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RESEARCH PAPER · Inorganic Chemistry · 2020

Examination of Molten Salt Reactor Relevant Elements Using Hydrothermal Synthesis

Cory J. Windorff, Alexander T. Chemey, Joseph M. Sperling, Bonnie E. Klamm, Thomas E. Albrecht‐Schmitt

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Examination of Molten Salt Reactor Relevant Elements Using Hydrothermal SynthesisOriginalExpansion of the Na3MIII(Ln/An)6F30 Series: Incorporation of Plutonium into a Highly Robust and Stable Framework11Hydrothermal synthesis and properties of MMF5(H2O)7 (M = Co2+ and Ni2+, M = Mn3+, Ga3+, and In3+)8Exploring the Oxidation States of Neptunium with Schiff Base Coordination Complexes19On the Structures of Thorium Fluoride and Oxyfluoride Anions in Molten FLiBe and FLiNaK21High temperature hydrothermal synthesis of inorganic compounds5Silicate‐Mediated Electrolytic Silicon Nanotube from Silica in Molten Salts16Developing Waste Forms for Transuranic Elements: Quaternary Neptunium Fluorides of the Type NaxMNp6F30 (M = Ti, V, Cr, Mn, Fe, Co, Ni, Al, Ga)9Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances12Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design17Chemical Storage of Elemental Fluorine in Nanostructured Cerium Fluorides3Thermal Properties of Binary Chlorides Relevant to Molten Salt Nuclear Chemistry1Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 200

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  1. Expansion of the Na3MIII(Ln/An)6F30 Series: Incorporation of Plutonium into a Highly Robust and Stable Framework

    Chemistry - A European Journal · 2020-07-10

    Kristen A. Pace, Vladislav V. Klepov, Travis K. Deason, Mark D. Smith, Gyanendra B. Ayer, David P. DiPrete, Jake Amoroso, Hans‐Conrad zur Loye

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  2. Hydrothermal synthesis and properties of MMF5(H2O)7 (M = Co2+ and Ni2+, M = Mn3+, Ga3+, and In3+)

    Solid State Sciences · 2020-08-07

    Navindra Keerthisinghe, Vladislav V. Klepov, Eric Zhang, Mark D. Smith, Shani Egodawatte, Stephen H. Foulger, Hans‐Conrad zur Loye

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  3. Exploring the Oxidation States of Neptunium with Schiff Base Coordination Complexes

    Inorganic Chemistry · 2020-11-25

    Bonnie E. Klamm, Cory J. Windorff, Cristian Celis‐Barros, María Joaquina Beltrán-Leiva, Joseph M. Sperling, Thomas E. Albrecht-Schönzart

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  4. On the Structures of Thorium Fluoride and Oxyfluoride Anions in Molten FLiBe and FLiNaK

    The Journal of Physical Chemistry B · 2021-02-03

    Chenyang Wang, Xiuting Chen, Yu Jun Gong

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  5. High temperature hydrothermal synthesis of inorganic compounds

    Elsevier eBooks · 2022-03-29

    Joseph W. Kolis, Colin D. McMillen

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  6. Silicate‐Mediated Electrolytic Silicon Nanotube from Silica in Molten Salts

    Small · 2022-08-07

    Shuangxi Jing, Juanxiu Xiao, Yijun Shen, Biao Hong, Dong Gu, Wei Xiao

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  7. Developing Waste Forms for Transuranic Elements: Quaternary Neptunium Fluorides of the Type NaxMNp6F30 (M = Ti, V, Cr, Mn, Fe, Co, Ni, Al, Ga)

    Journal of the American Chemical Society · 2022-12-19

    Travis K. Deason, Gregory W. Morrison, Amir Mofrad, Hunter B. Tisdale, Jake Amoroso, David DiPrete, Gary S. Was, Kai Sun, Theodore M. Besmann, Hans‐Conrad zur Loye

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  8. Equivalent cation-tuning to realize a new Ce( iv ) fluoride with excellent comprehensive nonlinear optical performances

    Inorganic Chemistry Frontiers · 2024-01-01

    Beibei Zhang, Wen‐Ye Gao, Wei Lin Xu, L. Ma, Wenlong Liu, Ru‐Ling Tang, Sheng‐Ping Guo

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  9. Centrosymmetric CaBaMF8 and Noncentrosymmetric Li2CaMF8 (M = Zr, Hf): Dimension Variation and Nonlinear Optical Activity Resulting from an Isovalent Cation Substitution-Oriented Design

    Inorganic Chemistry · 2024-03-06

    Mei Yan, Ru‐Ling Tang, Wei Xu, Wenlong Liu, Sheng‐Ping Guo

    Read original paper ↗ ·

  10. Chemical Storage of Elemental Fluorine in Nanostructured Cerium Fluorides

    ACS Applied Nano Materials · 2024-07-22

    Valentine Camus-Génot, Édouard Boivin, Christophe Legein, Monique Body, Étienne Durand, Alain Demourgues, Marc Dubois, Batiste Clavier, Kévin Lemoine, Vincent Sarou‐Kanian, Annie Hémon‐Ribaud, V. Maisonneuve, Jérôme Lhoste, Amandine Guiet

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  11. Thermal Properties of Binary Chlorides Relevant to Molten Salt Nuclear Chemistry

    International Journal of Thermophysics · 2026-02-27

    Alexander S. Pixler, Jeremy Jones, Colleen E. Kennedy, Aaron J. Unger, Vitaliy G. Goncharov, Paul Andersen, Cory J. Windorff

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  12. Mild Hydrothermal Synthesis of Zirconium-Containing Fluorides: K 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co), Rb 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni, Cu, Zn), Cs 2 [ M (H 2 O) 6 ][Zr 2 F 12 ] ( M = Fe, Co, Ni), and Cs 2 Zr 3 Mn 3 F 20

    Inorganic Chemistry · 2026-06-30

    Timothy E. Whitesell, Hope Eden Catalano, Mark D. Smith, Hans‐Conrad zur Loye

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