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RESEARCH PAPER · Chemistry of Materials · 2021

Structural Confinement for Cr 3+ Activators toward Efficient Near-Infrared Phosphors with Suppressed Concentration Quenching

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Structural Confinement for Cr 3+ Activators toward Efficient Near-Infrared Phosphors with Suppressed Concentration QuenchingOriginalImproved thermal stability of the near‐infrared Al‐modulated Zn 3 Ga 2 GeO 8 : Cr 3+ phosphors for plant growth applications36Efficient broadband near-infrared phosphor Sr2ScSbO6:Cr3+ for solar-like lighting146Achieving an ultra-broadband infrared emission through efficient energy transfer in LiInP2O7: Cr3+, Yb3+ phosphor80Structural Confinement toward Controlling Energy Transfer Path for Enhancing Near-Infrared Luminescence77Spectrally tunable and thermally stable near-infrared luminescence in Na 3 Sc 2 (PO 4 ) 3 :Cr 3+ phosphors by Ga 3+ co-doping for light-emitting diodes62Variation from Zero to Negative Thermal Quenching of Phosphor with Assistance of Defect States45Octahedron-dependent near-infrared luminescence in Cr3+-activated phosphors99Luminescence properties, energy transfer and thermal stability of white emitting phosphor Sr 3 (PO 4 ) 2 :Ce 3+ /Tb 3+ /Mn 2+ for white LEDs7Accessing High-Power Near-Infrared Spectroscopy Using Cr3+-Substituted Metal Phosphate Phosphors114Achievement of high efficiency and thermally stable near-infrared phosphors by designing a chromium crystallographic environment for nondestructive testing and night vision15Broadband near-infrared luminescence from Fe 3+ -activated NaScSi 2 O 6 phosphors for luminescence thermometry and night-vision applications70Consequence of optimal bonding on cation ordering and enhanced near-infrared luminescence in Cr 3+ -doped pyroxene oxides49Cr 3+ -Doped double perovskite antimonates: efficient and tunable phosphors from NIR-I to NIR-II78Crystal-field induced tuning of luminescence properties of Na 3 Ga x Al 1− x F 6 :Cr 3+ phosphors with good thermal stability for NIR LEDs20Crystallographic control for Cr 4+ activators toward efficient NIR-II luminescence91Defect Induced Anti-Thermal Quenching of Cr3+ Doped Zn1- X Li2 X Ga2o4 for Plant Growth Led28Efficient and thermally stable broadband near-infrared emission in a garnet Gd 3 In 2 Ga 3 O 12 :Cr 3+ phosphor44High thermal stability phosphors with a rigid structure similar to the benzene ring and application in plant growth21Luminescence properties of Cr 3+ -doped near-infrared emissive fluoroyttrates for light-emitting diodes18Thermally Robust Broadband Near-Infrared Luminescence in the Nagap2o7:Cr3+ Phosphor2Charge compensating effect of rare earth ions Ln3+ (Ln =Y, La) on the photoluminescence improvement of Sr9MgK(PO4)7:Eu2+ phosphor5Oxygen vacancy substitution tuning photoluminescence of self-activated LiGaSi(1-)Ge O4 phosphors9Glass‐Crystallized Luminescence Translucent Ceramics toward High‐Performance Broadband NIR LEDs120Effects of activated Sr 2+ ion content on strong blue‐emitting Ca 2 Sb 2 O 7 materials for high‐quality WLED devices5Novel Cr3+-activated far-red emitting phosphors with β-Ca3(PO4)2-type structure for indoor plant cultivation37Narrow-Band Red-Emitting Phosphors with High Color Purity, Trifling Thermal and Concentration Quenching for Hybrid White LEDs and Li3Y3BaSr(MoO4)8:Sm3+, Eu3+-Based Deep-Red LEDs for Plant Growth Applications99Efficient and Thermally Stable Broad-Band Near-Infrared Emission in a KAlP 2 O 7 :Cr 3+ Phosphor for Nondestructive Examination191Superb thermal stability purple-blue phosphor through synergistic