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RESEARCH PAPER · Materials Today Chemistry · 2022

A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospect

Shujie Gai, Chen Zhou, Peng Zhi Lu, Meihan Wu, Peixin Gao, Longjie Su, Мaxim S. Моlokeev, Zhi Zhou, Mao Xia

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A novel Cr3+-doped stannate far red phosphor for plant lighting: structure evolution, broad-narrow spectrum tuning and application prospectOriginalSpectroscopically enhanced far-red phosphor Li 2 Mg 3 TiO 6 :Cr 3+ and its application prospects to the cold resistance of rice6Tunable Spinel Structure Phosphors: Dynamic Change in Near‐Infrared Windows and Their Applications84High thermally stable deep red-emitting Sb3+,Ho3+-codoped Cs2NaScCl6 double perovskite for plant lighting42Novel Cr 3+ ‐Doped Garnet Phosphor with Broadband Efficient Far‐Red Emission for Photochrome Matching Plant‐Lighting61Cr 3+ ‐Cr 3+ Ion Pair Induced Fast Energy Migration in Cr 3+ Doped Na‐β‐Al 2 O 3 Ultra‐Wide Near‐Infrared Phosphors for NIR Spectroscopy Application72Efficient and stable near-infrared Y 2 Mg 2 Al 2 Si 2 O 12 :Cr 3+ phosphor: analysis of the luminescence source by a site elimination strategy35Highly efficient and thermostable far-red phosphor for promoting root growth in plants11Near-infrared afterglow enhancement of ZnGa 2 O 4 :Cr 3+ via regulating trap distribution guided by the VRBE diagram5Towards promoting plant growth and fruit maturation: a highly efficient and thermally stable Cr 3+ doped far-red phosphor15A novel highly thermal-stable Ba2GdSbO6:Sm3+ phosphor with intrinsic deep-red emission for personal identification and plant cultivation LEDs42High thermal stability near-infrared aluminoborate phosphor with spectral tunability and its rice lighting application9Thermally Stable Red-Emitting Ca18K3Sc(PO4)14:Mn2+ Phosphor and Enhanced Luminescence by Energy Transfer Between Ce3+-Eu2+-Mn2+22Phosphate phosphors with anti-thermal quenching properties for urban ecological lighting15Pressure/temperature-assisted crystallographic engineering–A strategy for developing the infrared phosphors11Harnessing the brilliance of Cr3+ doped LaAlO3–Al2O3 phosphors with exceptional responsiveness to far-red phytochrome for plant growth LEDs31Effective electron trap regulation in near-infrared persistent phosphor of ZnAl2O4:Cr3+ for round-the-clock plant lighting14Structural characterization and luminescence properties of Cr3+ activated ZnMgTiO4 far-red emitting phosphor2Enhanced broadband NIR luminescence of novel garnet-type Lu3Mg2GaSi2O12:Cr3+ phosphors with different fluxes6Abnormal Lattice Shrinkage, Site Occupation, and Luminescent Properties of Cr 3+ ‐Activated β‐Al 2 O 3 Structure Phosphors29Achieving an Improved NIR Performance of Ca4–xSc2xZr1–xGe3O12:Cr3+ via [Sc3+-Sc3+]→[Ca2+-Zr4+]9Far-red emitting β-LiAlSi2O6:Fe3+: Synthesis, luminescence properties and application prospect26Broadband and high internal quantum efficiency near-infrared phosphors obtained utilizing a chemical unit co-substitution strategy for plant lighting8Dual deep red and far red emitting Cr-doped garnet-perovskite based phosphors with excellent responsiveness to P fr for plant growth LED lighting7Near‐Unity Internal Quantum Efficiency and High Thermal Stability of Sr3MgGe5O14: Cr3+ Phosphor for Plant Growth56Insights into the fluorescence, afterglow and thermoluminescence mechanisms of the Er-doped Mg2SnO4 system and unusual electron traps5A novel dual-excitation and dual-emission (DE2) CaS:EuCe-CN@g-C3N4 phosphor with enhanced thermal stability and humidity resistance3MgF2 assisted synthesis of deep-red MgAl2O4:Cr3+ phosphors with improved emission properties for pc-LED applications4Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application11Simultaneous enhancement of quantum efficiency and thermal stability through double cation substitution (Sr2+→Lu3+, Ge4+→Al3+) in garnet structure for NIR pc-LED3Synthesis and luminescence properties of far-red emitting Li1.6Mg1.6Sn2.8O8:Fe3+ phosphor: Plant growth LED applications6A near-infrared-emitting Na-β"-Al2O3: Mn2+, Cr3+ phosphor and the multiple-sites occupancy of Cr3+2High-Purity Deep Red Emission of Cr3+-Doped YAlO3 Solid Solution with Perovskite Structure for Plant Growth1Optical properties of the double perovskite LaGeSbO6:Eu3 + phosphor with inversion symmetry under broadband excitation for personal identification and secure anti-counterfeiting ink10The great potential of inorganic phosphors in the growing field of plant cultivation: A review9Chromium Ion Pairs Induce Highly Efficient and Thermostable Broadband NIR Phosphor for Plant Lighting and Night Vision12Laser-Driven Sun-Like Full-Spectrum Lighting for High-Fidelity Bright Illumination via Spectrally Engineered Color Converters3White light emission regulation of Eu2+/Bi3+/Sm3+ Co-doped Ca4MgAl2Si3O14 phosphors under near-ultraviolet excitation3Structural Confinement Engineering of Cr 3+ in Nanocrystalline Spinel Glass‐Ceramics for Efficient and Thermally Robust Deep‐Red Plant‐Growth LEDs0Far‐Red Light Supplementation in Tomato Cultivation: A Quantitative Review of Morphological and Physiological Responses0

