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RESEARCH PAPER · Chemical Communications · 2020

Nonlinear organic–inorganic halide hybrids containing unprecedented linear [MIX 2 ] − coordination units and quasi-two-dimensional lone pairs

Qi Wu, Xian Liu, Yeshuang Du, Chunlin Teng, Fei Liang

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Nonlinear organic–inorganic halide hybrids containing unprecedented linear [MIX 2 ] − coordination units and quasi-two-dimensional lone pairsOriginalA Series of Organic–Inorganic Hybrid Compounds [(C2H5)4N]InCl4–xBrx (x = 0, 2, 4): Synthesis, Crystal Structure, and Nonlinear Optical Properties37Structural Evolution and Optical Property Tunability by Halogen Substitution in [N(CH3)4]MX2 (M = Ga+, In+, X = Cl, Br): A Family of Organically Templated Metal Halides8A In (III)-based organic-inorganic hybrid compound: (C4H7N2)4[InBr6][InBr4]·2H2O with a two-step phase transition and switchable dielectric property16Syntheses, structure and properties of a new series of organic–inorganic Hg-based halides: adjusting halogens resulted in huge performance mutations15Phase Transition and Dielectric Response Originating from Disorder‐Order Transition in the In‐Based Organic‐Inorganic Hybrid Material [NH3(CH2)5NH3][InCl5(H2O)] ⋅ H2O12Acentric Organic–Inorganic Hybrid Halide [N(CH3)4]2HgBr2I2 Featuring an Isolated [HgBr2I2]2– Tetrahedron and Second-Order Nonlinearity18A new square pyramidal copper(II) complex [Cu(C10H24N4)Br]Br: Crystal structure, thermal analysis, Hirschfeld surfaces, electrical and semiconducting properties25Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties8A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance8Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence46Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO48Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities28A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials150Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics26Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics7One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy3Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering39Chiral Ligand-Induced Second-Harmonic Generation Response in Helical One-Dimensional Hybrid Lead Bromides9Unlocking Strong SHG Response and Large Birefringence in Hybrid Antimony Halides via a Three-in-One Strategy7Halogen Engineering and Orbital Origins of Large Second-Harmonic Generation in Organic–Inorganic Hybrid Metal Halides2

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  1. A Series of Organic–Inorganic Hybrid Compounds [(C2H5)4N]InCl4–xBrx (x = 0, 2, 4): Synthesis, Crystal Structure, and Nonlinear Optical Properties

    Inorganic Chemistry · 2020-04-01

    Xian Liu, Wenli Xu, Siran Xu, Xin‐Yao Yu, Yuqing Deng, Xiaohui Wu, Fei Liang, Qi Wu

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  2. Structural Evolution and Optical Property Tunability by Halogen Substitution in [N(CH3)4]MX2 (M = Ga+, In+, X = Cl, Br): A Family of Organically Templated Metal Halides

    Inorganic Chemistry · 2020-07-15

    Xian Liu, Wan Ya, Qi Wu, Fei Liang, Jun Zhang

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  3. A In (III)-based organic-inorganic hybrid compound: (C4H7N2)4[InBr6][InBr4]·2H2O with a two-step phase transition and switchable dielectric property

    Polyhedron · 2020-08-02

    Min Li, Guan‐Cheng Xu, Wen‐Bo Xin, Yin-Qiang Zhang

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  4. Syntheses, structure and properties of a new series of organic–inorganic Hg-based halides: adjusting halogens resulted in huge performance mutations

    Dalton Transactions · 2021-01-01

    Can Yang, Xian Liu, Chunlin Teng, Qi Wu, Fei Liang

    Read original paper ↗ ·

  5. Phase Transition and Dielectric Response Originating from Disorder‐Order Transition in the In‐Based Organic‐Inorganic Hybrid Material [NH3(CH2)5NH3][InCl5(H2O)] ⋅ H2O

    European Journal of Inorganic Chemistry · 2021-01-21

    Yin‐Qiang Zhang, Min Li, Guan‐Cheng Xu

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  6. Acentric Organic–Inorganic Hybrid Halide [N(CH3)4]2HgBr2I2 Featuring an Isolated [HgBr2I2]2– Tetrahedron and Second-Order Nonlinearity

    Inorganic Chemistry · 2021-04-22

    Can Yang, Xian Liu, Chunlin Teng, Qi Wu, Fei Liang

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  7. A new square pyramidal copper(II) complex [Cu(C10H24N4)Br]Br: Crystal structure, thermal analysis, Hirschfeld surfaces, electrical and semiconducting properties