effect of emission compensation and nonradiative transition restriction of Eu2+31Spectral engineering and thermometric performance of LiIn(Si2-Ge )O6: Cr3+ phosphor for multi-mode NIR thermometry26NIR emission spectral engineering in NaSc(Si,Ge)2O6: Cr3+ solid-solution phosphors via crystal field regulation24Cr3+/Yb3+/Nd3+-doped Ba2LaGa11O20 broadband NIR phosphors for NIR pc-LED and c-Si solar cells10Highly Efficient and Stable Near‐Infrared Broadband Garnet Phosphor for Multifunctional Phosphor‐Converted Light‐Emitting Diodes118Broadband near-infrared emission in the NaInP2O7:Cr3+ phosphor for light-emitting-diode applications50Highly efficient Fe3+-doped A2BB′O6 (A = Sr2+, Ca2+; B, B′ = In3+, Sb5+, Sn4+) broadband near-infrared-emitting phosphors for spectroscopic analysis251Broadband Near-Infrared-Emitting Phosphors with Suppressed Concentration Quenching in a Two-Dimensional Structure47Efficient Broadband Near-Infrared CaMgGe 2 O 6 :Cr 3+ Phosphor for pc-LED85Broadband NIR-II phosphors with Cr4+ single activated centers based on special crystal structure for nondestructive analysis64A super stable Near-Infrared garnet phosphor resistant to thermal Quenching, thermal degradation and hydrolysis57Spectral Regulation and Efficiency Optimization in Cr3+‐Doped Gadolinium Aluminum Gallium Garnet Near‐Infrared Ceramic Phosphors via Crystal‐Field Engineering29Molten Salt Synthesis of Broad-Band Near-Infrared InBO 3 :Cr 3+ Submicron Phosphor and Its Luminescent Enhancement by Lanthanide Ion Codoping23Customization of novel double-perovskite (Ca,Sr)2InNbO6:Mn4+ red-emitting phosphors for luminescence lifetime thermometers with good relative sensing sensitivity43Sr-substitution-guided Eu2+ site engineering of Ca9Nd(PO4)7:Eu2+ for high-efficiency white light-emitting diodes9Energy Level Diagram of 3d2 Configuration in Tetrahedral Crystal Field and Its Applications to Cr4 + /Mn5 + ‐Doped Luminescent Materials43Advances in Chromium‐Activated Phosphors for Near‐Infrared Light Sources489Structure and tunable broadband near-infrared luminescence of Cr3+ in borophosphate glass23The third biological window luminescence for tissue penetration through Cr–Er energy transfer6Two-stage ultra-broadband luminescence of Cr3+-doped multisite layered phosphor Sr3Ga2Ge4O14 and its application in pc-LEDs33Thermally Robust Broadband Near-Infrared Luminescence in the NaGaP2O7:Cr3+ Phosphor23Systematical site investigation and temperature sensing in Pr3+-doped M3RE4O9 (M = Sr and Ba; RE = Sc, Y, Lu)18Multifunctional optical sensing applications of luminescent ions doped perovskite structured LaGaO3 phosphors in near-infrared spectroscopy50Blue–red dual emission of ZnGa2−xO4:xCr3+ phosphors with satisfactory thermal stability for plant cultivation5Producing Tunable Broadband Near-Infrared Emission through Co-Substitution in (Ga1–xMgx)(Ga1–xGex)O3:Cr3+77Does Cr3+Occupy Tetrahedral Sites and Luminesce in Oxides? A First-Principles Exploration36A novel efficient broadband near-infrared phosphor LiGaGe 2 O 6 :Cr 3+ with EQE enhancement and spectral tuning by Sc 3+ –Ga 3+ substitution for NIR pc-LED application43Engineering the local structure of ZnGa2O4: Cr3+ via Mg substitution to realize superior luminescence18Ultra-broadband near-infrared emission in the double-perovskite Ca2InTaO6:Cr3+ phosphor for light-emitting-diode applications43Recent Advances in Chromium‐Doped Near‐Infrared Luminescent Materials: Fundamentals, Optimization Strategies, and Applications252Double‐Site Occupation Triggered Broadband and Tunable NIR‐I and NIR‐II Luminescence in AlNbO4:Cr3+ Phosphors15An Efficient Perovskite‐Like