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  1. Spectroscopically enhanced far-red phosphor Li 2 Mg 3 TiO 6 :Cr 3+ and its application prospects to the cold resistance of rice

    Materials Advances · 2023-01-01

    Yibiao Ma, Siying Li, Jiaqi Wei, Weifang Liao, Beibei Quan, Мaxim S. Моlokeev, Ming Cheng, Xiaoyan Chen, Zhi Zhou, Mao Xia

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  2. Tunable Spinel Structure Phosphors: Dynamic Change in Near‐Infrared Windows and Their Applications

    Advanced Optical Materials · 2023-07-26

    Wen‐Tse Huang, Kuan‐Chun Chen, Ming‐Hsuan Huang, Ru‐Shi Liu

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  3. High thermally stable deep red-emitting Sb3+,Ho3+-codoped Cs2NaScCl6 double perovskite for plant lighting

    Journal of Rare Earths · 2023-11-02

    Houjiang You, Gaoxuanyu Guan, Tianchun Lang, Mingsheng Cai, Peng Su, Huichao He, Yang Zhi Zhong, Tao Han

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  4. Novel Cr 3+ ‐Doped Garnet Phosphor with Broadband Efficient Far‐Red Emission for Photochrome Matching Plant‐Lighting

    Advanced Optical Materials · 2023-12-08

    Xiangyi Dai, Xikun Zou, Haoran Zhang, Weibin Chen, Chaowei Yang, Мaxim S. Моlokeev, Zhiguo Xia, Yingliang Liu, Xuejie Zhang, Mingtao Zheng, Bingfu Lei

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  5. Cr 3+ ‐Cr 3+ Ion Pair Induced Fast Energy Migration in Cr 3+ Doped Na‐β‐Al 2 O 3 Ultra‐Wide Near‐Infrared Phosphors for NIR Spectroscopy Application

    Laser & Photonics Review · 2023-12-16

    Qianxi Pang, Yichao Wang, Liqing Yan, Ge Zhu, Sai Xu, Jinsu Zhang, Xizhen Zhang, Yongze Cao, Baojiu Chen

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  6. Efficient and stable near-infrared Y 2 Mg 2 Al 2 Si 2 O 12 :Cr 3+ phosphor: analysis of the luminescence source by a site elimination strategy