    Journal of Molecular Structure · 2021-05-09

    Wassim Maalej, Philippe Guionneau, Zakaria Elaoud

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  8. Halogen-Ion-Induced Structural Phase Transition Giving a Polymorph of HgBr2 with Balanced Nonlinear Optical Properties

    Inorganic Chemistry · 2021-12-02

    Qi Wu, Can Yang, Jie Ma, Xian Liu, Yanjun Li

    Read original paper ↗ ·

  9. A novel 2-(aminomethyl)pyridineH 2 PO 4 crystal with second-order nonlinear optical performance

    CrystEngComm · 2022-01-01

    Duanliang Wang, Defu Sun, Shoubao Zhang, Jiancai Leng, Ruoxian Hou, Hanzhang Chen, Jie Sun, Yangyang Dang, Chuanying Shen

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  10. Organic Cation Modulation Triggered Second Harmonic Response in Manganese Halides with Bright Fluorescence

    Inorganic Chemistry · 2022-07-20

    Yue Guo, Jiajing Wu, Wenlong Liu, Sheng‐Ping Guo

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  11. Characteristics of structure, thermal stability and optical properties for a novel NLO crystal (C5H12NO)H2PO4

    Optical Materials · 2022-11-27

    Duanliang Wang, Xiangsheng Meng, Nana Zhang, Defu Sun, Ruoxian Hou, Hanzhang Chen, Xiaobing Liu

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  12. Quasi-linear CuX 2 (X = Cl, Br) motif-built hybrid copper halides realizing encouraging nonlinear optical activities

    Inorganic Chemistry Frontiers · 2023-01-01

    Jing‐Li Qi, Jiajing Wu, Yue Guo, Zhong-Ping Xu, Wenlong Liu, Sheng‐Ping Guo

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  13. A review of the relationship between the structure and nonlinear optical properties of organic-inorganic hybrid materials

    Coordination Chemistry Reviews · 2023-10-06

    Yuwei Kang, Qi Wu

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  14. Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics

    Angewandte Chemie International Edition · 2024-05-15

    Chen Sun, Yukong Li, Jinlin Yin, Dongyang Li, Chao Wu, Chi Zhang, Honghan Fei

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  15. Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics

    Angewandte Chemie · 2024-05-15

    Chen Sun, Yukong Li, Jinlin Yin, Dongyang Li, Chao Wu, Chi Zhang, Honghan Fei

    Read original paper ↗ ·

  16. One-Dimensional Perovskite RbGeI3 with Large Optical Anisotropy

    Inorganic Chemistry · 2025-02-12

    Huige Chen, Deshuai Xiao, Pifu Gong, Xinyuan Zhang, Zheshuai Lin, Lei Kang

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  17. Toward the Strongest Nonlinear Optical Response and Largest Birefringence in Solvent‐Free Organic–Inorganic Metal Halides by Hydrogen Bond Engineering

    Advanced Functional Materials · 2025-03-05

    Yong Wu, Yuchao Li, Yangkai Zhang, Bing Teng, Xingxing Jiang, Hu Chen, Shijia Sun, Lifeng Cao, Jinkang Ma, Kai Xu, Degang Xu, Zheshuai Lin, Degao Zhong

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  18. Chiral Ligand-Induced Second-Harmonic Generation Response in Helical One-Dimensional Hybrid Lead Bromides

    Inorganic Chemistry · 2025-06-02

    Qiao‐Feng Huang, Shufang Yan, Ying Fu, Wenlong Liu, Jiajing Wu, Sheng‐Ping Guo

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  19. Unlocking Strong SHG Response and Large Birefringence in Hybrid Antimony Halides via a Three-in-One Strategy

    Inorganic Chemistry · 2026-02-03

    Yuqi Xu, Yi-Fan Fu, Wen-Dong Yao, Yumei Zhang, Liming Kong, Wenlong Liu, Jiajing Wu

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  20. Halogen Engineering and Orbital Origins of Large Second-Harmonic Generation in Organic–Inorganic Hybrid Metal Halides

    The Journal of Physical Chemistry Letters · 2026-03-26

    Sajid Ali, Xiyue Cheng, Qilu Xu, Sohail Mumtaz, Hanxiang Mi, Tingting Liang, Shuiquan Deng

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