Phosphor with Peak Emission Wavelength at 850 nm for High‐Performance NIR LEDs43Simultaneous Absorption and Near‐Infrared Emission Enhancement of Cr 3+ Ions in MgGa 2 O 4 Spinel Oxide via Anionic F‐Substitution88An efficient and thermally stable Cr 3+ -activated Y 2 GdSc 2 Al 2 GaO 12 garnet phosphor for NIR spectroscopy applications14Blue-light-excitable pure and efficient short-wave infrared luminescence via Cr 3+ → Yb 3+ energy transfer in a KYbP 2 O 7 :Cr 3+ phosphor24Composition–structure–luminescence and enhancement of Cr 3+ activated broadband near infrared phosphors for night vision, bio-imaging, and noninvasive detection19Dynamic readout of optical information based on the color-tunable emitting electron-trapping material BaAl 12 O 19 :Eu 2+ toward high security level optical data storage and anticounterfeiting27K 2 LiScF 6 :Cr 3+ /Mn 4+ fluoride phosphor with enhanced broadband emission for NIR pc-LEDs29Near-infrared luminescence and high thermal stability of Rb 2 NaScF 6 :Cr 3+ phosphor for spectroscopy applications14Near-infrared Sr 7 NaGa(PO 4 ) 6 :Cr 3+ ,Ln 3+ (Ln = Nd, Er, and Yb) phosphors with different energy transfer paths: photoluminescence enhancement and versatility39Spectrally tunable near-infrared photoluminescence in MP 3 O 9 :Cr 3+ (M = Al, Ga, In) phosphate phosphors13Spectroscopically enhanced far-red phosphor Li 2 Mg 3 TiO 6 :Cr 3+ and its application prospects to the cold resistance of rice6Structural confinement toward suppressing concentration and thermal quenching for improving near-infrared luminescence of Fe 3+69Cr3+‐Facilitated Ultra‐Sensitive Luminescence Ratiometric Thermometry at Cryogenic Temperature51Ultrawide near‐infrared SrHfO 3 :Cr 3+ phosphor with dual emission bands40Tunable broadband near-infrared emission in LiScO2:Cr3+ phosphor induced by the variation of chromium ion concentration26Dual anti-thermal quenching induced by defect levels of the Ba3EuAl2O7.5 phosphor12Screening of Broadband Near-Infrared Cr3+-Activated Phosphors Using Ce3+ as a Probe39Introducing Jahn-Teller distortion to enhance the practicability of (Ga,Sc)2O3:Cr3+ near-infrared phosphor18Luminescence enhancement of Cr3+ doped garnet phosphor for high-performance LED towards smart NIR light source47Thermal Stability Improvement of Cr3+‐Activated Broadband Near‐Infrared Phosphors via State Population Optimization60Design and fabrication of a bimodal emitting phosphor by co-doping two different activators for high sensitivity temperature sensing12Novel AMoO4:Eu3+ (A = Ca and Ba) optical thermometer: Investigation of effect of local ionic coordination environment on optical performance and temperature measurement sensitivity11Energy recruitment via lanthanide-chelate to boost the persistent luminescence of nanophosphor for contrast-enhanced tumor navigation19Creating an efficient and tunable near-infrared emission by using [Mg2+-Sn4+] chemical unit co-substitution in Ga2O3:Cr3+ phosphor7Intervalence charge transfer of Cr3+-Cr3+ aggregation for NIR-II luminescence165Multiple defects induced near-infrared self-luminescence of (Ca,Sr)LaMgTaO6 double perovskite phosphor29Soft X-ray induced color-tunable long afterglow phosphors Ca9-xTb(PO4)7:xMn2+ based on Mn2+ modulation and energy transfer13Achieving an ultra-high absorption efficiency in a monoclinic LiAlP2O7:Cr3+ near-infrared phosphor16Broadband near infrared emission in Cr3+: Cs2AgBiCl6 double perovskite halides16Study on preparation, optical properties and mechanism of Zn2SnO4:Cr3+ with high NIR luminescence intensity6Suppressed Concentration Quenching Brightens Short‐Wave Infrared Emitters74Structural