    Journal of Materials Chemistry C · 2024-01-01

    Yixin Sun, Mengmeng Shang, Yining Wang, Yiying Zhu, Xiaole Xing, Peipei Dang, Jun Lin

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  7. Highly efficient and thermostable far-red phosphor for promoting root growth in plants

    Journal of Materials Chemistry C · 2024-01-01

    Sha Ouyang, Jiamai Yin, Liujuan Su, Maohai Yao, Guichao Wang, Jiayi Yang, Maxim S. Molokeev, Zhi Zhou, Sijin Zhang, Mao Xia

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  8. Near-infrared afterglow enhancement of ZnGa 2 O 4 :Cr 3+ via regulating trap distribution guided by the VRBE diagram

    Dalton Transactions · 2024-01-01

    Shuyu Huang, Xinxin Han, Chuanyu Zeng, Anxian Liang, Bingsuo Zou

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  9. Towards promoting plant growth and fruit maturation: a highly efficient and thermally stable Cr 3+ doped far-red phosphor

    Journal of Materials Chemistry C · 2024-01-01

    Chaowei Yang, Xikun Zou, Mengqi Lyu, Mingkai Wei, Ziyi Wang, Xiaoyu Shuang, Xuejie Zhang, Bin Dong, Xinming Li, Cong Yan, Mingtao Zheng, Мaxim S. Моlokeev, Bingfu Lei

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  10. A novel highly thermal-stable Ba2GdSbO6:Sm3+ phosphor with intrinsic deep-red emission for personal identification and plant cultivation LEDs

    Journal of Alloys and Compounds · 2024-01-14

    Kezhou Jiang, Chang Yu Zhou, Wenhao Li, Haoran Su, Daomiao He, Xingyu Chen, Dan Zhang, Shouan Xie, Ruijin Yu

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  11. High thermal stability near-infrared aluminoborate phosphor with spectral tunability and its rice lighting application

    Materials Today Chemistry · 2024-02-10

    Hui Zhu, Yuanyuan Zhao, Siqi He, Zhe Yang, Sha Ouyang, Yuexiang Xi, Chunli Xin, Мaxim S. Моlokeev, Ming Cheng, Xiaoyan Chen, Gemechu Deressa Edossa, Mao Xia, Zhi Zhou

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  12. Thermally Stable Red-Emitting Ca18K3Sc(PO4)14:Mn2+ Phosphor and Enhanced Luminescence by Energy Transfer Between Ce3+-Eu2+-Mn2+

    Inorganic Chemistry · 2024-02-16

    Minliang Deng, Mengmeng Shang, Yixin Sun, Yining Wang, Xiaole Xing

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  13. Phosphate phosphors with anti-thermal quenching properties for urban ecological lighting

    Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy · 2024-02-29

    Cheng Zhou, Peng Dong, Peixin Gao, Zirui Wang, Huifang Ning, Mao Xia, Zhi Zhou

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  14. Pressure/temperature-assisted crystallographic engineering–A strategy for developing the infrared phosphors

    Chemical Engineering Journal · 2024-04-24

    Yi‐Ting Tsai, Tadeusz Leśniewski, Natalia Majewska, Mikołaj Kamiński, Justyna Barzowska, En-Pei Liu, Wei‐Tin Chen, Sebastian Mahlik, Mu‐Huai Fang

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  15. Harnessing the brilliance of Cr3+ doped LaAlO3–Al2O3 phosphors with exceptional responsiveness to far-red phytochrome for plant growth LEDs

    Ceramics International · 2024-05-02

    Khuat Thi Thu, Nguyen Tu, Đỗ Quang Trung, Nguyen Van Du, Manh Trung Tran, Nguyễn Văn Quảng, Ta Ngoc Bach, Thi Ha Lien Nghiem, Duy‐Hung Nguyen, Dao Xuan Viet, Nguyen Duc Trung Kien, Phạm Thành Huy

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  16. Effective electron trap regulation in near-infrared persistent phosphor of ZnAl2O4:Cr3+ for round-the-clock plant lighting

