castro, G. Vaitheeswaran, V. Kanchana

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  18. Synthesis, crystal structure and high-temperature investigation of new Dion-Jacobson type titanoniobates

    Journal of Solid State Chemistry · 2026

    О. В. Крашенинникова, M.S. Lomakin, I.S. SOROKIN, Evgeny V. Suleimanov, V.A. Oloventsova, Dmitry N. Titaev

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  19. Atomic-Scale Visualization of Competing Polar Orders in Dion–Jacobson Layered Perovskites

    Chemistry of Materials · 2026

    Shu Morita, Keita Nishibashi, Keito Niwa, Makoto Kobayashi, Eisuke Yamamoto, Rubén Cantón-Vitoria, Daisuke Urushihara, Toru Asaka, Hidetaka Kasai, Shigeo Mori, Minoru Osada

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  20. Unexpected Structural Complexity in Pseudo-Ruddlesden–Popper Phases

    Chemistry of Materials · 2026

    Tucker Jennings Swenson, Rachel Conway, Subhadip Mallick, Michael A. Hayward, Nicole A. Benedek

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  21. 2D dielectrics and ferroelectrics: emerging materials, physics and design principles

    Applied Physics Express · 2026

    Minoru Osada

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  22. Microwave-Assisted Synthesis of (C12H25NH3)2MCl4 Hybrid Perovskites (M: Zn, Cu, and Mn): Metal-Ion Effects on Structural and Thermal Properties

    ACS Omega · 2026

    Ali Mirahmad, Ravi Shankar Kumar, Breogán Pato‐Doldán, Javier Díez-Sierra

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