Confinement Induced Near‐Unity Quantum Yield for Single‐Band Ratiometric Thermometry36Zero thermal quenching and suppressed concentration quenching in a highly efficient structure‐confined fluoride near-infrared phosphor20High-color-quality blue-light-pumped full-spectrum white-light-emitting diodes realized by efficient green-emitting CaY2HfScAl3O12:Ce3+ phosphors24Synergistic effect of dual-site occupation and activators confinement realizing an efficient ultra-broadband NIR emitter5Crystallization of Na2SrGe6O14:Cr3+,Yb3+ Glass Ceramics Enabling a Watt‐Level Output Power NIR‐I/NIR‐II Lighting Source56Broadband La 2 LiSbO 6 : Cr 3+ Phosphors with Double Luminescent Centers for NIR pc-LEDs32How to Achieve Excellent Luminescence Properties of Cr Ion‐Doped Near‐Infrared Phosphors103Multiple lattice sites occupied AlTaO4:Cr3+ phosphor for luminescence ratiometric thermometry and NIR light source31High‐Performance NIR Emission in Chromium‐Doped Garnet Phosphors Enabled by Structure and Excitation Regulation67An ultra broadband NIR phosphor LiScSnO4:Cr3+ with emission wavelength peaking at 900 nm for component analysis14Tunable broadband near-infrared photoluminescence of Mg2LaTaO6:Cr3+ phosphors for light-emitting diodes20Ni2+-doped MgTa2O6 phosphors capable of near-infrared II and III emission under blue-light excitation126Developing and optimizing novel Cr 3+ -activated inorganic NIR phosphors by combining triple-objective optimization and crystal field engineering25Cooperative cationic substitution strategy triggers high blue-light absorptance and near-infrared emission with high quantum efficiency in Cr3+-activated pyroxene-type assembly11Enhancement of photoluminescence properties in Na+ doped K2BaPO4F:Sm3+ phosphors13A highly Mn 2+ -doped narrowband green phosphor toward wide color-gamut display applications26Achieving Luminescence of Sr3Ga1.98In0.02Ge4O14:0.03Cr3+ via [In3+] Substitution [Ga3+] and Its Application to NIR pc-LED in Non-Destructive Testing5Tailoring Fe3+‐Activated Broadband NIR Phosphors: Enhancing External Quantum Efficiency and Spectrum Adjustability Through Crystal Field Engineering in Double Perovskite Antimonate Structures46A novel broadband near‐infrared Ca 2 Y 3 Sb 3 O 14 : Cr 3+ rhombohedral pyrochlores phosphor and its application in pc‐LEDs12Small Stokes Shift and Two‐Site Occupation in the ANb2O6:Cr3+ (A = Zn/Mg) Phosphors Toward Highly Efficient Ultra‐Broadband Near‐Infrared Emission for Multifunctional Applications24A novel near-infrared phosphor Li 1.6 Mg 1.6 Sn 2.8 O 8 :Cr 3+ for near-infrared spectral analysis25Abnormal spectral broadening of ordered-structure near-infrared phosphor La 2 CaHfO 6 :Cr 3+15Broadband Ca 3 MgZrGe 3 O 12 :Cr 3+ garnet phosphor for high-performance NIR pc-LED application14Broadband near-infrared luminescence in a cubic pyrophosphate Al 0.5 Ta 0.5 P 2 O 7 :Cr 3+ phosphor for multi-functional applications7Fluorescence Properties of Fluorapatite with Various Eu-Doped Concentration0High performance NIR-I to NIR-II emission of a Cr 3+ -doped Cs 2 NaLuCl 6 phosphor with an IQE and EQE of up to 92.9% and 60.75%44Ions Co-Substitution Strategy Toward Tunable Broadband Near-Infrared Luminescence from Cr3+ Doped Gallium Oxide Based Phosphors0Long-wavelength near-infrared emission in chromium-activated LiZnNbO 4 spinel crystals and valence-converting enhancement via Er 3+ ion heterotopic doping11Near-infrared Cr 3+ -doped lead-free halide perovskite microcrystals for information encryption and temperature thermometry34Tunable broadband near-infrared luminescence from Cr 3+ -doped gallium oxide-based phosphors