    Materials Today Chemistry · 2024-07-16

    Chen Lü, Peiyang Li, Guichang Shen, X. L. Kang, Shuai Tang, Tao Zhang, Qi Zhu

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  17. Structural characterization and luminescence properties of Cr3+ activated ZnMgTiO4 far-red emitting phosphor

    Journal of Materials Science Materials in Electronics · 2024-09-01

    Keyue Wu, Jingbiao Cui

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  18. Enhanced broadband NIR luminescence of novel garnet-type Lu3Mg2GaSi2O12:Cr3+ phosphors with different fluxes

    Ceramics International · 2024-09-17

    Yixin Sun, Yining Wang, Minliang Deng, Xiaole Xing, Yiying Zhu, Mengmeng Shang

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  19. Abnormal Lattice Shrinkage, Site Occupation, and Luminescent Properties of Cr 3+ ‐Activated β‐Al 2 O 3 Structure Phosphors

    Laser & Photonics Review · 2024-10-04

    Hui Zhu, Yanan Li, Yuexiang Xi, Chunli Xin, Cheng Zhou, Zhe Yang, Lang Ruan, Yanyue Li, Yao Peng, Maxim S. Molokeev, Andrey Zolotov, Jing Wang, Zhi Zhou, Mao Xia

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  20. Achieving an Improved NIR Performance of Ca4–xSc2xZr1–xGe3O12:Cr3+ via [Sc3+-Sc3+]→[Ca2+-Zr4+]

    Inorganic Chemistry · 2024-12-07

    Ying Chen, Rongfei Wei, Lanjiao Li, Xiangling Tian, Fangfang Hu, Hai Guo

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  21. Far-red emitting β-LiAlSi2O6:Fe3+: Synthesis, luminescence properties and application prospect

    Ceramics International · 2024-12-31

    Renping Cao, Xinyue Yang, Xiao-Chun Li, Ruirui Yang, Ting Chen, Bang Lan, Fangrui Cheng, Jing Wang

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  22. Broadband and high internal quantum efficiency near-infrared phosphors obtained utilizing a chemical unit co-substitution strategy for plant lighting

    Journal of Materials Chemistry C · 2025-01-01

    Mengqi Lyu, Jueran Cao, Baoling Tang, Tianrui Li, Mingkai Wei, Haoran Zhang, Xuejie Zhang, Mingtao Zheng, Мaxim S. Моlokeev, Bingfu Lei

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  23. Dual deep red and far red emitting Cr-doped garnet-perovskite based phosphors with excellent responsiveness to P fr for plant growth LED lighting

    RSC Advances · 2025-01-01

    Khuat Thi Thu, Nguyen Tu, Đỗ Quang Trung, Nguyen Van Du, Nguyễn Văn Quảng, Ta Ngoc Bach, Thi Ha Lien Nghiem, Nguyễn Duy Hùng, Dao Xuan Viet, Phạm Thị Lan Hương, Tong Thi Hao Tam, Nguyễn Minh Hiếu, Manh Trung Tran, Phạm Thành Huy

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  24. Near‐Unity Internal Quantum Efficiency and High Thermal Stability of Sr3MgGe5O14: Cr3+ Phosphor for Plant Growth

    Laser & Photonics Review · 2025-02-08

    Qiuming Lin, Xiaozhong Wu, Jiaqing Peng, Weixiong You, Xinyu Ye, Decai Huang

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  25. Insights into the fluorescence, afterglow and thermoluminescence mechanisms of the Er-doped Mg2SnO4 system and unusual electron traps

    Ceramics International · 2025-03-04

    Hongyu Wu, Qiang Liu, Yanhao Huang, Xudong Cui, Chuanliang Feng, Feng Wang

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  26. A novel dual-excitation and dual-emission (DE2) CaS:EuCe-CN@g-C3N4 phosphor with enhanced thermal stability and humidity resistance

    Journal of Luminescence · 2025-03-06

    Mei Peng, Jiaen Xu, Li Shaoai, Zhongxian Qiu, Qinghua Mi, Wenli Zhou, Jilin Zhang, Liping Yu, Liping Yu, Shixun Lian