for advanced sensing and LED applications12Tunable near-infrared phosphor LiSc 2 SbO 6 :Cr 3+ by Mg 2+ substitution and Yb 3+ co-doping for phosphor-converted light-emitting diodes4Tailoring Ultra‐Wide Visible‐NIR Luminescence by Ce3+/Cr3+/Yb3+‐alloying Sc‐Based Oxides for Multifunctional Optical Applications24Manipulating alkali charge compensation to improve red fluorescence and thermostability in Ba5P6O20:Eu3+ phosphor51Vibronically Coupled Near-Infrared Emission and Excitation from d−d Transitions of Cs2MX6 (M = Mo/W, X = Cl/Br)42A highly thermal stable cubic-phase Sc(PO3)3:Cr3+ phosphor with emitting peak at 875 nm17Thermally Stable Red-Emitting Ca18K3Sc(PO4)14:Mn2+ Phosphor and Enhanced Luminescence by Energy Transfer Between Ce3+-Eu2+-Mn2+22Efficient broad-band NIR-II emitting phosphor Mg4Ta2O9: Ni2+ with satisfactory thermal stability of luminescence59Super thermally stable Rb-β-Al2O3:Eu blue phosphor for full-spectra lighting4Advances in Fe3+-activated luminescent materials for near-infrared light sources64Extending Near-Infrared Emission Beyond 900 nm in Cr3+-Activated Niobate Double Perovskites10Obtaining versatile Cr3+-activated phosphors with improved far-red emissions via host composition modulation13Remote optical thermometry by two-dimensional LiAl5O8:Cr3+ luminescence sensor probe5Synthesis and luminescent properties of highly thermally stable GdGa3(BO3)4:Cr3+ broadband near-infrared phosphors for near-infrared LED applications19Blue‐Light‐Excitable Broadband Ca 3 Ga 2 Ge 3 O 12 :Cr 3+ ,Ni 2+ Phosphor for the Applications in NIR‐II Window82A novel far-red and near-infrared adjustable phosphor Sr9Al(PO4)7:Cr3+: structure and luminescence properties4Two substitution strategies realize single-phase full-spectrum emission in Ca10Na(PO4)7:Eu2+ phosphors for WLED17Na2CaP2O7:Cr3+ phosphor toward broadband emission3An energy transfer strategy towards versatile sensing applications from Cr3+ and Yb3+ codoped near infrared phosphors4Efficient violet-light-excitable blue-cyan-emitting Ca2YHf2GaAl2O12:Ce3+ garnet phosphors enable high-color-rendering full-spectrum warm-white LEDs44NIR‐II Luminescence With A Recorded 76% EQE Through Energy Extraction From Dark Cr3+40Near‐Infrared Mechanoluminescence from Cr 3+ ‐Doped Spinel Nanoparticles for Potential Oral Diseases Detection47Near-infrared-emitting (Gd1-Nd )3(Ga1-Cr )5O12 glass ceramic phosphors for light-emitting diodes2Activator Heavy Solid Solution in Rigid Framework: An Effective Strategy Toward Highly Efficient and Thermally Stable Near‐Infrared Emission for Wireless Communication25Hydrofluoric Acid-Free Broadband Near-Infrared Phosphors K2LiMF6:Cr3+ with Zero-Thermal Quenching: Structure, Luminescence, and Application29Uncovering the presence or absence of photoluminescence from iron ions in crystals10Efficient and Near-Zero Thermal Quenching Cr3+-Doped Garnet-Type Phosphor for High-Performance Near-Infrared Light-Emitting Diode Applications6Tunable Luminescence in LiSc1‐yGayW2O8:Cr3+ Phosphors for LED Applications34Suppressed concentration quenching and tunable photoluminescence in Eu2+-activated Rb3Y(PO4)2 phosphors for full-spectrum lighting87Energy-Transfer-Enhanced Cr 3+ /Ni 2+ Co-doped Broadband Near-Infrared Phosphor for Fluorescence Thermometers and Near-Infrared Window Imaging27Cr3+-Doped LiAlO2 NIR-I Emitting Phosphors with Superior Resistance to Thermal Quenching for Night Vision Monitoring and Bioimaging47Red-shifting and boosting the emission of NaScP2O7:Cr3+ via efficient energy transfer for information encryption and anti-counterfeiting5

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