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  27. MgF2 assisted synthesis of deep-red MgAl2O4:Cr3+ phosphors with improved emission properties for pc-LED applications

    Ceramics International · 2025-03-06

    Xiaoniu Li, Shijie Sun, Jie Gao, Jie Gao, Dong Fang, Mingshun Zhang, Baoxiu Mi, Zhiqiang Gao

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  28. Rare-earth-free far-red-emitting Li1.5La1.5TeO6:Mn4+ phosphors for transparent phosphor film-based light projection application

    Journal of Alloys and Compounds · 2025-04-01

    Jun Kyu Lee, Weiwei Xiang, Jae Su Yu

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  29. Simultaneous enhancement of quantum efficiency and thermal stability through double cation substitution (Sr2+→Lu3+, Ge4+→Al3+) in garnet structure for NIR pc-LED

    Ceramics International · 2025-04-02

    Yichen Yang, Wei Lü, Xiaojiao Kang, Zhennan Zhu, Qiwen Pan, Hongcheng Wang

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  30. Synthesis and luminescence properties of far-red emitting Li1.6Mg1.6Sn2.8O8:Fe3+ phosphor: Plant growth LED applications

    Journal of Alloys and Compounds · 2025-05-22

    Zhenyu Tang, Peichang Ouyang, Yunfang Liu

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  31. A near-infrared-emitting Na-β"-Al2O3: Mn2+, Cr3+ phosphor and the multiple-sites occupancy of Cr3+

    Ceramics International · 2025-06-10

    Xu Sun, Yingnan Dong, Jun Shi, Lipeng Jiang, Jing Wang

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  32. High-Purity Deep Red Emission of Cr3+-Doped YAlO3 Solid Solution with Perovskite Structure for Plant Growth

    ACS Applied Optical Materials · 2025-06-16

    Mengyu Zhang, Chong Li, Wenzhi Su, Chuancheng Zhang, Haitang Hu, Yong Zou, Wenpeng Liu, Qingli Zhang, Shoujun Ding

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  33. Optical properties of the double perovskite LaGeSbO6:Eu3 + phosphor with inversion symmetry under broadband excitation for personal identification and secure anti-counterfeiting ink

    Journal of Alloys and Compounds · 2025-07-15

    Xiya Miao, Xinyue Zhang, Mengkun Zhang, Huixin Yu, Yu Zhang, Kai Sheng, Jinsen Hou, Mubiao Xie, Ruijin Yu

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  34. The great potential of inorganic phosphors in the growing field of plant cultivation: A review

    Inorganic Chemistry Communications · 2025-07-15

    Liza Rani Deka, Vikas Dubey

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  35. Chromium Ion Pairs Induce Highly Efficient and Thermostable Broadband NIR Phosphor for Plant Lighting and Night Vision

    ACS Applied Materials & Interfaces · 2025-08-08

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  36. Laser-Driven Sun-Like Full-Spectrum Lighting for High-Fidelity Bright Illumination via Spectrally Engineered Color Converters

    ACS Applied Electronic Materials · 2025-12-04

    Dheeraj Kumar, Ravendra Kumar Varshney, Dalip Singh Mehta

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  37. White light emission regulation of Eu2+/Bi3+/Sm3+ Co-doped Ca4MgAl2Si3O14 phosphors under near-ultraviolet excitation

    Materials Research Bulletin · 2026-02-02

    Daoyi Wu, Mengmeng SHANG

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  38. Structural Confinement Engineering of Cr 3+ in Nanocrystalline Spinel Glass‐Ceramics for Efficient and Thermally Robust Deep‐Red Plant‐Growth LEDs

    Laser & Photonics Review · 2026-08-22

    Yunshan Xu, Ping Zhang, Qi Chen, Minggui Zhang, Panpan Li, Yao Ji, Enhai Song, Bo Zhou, Weichao Wang, Qinyuan Zhang

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  39. Far‐Red Light Supplementation in Tomato Cultivation: A Quantitative Review of Morphological and Physiological Responses

    Physiologia Plantarum · 2026-09-01

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